Origin of Hydrocarbons in Hydrothermal Sulfide Ores in the Mid-Atlantic Ridge   总被引：2，自引：0，他引：2  

Lein  A. Yu.  Peresypkin  V. I.  Simoneit  B. R. T. 《Lithology and Mineral Resources》2003,38(5):383-393

The Rainbow hydrothermal field (36° N Mid-Atlantic Ridge) is one of the three presently known fields related to serpentinization of ultramafic rocks accompanied by the formation of hydrogen- and methane-rich solutions. Gas chromatographic (GC) and molecular gas chromatographic–mass spectrometric (GC-MS) investigations of sulfide ores and sediments from this field confirmed a predominantly biological nature of bitumoids related to the high-temperature transformation of biomass of the hydrothermal biological community. At the same time, ores of the Rainbow field contain significant amounts of compounds that are not directly related to biogenic synthesis. This fact suggests the possibility of an abiogenic synthesis of methane and even complex hydrocarbons during the serpentinization of ultramafic rocks.  相似文献   

Methanol emission in distant protoplanetary disks     

I. E. Val'tts  S. Yu. Lyubchenko 《Astronomy Reports》2003,47(10):797-808

Thirty four-frequency line profiles of Class II methanol masers have been analyzed to investigate carefully the coincidences of various spectral features. Data at 6.7, 12.2, 107, and 156.6 GHz have been analyzed. Two clusters of Class II methanol maser lines at 6.7 and 12.2 GHz are observed in the spectra of many sources. These maser-line clusters are located on either side of the thermal methanol lines at 107 and 156.6 GHz. To avoid the effect of amplification in these thermal methanol lines, a similar analysis was performed for 80 sources having both maser emission at 6.7 GHz and thermal CS emission. The relative distributions of the methanol maser lines and the thermal CS line confirm on the basis of richer statistics that the maser lines are located in two clusters on either side of the thermal feature. It is proposed that the two maser-line clusters correspond to two edges of a Keplerian disk. The thermal methanol and CS emission is formed in dense molecular cores, whose centers are coincident with the disk centers.  相似文献   

Mineralized Microbiota: A Possible Indicator of Hydrocarbon Flows in the Rift Zone of Iceland     

A. P. Geptner  Yu. I. Pikovskii  L. T. Protasevich  T. A. Alekseeva  M. E. Ramenskaya 《Lithology and Mineral Resources》2003,38(6):509-521

Relationships of mineralized microbiota with the content of polycyclic aromatic hydrocarbons in hydrothermal systems are considered. It has been established that the mineralized microbiota can serve as an indicator of hydrothermal hydrocarbon flows in present-day and ancient deposits.  相似文献   

An Unusual Texture: Skeletal Sphalerite in Pyrite from Dajing Tin-polymetallic Deposit, China     

Yu Wang Wang    Jing Bin Wang  Li Juan Wang 《Resource Geology》2003,53(1):67-72

Abstract. Skeletal sphalerite with stellar, cruciform and snowflake-like (or cauliflower-like) shapes included in pyrite is widely found in the Dajing tin-polymetallic deposit. It occurs only in chalcopyrite-pyrite mineralization stage. The compositions of all sphalerites in the chalcopyrite-pyrite stage are characterized by high Cu content (3.9 - 7.0 wt% with a mean of 5.4 wt%), while the skeletal crystal sphalerite has higher zinc and cadmium contents, and lower copper and iron contents, compared with other sphalerites of the same stage. The skeletal crystal sphalerite in pyrite is possibly generated by exsolution.  相似文献   

Desorption kinetics of radiocesium from subsurface sediments at Hanford Site, USA     

Chongxuan Liu  John M. Zachara  James P. McKinley 《Geochimica et cosmochimica acta》2003,67(16):2893-2912

