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31.
Structural investigations, especially on quartz c-axis fabrics, combined with petrological work, were carried out in Precambrian rocks from the basement outcrops Bir Safsaf, Gebel el Asr und Gebel Umm Shâghir in the Western Desert in SW Egypt. The principal rock types are migmatites with local mylonite zones. The foliation and shear planes strike WNW-ESE, the axes of the wide and open folds NE-SW to N-S. Investigation of recrystallization features and mineral parageneses lead to P–T-estimates for the different stages of the metamorphic evolution. They range from early granulite facies down to greenschist facies. Quartz-c-axis fabrics of the migmatites and mylonites are similar (crossed-girdle fabrics) but they have a different regional orientation of the strain ellipsoid. Shear zones developed after the main migmatite facies event. The geological evolution of the basement outcrops in Bir Safsaf, Gebel el Asr and Gebel Umm Shâghir is comparable and the whole region is thought to be part of the East Sahara Craton.
Zusammenfassung Strukturuntersuchungen, besonders Quarz-c-Achsen-Regelungen, kombiniert mit petrologischen Arbeiten, wurden an Gesteinen der präkambrischen Grundgebirgsaufschlüsse Bir Safsaf, Gebel el Asr und Gebel Umm Shâghir in der Western Desert, ägypten, durchgeführt. Die hauptsächlich auftretenden Gesteinstypen sind Migmatite mit lokalen Mylonitzonen. Schieferungs- und Scherflächen streichen WNW-ESE, die Achsen der weiten bis offenen Faltung NE-SW bis N-S. Mit Hilfe des Rekristallisationsverhaltens und der Paragenesen werden P-T-Abschätzungen der Metamorphosestadien angegeben. Sie reichen von früher Granulitfazies bis zu später Grünschieferfazies. Die Quarz-c-Achsenregelung in Migmatiten und Myloniten ist ähnlich (Kreuzgürtelregelung), jedoch mit unterschiedlicher regionaler Orientierung des Strainellipsoids. Scherzonen entwickelten sich nach dem migmatitfaziellen Hauptmetamorphose-Ereignis. Die geologische Entwicklung in den Grundgebirgsaufschlüssen von Bir Safsaf, Gebel el Asr und Gebel Umm Shâghir ist vergleichbar und das gesamte Gebiet wird als Teil des Ostsaharakratons angesehen.

Résumé Cette note fait état des résultats de recherches menées dans les aires d'affleurement du socle pré-cambrien de Bir Safsaf, du Jebel al Asr et du Jebel Umm Shâghir, dans le désert occidental d'Egypte; ces recherches ont consisté en l'étude des structures, particulèrement des fabriques des axes c du quartz, combinée avec une étude pétrologique. Les roches sont essentiellement des migmatites accompagnées de zones de mylonites locales. La schistosité et les plans de cisaillement y sont orientés WNW-ESE; elles présentent des plis ouverts dont les axes sont NE-SW à N-S. L'étude des structures de recristallisation et des paragenèses minérales fournit une estimation des conditions (p,t) au cours des stades successifs de l'évolution métamorphique. Ces conditions s'échelonnent du faciès des granulites jusqu'à celui des schistes verts. Les fabriques des axes c du quartz sont les mÊmes dans les migmatites et les mylonites (fabrique à «ceintures croisées»), mais ces roches présentent des orientations régionales différentes de l'ellipsoÏde des déformations. L'événement métamorphique principal à caractère migmatitique a été suivi de la formation de couloirs de cisaillement (shear-zones). L'évolution géologique du socle est comparable dans les trois aires étudiées; l'ensemble est considéré comme faisant partie du craton du Sahara oriental.

, Bir Safsaf, Gebel el Asr Gebel Umm Shâghir, . . WNW-ESE, — NE-SW N-S. , . . / Kreuzgü rtelregelung /, . . Bir Safsaf, Gebel el Asr Gebel Umm Shaghir , .
