Interactions among metals in the spectrochemical determination of trace amounts of cadmium in marine mussels     

A. Mazzucotelli  A. Viarengo  G. Martino  R. Frache 《Marine environmental research》1988,24(1-4)

The determination of trace amounts of inorganic elements by electrothermal atomic absorption spectrophotometry (ETA-AAS) or inductively coupled plasma atomic emission spectrometry (ICP-AES) suffers from some kinds of interference due to the inorganic fraction of the matrix of many environmental samples. The ratio between a major matrix element and the analyzed trace element plays an important role in the spectrochemical behaviour of the latter. The resulting enhancing or depressing effect also gives rise to severe faults when the well known standard addition method (SAM) is used. The present work shows the interactions due to the presence of elements such as calcium, sodium, potassium, magnesium and iron during the spectrochemical determinations of trace amounts of cadmium in marine mussels. A possible liquid anion exchange extraction is suggested for the analysis of cadmium by ETA-AAS.  相似文献   

Sea-level, sediment supply and coastal changes: Examples from the coast of Ireland     

R.W.G. Carter  T.W. Johnston  J. McKenna  J.D. Orford 《Progress in Oceanography》1987,18(1-4)

Sediment supply and pre-existing shoreline morphology are crucial factors in controlling coastal changes due to sea-level rise. Using examples from both southeast and northeast Ireland, it can be shown that sea-level change may trigger a sequence of events which leads to both static and dynamic shoreline equilibrium. Cliff erosion and longshore sediment movement in east Co. Wexford has led to injection of sediment onto the shelf, and the growth, under both wave and tide regimes, of linear offshore shoals. These shoals now control the pattern of shoreline erosion and provide a template for possible stepwise evolution of the coast under any future sea-level rise. In contrast, the nearby coast of south Co. Wexford comprises a series of coarse clastic barriers moving monotonously onshore, via overwash processes. Here the behavior of the barrier is conditioned by the antecedent morphology of both the beach face and stream outlet bedforms. Finally, the rock platform coast of Co. Antrim presents a far more resistant shoreline to incident marine processes, yet even here there is strong evidence of present process control over so-called ‘raised’ platforms and embayments. It is concluded that coastal sediment supply and dynamics, together with coastal morphology and its interaction with waves, present a far more complex variety of sea-level indicators than is normally acknowledged.  相似文献   

Seasonal Variation in the Biomass of Marine Macrophyta from Greek Coasts     

S. Haritonidis    G. Nikolaidis  I. Tsekos 《Marine Ecology》1986,7(4):359-370

Abstract. The marine plant communities of the littoral zone in different biotopes of the Greek coasts were investigated in 1980-81. Seasonal distribution and variation of marine plant biomass were assessed. The communities of Cystoseira crinita and C. compressa were outstanding with maximum biomass during the summer months. Corallina officinalis and Pterocladia capillacea + Viva rigida communities predominated with maximum biomass in autumn and exhibited a decrease in winter, except in stressed biotopes. The species diversity and productivity of seaweeds along the Greek coasts are interpreted in relation to a number of environmental parameters.  相似文献   

Simulation of additive transport from the land surface on the basis of experimental data on heat transfer in the atmospheric surface layer     

V. P. Kukharets  H. G. Nalbandyan 《Izvestiya Atmospheric and Oceanic Physics》2006,42(3):313-318

A method is proposed to study the transport of a passive additive in the atmospheric surface layer with the use of the atmospheric transfer function. This method makes it possible to estimate the spatial distribution of the concentration of a passive additive in the atmospheric surface layer from the additive’s surface source without experimentally determining the vertical profile of the transport coefficient or without resorting to various hypotheses for the character of its behavior. The transfer function, which contains the information on the wind-field structure, can be obtained from simple one-point measurements of surface-and air-temperature fluctuations and from subsequent spectral processing of the data. The effects of the wind-velocity profile and turbulence on the spatial distribution of additive concentration are assessed. This method allows one to simplify experiments during development and verification of the models of atmospheric diffusion. This method may also be useful in emergency situations to predict the propagation of hazardous additives.  相似文献   

Baroclinic Buoyancy-Inertia Joint Stability Parameter     

Hideo Kawai 《Journal of Oceanography》2005,61(2):235-246

At present, the barotropic buoyant stability parameter has been derived from a vertical virtual displacement of a water parcel. The barotropic inertial stability parameter in the eccentrically cyclogeostrophic, basic current field was derived in 2003 from a horizontal cross-stream virtual displacement of a parcel. By expressing acceleration of a parcel due to a virtual displacement, which is arbitrarily sloping within a vertical section across the basic current, in terms of natural coordinates, we derived the vertical component of baroclinic buoyant stability parameter B ₂ ², the horizontal component of baroclinic inertial stability parameter I ₂ ², the baroclinic joint stability parameter J ², its buoyant component B ² and its inertial component I ². B ² is far greater than I ₂ ², and when neglecting relative vorticity except for vertical shear, a downward convex curve of J ² plotted against the slope of a virtual displacement follows a trend of B ² curve. If a parcel displaces along a horizontal surface or an isopycnal surface, however, B ² vanishes, and J ² becomes equal to I ². Actual parcel is apt to displace not only along the bottom slope, but also along the sea surface and an isopycnal interfacial surface, which is approximately equivalent to an isentropic surface, preferred by lateral mixing and exchange of momentum. Such actual displacement makes B ² vanishing, and grants I ² an important role. The present analysis of I ² examining effects due to curvature and horizontal and vertical shear vorticities are useful in deepening our understanding of baroclinic instability in actual oceanic streams.  相似文献   

Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar)     

Yosuke Fujii 《Journal of Oceanography》2005,61(1):167-181

I present the derivation of the Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar), which is developed for adopting a non-diagonal background error covariance matrix in nonlinear variational analyses (i.e., analyses employing a non-quadratic cost function). POpULar is based on the idea of a linear preconditioned conjugate gradient method widely adopted in ocean data assimilation systems. POpULar uses the background error covariance matrix as a preconditioner without any decomposition of the matrix. This preconditioning accelerates the convergence. Moreover, the inverse of the matrix is not required. POpULar therefore allows us easily to handle the correlations among deviations of control variables (i.e., the variables which will be analyzed) from their background in nonlinear problems. In order to demonstrate the usefulness of POpULar, we illustrate two effects which are often neglected in studies of ocean data assimilation before. One is the effect of correlations among the deviations of control variables in an adjoint analysis. The other is the nonlinear effect of sea surface dynamic height calculation required when sea surface height observation is employed in a three-dimensional ocean analysis. As the results, these effects are not so small to neglect.  相似文献   

Numerical Simulation of Wind Currents and Propagation of Impurities in the Balaklava Bay     

V. V. Fomin  L. N. Repetin 《Physical Oceanography》2005,15(4):232-246

We present the results of numerical experiments aimed at the simulation of the circulation of waters and transport of impurities in the Balaklava Bay for typical wind conditions established on the basis of the analysis of the data of in-situ measurements. The currents are computed by using the nonlinear σ-coordinate model. The specific features of the integral circulation and three-dimensional structure of the current field are investigated. The statistical characteristics of currents are estimated on the basis of the in-situ data on winds and model calculations. Possible scenarios of propagation of impurities from the coastal sources are analyzed for various hydrodynamic conditions. It is shown that the localized eddy structures in the current fields (in combination with the zones of intense vertical motion) can result in a complex character of the transport of substances in the bay and lead to the formation of local regions of maximum concentrations of impurities on the boundary of the north and central parts of the bay. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 43–58, July–August, 2005.  相似文献   

Swimming endurance of haddock (Melanogrammus aeglefinus L.) at prolonged and sustained swimming speeds, and its role in their capture by towed fishing gears     

Breen  Mike; Dyson  Jamie; O'Neill  Finbarr G.; Jones  Emma; Haigh  Michael 《ICES Journal of Marine Science》2004,61(7):1071-1079

  相似文献   

Probing molecular-level transformations of dissolved organic matter: insights on photochemical degradation and protozoan modification of DOM from electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry     

Elizabeth B. Kujawinski  Rossana Del Vecchio  Neil V. Blough  Geoffrey C. Klein  Alan G. Marshall   《Marine Chemistry》2004,92(1-4):23

Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.  相似文献   

Temperature fluctuations in the atmospheric surface layer over the thermally inhomogeneous underlying surface     

V. P. Kukharets  H. G. Nalbandyan 《Izvestiya Atmospheric and Oceanic Physics》2006,42(4):456-462

The influence of both spatial and temporal temperature inhomogeneities of the underlying surface on the temperature field in an unstably stratified atmospheric surface layer is considered. The methods of correlation and spectral analyses are proposed to estimate statistical characteristics of surface-air temperature fluctuations caused by both turbulent mixing and inhomogeneities in the temperature of the underlying surface. Analysis of experimental data obtained from measurements in the atmospheric surface layer yields estimates for the contribution made by the time-dependent thermal properties of the underlying surface to the total variance of air-temperature fluctuations. It is shown that the additional air-temperature fluctuations generated by surface-temperature inhomogeneities and unrelated to shear flow may reach 70% and 30% of the total variance of measured fluctuations under variable cloudiness and clear skies, respectively. For the height z = 2 m within the wave-number range 2 × 10^?3 rad m^?1 < k < 0.1 rad m^?1, the contribution made by a spatial surface-temperature inhomogeneity to the variance of air-temperature fluctuations does not exceed 10% of the total variance. Correlation and spectral analyses of experimental data make it possible to isolate the spectra of properly turbulent fluctuations from the measured fluctuations and thus to obtain more accurate values of the universal function of similarity theory for temperature in the range of small wave numbers beyond the inertial range.  相似文献