Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites     

David T. Adamson PhD  PE  Grayson Uhlir BS  Sharon R. Rauch BA  Tessa Klein BS  Anthony S. Danko PhD  PE 《Ground Water Monitoring & Remediation》2021,41(3):29-40

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.  相似文献   

The Centurion 18 telescope of the Wise Observatory     

Noah Brosch  David Polishook  Avi Shporer  Shai Kaspi  Assaf Berwald  Ilan Manulis 《Astrophysics and Space Science》2008,314(1-3):163-176

We describe the second telescope of the Wise Observatory, a 0.46-m Centurion 18 (C18) installed in 2005, which enhances significantly the observing possibilities. The telescope operates from a small dome and is equipped with a large-format CCD camera. In the last two years this telescope was intensively used in a variety of monitoring projects. The operation of the C18 is now automatic, requiring only start-up at the beginning of a night and close-down at dawn. The observations are mostly performed remotely from the Tel Aviv campus or even from the observer’s home. The entire facility was erected for a component cost of about 70k$ and a labor investment of a total of one man-year. We describe three types of projects undertaken with this new facility: the measurement of asteroid light variability with the purpose of determining physical parameters and binarity, the following-up of transiting extrasolar planets, and the study of AGN variability. The successful implementation of the C18 demonstrates the viability of small telescopes in an age of huge light-collectors, provided the operation of such facilities is very efficient.  相似文献   

Observable consequences of planet formation models in systems with close-in terrestrial planets     

Sean N. Raymond †‡  Rory Barnes  Avi M. Mandell †‡ 《Monthly notices of the Royal Astronomical Society》2008,384(2):663-674

To date, two planetary systems have been discovered with close-in, terrestrial-mass planets     . Many more such discoveries are anticipated in the coming years with radial velocity and transit searches. Here we investigate the different mechanisms that could form 'hot Earths' and their observable predictions. Models include: (1) in situ accretion; (2) formation at larger orbital distance followed by inward 'type 1' migration; (3) formation from material being 'shepherded' inward by a migrating gas giant planet; (4) formation from material being shepherded by moving secular resonances during dispersal of the protoplanetary disc; (5) tidal circularization of eccentric terrestrial planets with close-in perihelion distances and (6) photoevaporative mass-loss of a close-in giant planet. Models 1–4 have been validated in previous work. We show that tidal circularization can form hot Earths, but only for relatively massive planets     with very close-in perihelion distances (≲0.025 au), and even then the net inward movement in orbital distance is at most only 0.1–0.15 au. For planets of less than     , photoevaporation can remove the planet's envelope and leave behind the solid core on a Gyr time-scale, but only for planets inside 0.025–0.05 au. Using two quantities that are observable by current and upcoming missions, we show that these models each produce unique signatures, and can be observationally distinguished. These observables are the planetary system architecture (detectable with radial velocities, transits and transit timing) and the bulk composition of transiting close-in terrestrial planets (measured by transits via the planet's radius).  相似文献   

Historical and Modern Fluctuations of Lakes Tanganyika and Rukwa and Their Relationship to Rainfall Variability     

Sharon E. Nicholson 《Climatic change》1999,41(1):53-71

This paper describes the fluctuations of Lakes Tanganyika and Rukwa over the last two centuries. Lake chronologies extending back to the late eighteenth century are derived from reports of European visitors, settlers and explorers and from oral accounts of the local peoples. The historical fluctuations are meshed with the modern record to provide a picture of the lakes' fluctuations until the late twentieth century. The historical fluctuations of the lakes are quite similar. The most important of these are low levels during the first half of the nineteenth century, very high stands in the last decades of the nineteenth century, and, around the turn of the century, a rapid fall to twentieth century levels. This pattern is ubiquitous throughout eastern Africa and is apparent in numerous other lakes, including Victoria, Naivasha, Stefanie, Turkana, Malawi and Chilwa. Driest periods were in the 1920s or earlier and in the 1950s. Lake Tanganyika returned to extremely high stands in the 1960s and has continued to maintain relatively high stands since that time. Lake Rukwa rose to high stands during the 1980s and maintained them for several years. An analysis of rainfall variability shows that these trends are generally explained by variations in catchment rainfall. However, the lakes' responses to rainfall variability are sometimes dissimilar because Lake Rukwa is a closed basin. Our results demonstrate the complexity of the rainfall/lake-level relationships and the need to use water balance relationships in order to interpret the lakes' historical or paleo-fluctuations in terms of rainfall.  相似文献   

A multicatchment analysis of headwater and downstream temperature effects from contemporary forest harvesting          下载免费PDF全文

Kevin D. Bladon  Catalina Segura  Nicholas A. Cook  Sharon Bywater‐Reyes  Maryanne Reiter 《水文研究》2018,32(2):293-304