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This paper analyses long-term (1951–2000) phenological observations of20 plant seasonal phases recorded within the phenological network of the German Weather Service in relation to climate data and NAO. Phenological inter-annual variability and temporal trends were determined by using mean anomaly curves for Germany. For all phases, the mean trends derived by this method are similar to German averages of linear trends of single station records. Trend analysis using anomaly curves appears to be effective in relating seasonal phenological trends to climate or satellite data: Spring and summer phenological anomalies, such as leaf unfolding and flowering of different species, strongly correlate with temperature of the preceding months (R2 between 0.65 and 0.85, best one-variable model) andtheir onsets have advanced by 2.5 to 6.7 days per ° C warmer spring. Fruit ripening of Sambucus nigra and Aesculus hippocastanum, keyphenophases of early and mid autumn, correlate well with summer temperature (R2 0.74 and 0.84) and also advance by 6.5and 3.8 days per ° C (April–June). But the response of autumn colouringto warmer climate is more complex because two opposing factors influence autumn colouring dates. Higher spring and early summer temperatures advance leaf colouring, whereas warmer autumn temperatures delay leaf colouring. The percentage of variance explained by temperature (R2 0.22 to 0.51,best one-variable model) is less than for spring and summer phases. The length of the growing season is mainly increased by warmer springs (R2 0.48to 0.64, best one-variable model) and lengthened by 2.4 to 3.5 days/° C (February–April). The North Atlantic Oscillation Index (NAO) of January–March correlates with spring phenological anomalies(R2 0.37 to 0.56, best one-variable model), summer to mid autumn phases respond to NAO of February–March (R2 0.23 to 0.36) (both negativecorrelations). Leaf colouring is delayed by higher NAO of (August) September (R2 0.10to 0.18). NAO of January–February explains 0.41 to 0.44% of thevariance of the length of the growing season.  相似文献   
34.
Phenology: Its Importance to the Global Change Community   总被引:10,自引:0,他引:10  
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35.
Prediction of colloid release and transport as affected by reactive species remains a significant challenge for field applications. In this paper, we report experimental and modeling results of ferrihydrite colloid release under the influence of citrate species. Using a 3-plane surface complexation model, equilibrium constants were obtained for the three proposed inner-sphere complexes by fitting a citrate adsorption isotherm on ferrihydrite at pH 4, and a pH adsorption envelop with 0.64 mM citrate. The constants were used in a reactive transport model for simulating reaction fronts of dissolved species during injection of citrate in ferrihydrite-coated quartz columns. Simulation results show that sorption alone may not adequately describe the breakthrough curves. Inclusions of ferrihydrite dissolution and re-adsorption of Fe(III) improve the prediction of dissolved species transport. Additionally, matrix diffusion may be needed for improved prediction. For the release of colloidal iron oxides it was shown that both oxide dissolution and interfacial repulsion controlled the process during complete breakthrough. However, the peak release of colloids, which occurred during the actual breakthrough of dissolved species, was mainly brought about by electric double layer forces. These particles underwent detachment-deposition-detachment cycles along the flow path, and emerged in the effluent with the major reaction front. To quantitatively predict colloid release, a semi-empirical linear correlation was established, linking the calculated electric potential to experimental colloid release rates. The model may be applied to the prediction and scaling of aquifer remediation studies involved in the injection of organic ligands to mobilize particle bound contaminants.  相似文献   
36.
The Sb speciation in soil samples from Swiss shooting ranges was determined using Sb K-edge X-ray absorption spectroscopy (XAS) and advanced statistical data analysis methods (iterative transformation factor analysis, ITFA). The XAS analysis was supported by a spectral data set of 13 Sb minerals and 4 sorption complexes. In spite of a high variability in geology, soil pH (3.1-7.5), Sb concentrations (1000-17,000 mg/kg) and shooting-range history, only two Sb species were identified. In the first species, Sb is surrounded solely by other Sb atoms at radial distances of 2.90, 3.35, 4.30 and 4.51 Å, indicative of metallic Sb(0). While part of this Sb(0) may be hosted by unweathered bullet fragments consisting of PbSb alloy, Pb LIII-edge XAS of the soil with the highest fraction (0.75) of Sb(0) showed no metallic Pb, but only Pb2+ bound to soil organic matter. This suggests a preferential oxidation of Pb in the alloy, driven by the higher standard reduction potential of Sb. In the second species, Sb is coordinated to 6 O-atoms at a distance of 1.98 Å, indicative of Sb(V). This oxidation state is further supported by an edge energy of 30,496-30,497 eV for the soil samples with <10% Sb(0). Iron atoms at radial distances of 3.10 and 3.56 Å from Sb atoms are in line with edge-sharing and bidentate corner-sharing linkages between Sb(O,OH)6 and Fe(O,OH)6 octahedra. While similar structural units exist in tripuhyite, the absence of Sb neighbors contradicts formation of this Fe antimonate. Hence the second species most likely consists of inner-sphere sorption complexes on Fe oxides, with edge and corner-sharing configuration occurring simultaneously. This pentavalent Sb species was present in all samples, suggesting that it is the prevailing species after weathering of metallic Sb(0) in oxic soils. No indication of Sb(III) was found.  相似文献   