The desorption of ¹³⁷Cs⁺ was investigated on sediments from the United States Hanford site. Pristine sediments and ones that were contaminated by the accidental release of alkaline ¹³⁷Cs⁺-containing high level nuclear wastes (HLW, 2 × 10⁶ to 6 × 10⁷ pCi ¹³⁷Cs⁺/g) were studied. The desorption of ¹³⁷Cs⁺ was measured in Na⁺, K⁺, Rb⁺, and NH₄⁺electrolytes of variable concentration and pH, and in presence of a strong Cs⁺-specific sorbent (self-assembled monolayer on a mesoporous support, SAMMS). ¹³⁷Cs⁺ desorption from the HLW-contaminated Hanford sediments exhibited two distinct phases: an initial instantaneous release followed by a slow kinetic process. The extent of ¹³⁷Cs⁺ desorption increased with increasing electrolyte concentration and followed a trend of Rb⁺ ≥ K⁺ > Na⁺ at circumneutral pH. This trend followed the respective selectivities of these cations for the sediment. The extent and rate of ¹³⁷Cs⁺ desorption was influenced by surface armoring, intraparticle diffusion, and the collapse of edge-interlayer sites in solutions containing K⁺, Rb⁺, or NH₄⁺. Scanning electron microscopic analysis revealed HLW-induced precipitation of secondary aluminosilicates on the edges and basal planes of micaceous minerals that were primary Cs⁺ sorbents. The removal of these precipitates by acidified ammonium oxalate extraction significantly increased the long-term desorption rate and extent. X-ray microprobe analyses of Cs⁺-sorbed micas showed that the ¹³⁷Cs⁺ distributed not only on mica edges, but also within internal channels parallel to the basal plane, implying intraparticle diffusive migration of ¹³⁷Cs⁺. Controlled desorption experiments using Cs⁺-spiked pristine sediment indicated that the ¹³⁷Cs⁺ diffusion rate was fast in Na⁺-electrolyte, but much slower in the presence of K⁺ or Rb⁺, suggesting an effect of edge-interlayer collapse. An intraparticle diffusion model coupled with a two-site cation exchange model was used to interpret the experimental results. Model simulations suggested that about 40% of total sorbed ¹³⁷Cs⁺ was exchangeable, including equilibrium and kinetic desorbable pools. At pH 3, this ratio increased to 60-80%. The remainder of the sorbed ¹³⁷Cs⁺ was fixed or desorbed at much slower rate than our experiments could detect.  相似文献   

天津气象塔风温梯度观测资料的统计特征   总被引：6，自引：0，他引：6       下载免费PDF全文

解以扬  刘学军 《气象》2003,29(1):12-16

利用天津气象塔风温梯度观测资料对其统计特征及平均风温廓线的日变化规律进行了分析，特别是分析了稳定层结的风温廓线特征，还给出了几种典型天气的低层大气结构的个例分析。  相似文献   

重庆雾的特点及其变化分析   总被引：16，自引：2，他引：16       下载免费PDF全文

向波  刘德  廖代强 《气象》2003,29(2):48-52

利用重庆市沙坪坝195l一2001年的资料，对重庆市区雾的生消时间、持续时间、能见度等主要特征变量及其相对湿度，温度差等相关气象要素做了较为全面的分析，认为城市热岛效应可能是造成重庆主城区雾日数减少的重要原因之一。  相似文献   

BP神经网络模型在重庆伏旱预测中的应用研究   总被引：7，自引：0，他引：7  

李永华  刘德  金龙  高阳华 《气象》2003,29(12):14-17

采用气象要素定义伏旱指数，利用小波分析等方法分析重庆地区伏旱变化特征，最后采用BP神经网络模型对伏旱进行预测试验，结果表明，重庆伏旱变化具有明显的阶段性特征，而基于BP神经网络模型的伏旱预测模型预测效果良好，可以应用于实际预测。  相似文献   

用非线性多因子动态组合方法作降水概率预报   总被引：1，自引：0，他引：1       下载免费PDF全文

邵明轩刘凤辉  程维中魏建明窦以文  陈大刚 《气象科技》2003,31(4):206-210

将逐时段定点降水预报这个以往一般作为非连续量处理的预报问题转化为对一个连续的降水可能函数的预报问题。降水可能函数为一由实况值确定的函数。因为现在模式变化较快，且许多因子和降水可能函数为非线性关系，文章采用一种新的非线性多因子动态组合方法，通过对降水可能函数的预报，作客观分站降水概率预报。  相似文献   

日照市短时冰雹定时-定点-定量预报          下载免费PDF全文

王繁强陆桂荣  周秀君张文琴 于怀征 《气象科技》2003,31(4):220-222

利用1960～2000年青岛、射阳、徐州3站08时探空资料及日照站08时地面气象资料，分析了日照地区出现的16次降雹天气的时空分布特征，在对降雹天气分型的基础上利用积云数值模式计算降雹因子，用降雹因子和单站要素因子建立历史降雹因子个例库，用历史实况资料建立实况个例库，用距离相似法实现日照地区短时冰雹定时、定点、定量的客观预报。  相似文献