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Facies architecture and platform evolution of an early Frasnian reef complex in the northern Canning Basin of north‐western Australia were strongly controlled by syn‐depositional faulting during a phase of basin extension. The margin‐attached Hull platform developed on a fault block of Precambrian basement with accommodation largely generated by movement along the Mount Elma Fault Zone. Recognition of major subaerial exposure and flooding surfaces in the Hull platform (from outcrop and drillcore) has enabled comparison of facies associations within a temporal framework and led to identification of three stages of platform evolution. Stage 1 records initial ramp development on the hangingwall dip slope with predominantly deep subtidal conditions that prevented any cyclic facies arrangements. This stage is characterised by basal siliciclastic deposits and a major deepening‐upward facies pattern that is capped by a sequence boundary towards the footwall (north‐west) and a major flooding surface towards the hangingwall. Stage 2 reflects the bulk of platform aggradation, significant platform growth towards the hangingwall and the development of reef margins and cyclic facies arrangements. Thickening of this stage towards the hangingwall indicates that accommodation was generated by rotation of the fault block and overlying platform. Stage 3 records a major flooding and backstep of the platform margin. The Hull platform illustrates important elements of margin‐attached carbonate platforms in a half‐graben setting, including: (i) prominent, but limited, coarse siliciclastic input that does not have a major detrimental effect on carbonate production near the rift margin in arid to semi‐arid settings; (ii) wedge‐shaped accommodation created by syn‐depositional rotation of fault blocks and tilting of the hangingwall dip slope, resulting in shallow‐water facies and subaerial exposure up‐dip of the rotational axis and deeper water facies down‐dip; and (iii) evolution of a ramp to rimmed shelf, coincident with a sequence boundary–flooding surface, that is accelerated by tilting of the hangingwall dip slope during fault‐block rotation.  相似文献   
40.
Epistemic uncertainties arise during the estimation of hydraulic gradients in unconfined aquifers due to planar approximation of the water table as well as data gaps arising from factors such as instrument failures and site inaccessibility. A multidimensional fuzzy least-squares regression approach is proposed here to estimate hydraulic gradients in situations where epistemic uncertainty is present in the observed water table measurements. The hydraulic head at a well is treated as a normal (Gaussian) fuzzy variable characterized by a most likely value and a spread. This treatment results in hydraulic gradients being characterized as normal fuzzy numbers as well. The multidimensional fuzzy least-squares regression has an exact analytical form and as such can be implemented easily using matrix algebra methods. However, the method was noted to be sensitive to round-off and truncation errors when the epistemic uncertainties are small. A closeness index based on the cardinality of a fuzzy number is used to evaluate how well the regression model fits the fuzzy hydraulic head observations. A fuzzy Euclidian distance measure is used to compare two fuzzy numbers and to evaluate how fuzziness in the observed hydraulic heads affects the fuzziness in the estimated hydraulic gradients. The Euclidian distance measure is also used to ascertain the influence of each well on the fuzzy hydraulic gradient estimation. The fuzzy regression framework is illustrated by applying it to evaluate hydraulic gradients in the unconfined portion of the Gulf Coast aquifer in Goliad County, TX. The results from the case-study indicate that there is greater uncertainty associated with the estimation of the hydraulic gradients in the vertical (Z-axis) direction. The epistemic uncertainties in the hydraulic head data at the wells have a significant impact on the gradient estimates when they are of the same order of magnitude as the most likely values of the observed heads. The influence analysis indicated that 5 of the 13 wells in the network had a critical influence on at least one of the hydraulic gradients. Three wells along the northeastern section of the study area and bordering the Victoria County were noted to have the least influence on the regression estimates. The fuzzy regression framework along with the associated goodness-of-fit and influence measures provides a useful set of tools to characterize the uncertainties in the hydraulic heads and gradients arising from data gaps and planar water table approximation.  相似文献   
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