Stream temperature is a key physical water‐quality parameter, controlling many biological, chemical, and physical processes in aquatic ecosystems. Maintenance of cool stream temperatures during summer is critical for high‐quality aquatic habitat. As such, transmission of warm water from small, nonfish‐bearing headwater streams after forest harvesting could cause warming in downstream fish‐bearing stream reaches with negative consequences. In this study, we evaluate (a) the effects of contemporary forest management practices on stream temperature in small, headwater streams, (b) the transmission of thermal signals from headwater reaches after harvesting to downstream fish‐bearing reaches, and (c) the relative role of lithology and forest management practices in influencing differential thermal responses in both the headwater and downstream reaches. We measured summer stream temperatures both preharvest and postharvest at 29 sites—12 upstream sites (4 reference, 8 harvested) and 17 downstream sites (5 reference, 12 harvested)—across 3 paired watershed studies in western Oregon. The 7‐day moving average of daily maximum stream temperature (T_7DAYMAX) was greater during the postharvest period relative to the preharvest period at 7 of the 8 harvested upstream sites. Although the T_7DAYMAX was generally warmer in the downstream direction at most of the stream reaches during both the preharvest and postharvest period, there was no evidence for additional downstream warming related to the harvesting activity. Rather, the T_7DAYMAX cooled rapidly as stream water flowed into forested reaches ~370–1,420 m downstream of harvested areas. Finally, the magnitude of effects of contemporary forest management practices on stream temperature increased with the proportion of catchment underlain by more resistant lithology at both the headwater and downstream sites, reducing the potential for the cooling influence of groundwater.  相似文献   

B and Li isotopes as intrinsic tracers for injection tests in aquifer storage and recovery systems     

Wolfram Kloppmann  Haim Chikurel  Géraldine Picot  Joseph Guttman  Marie Pettenati  Avi Aharoni  Catherine Guerrot  Romain Millot  Irina Gaus  Thomas Wintgens 《Applied Geochemistry》2009

Boron and Li isotopes have been tested as environmental tracers of treated sewage injected into a sandy aquifer (Shafdan reclamation project, Israel). During a 38 days injection test in a newly dug injection well, a conservative artificial tracer (Br⁻) was monitored together with δ¹¹B and δ⁷Li in the injectate, in the unsaturated soil zone (porous cup) and an observation well in the aquifer. In spite of B and Li concentrations in the injectate close to background values, significant shifts of the isotope signatures could be observed over the duration of the injection test. Boron isotope ratios show a breakthrough curve delayed with respect to Br⁻ breakthrough due to some reversible sorption on the aquifer material. No isotope fractionation was observed in the unsaturated or the saturated zone so that B isotopes can be considered as conservative in the investigated part of the aquifer system. Lithium isotopes are strongly fractionated, probably due to sorption processes. Lithium concentrations point to a Li sink in the system, δ⁷Li values vary strongly with a tendency of ⁷Li depletion in the liquid phase over the duration of the experiment. This is opposite to the expected preferential sorption of ⁶Li onto clay minerals. Boron isotopes reveals a valuable tracer of artificial recharge of freshwaters derived from treated sewage, both for short term tracer tests and for long-term monitoring of artificial recharge, even if in aquifers with higher clay contents, sorption-linked isotope fractionation cannot be excluded. More data are needed on Li isotope fractionation in natural groundwater systems to assess the potential of this tracer as monitoring tool.  相似文献   

Reproductive characteristics and steroid levels in the scleractinian coral Oculina patagonica inhabiting contaminated sites along the Israeli Mediterranean coast     

Armoza-Zvuloni R  Kramarsky-Winter E  Rosenfeld H  Shore LS  Segal R  Sharon D  Loya Y 《Marine pollution bulletin》2012,64(8):1556-1563

In this study we compared reproductive characteristics and steroid hormone levels in the non-indigenous scleractinian coral, Oculina patagonica, inhabiting contaminated vs. uncontaminated reference sites along the Israeli Mediterranean coast. Our results indicate significantly higher steroid levels in both seawater and coral tissue samples from contaminated sites as compared to reference sites, suggesting that corals tend to accumulate steroids from the surrounding waters. Despite their higher steroid levels, corals from the contaminated sites showed reproductive potential comparable to those of the reference sites. Interestingly, a clear distinction could be seen between corals exposed to pollution for long vs. short durations, with the latter showing a failure to complete gametogenesis. This suggests that reproduction in O. patagonica is susceptible to acute rather than chronic stress. The involvement of adjustment/adaptation processes may explain this species tolerance, and may reflect the ability of O. patagonica to successfully invade new areas in the Mediterranean Sea.  相似文献   

Archeoseismic study of damage in Roman and Medieval structures in the center of Cologne, Germany     

Klaus-G. Hinzen  Stephan Schreiber  Claus Fleischer  Sharon K. Reamer  Isabel Wiosna 《Journal of Seismology》2013,17(2):399-424

The causes of damage observed in archeological records or preserved monuments are often difficult to be determined unequivocally, particularly when the possibility of secondary earthquake damage exists. Such secondary damage has been previously proposed for the Roman Praetorium, the governor’s palace in the center of Cologne. Ongoing excavations since 2007 revealed additional damage. The existing ground that has been uncovered and documented extends the affected area to 175?×?180 m. We present a comprehensive virtual model of the excavation area based on 200 3D laserscans together with a systematic analysis of the damage patterns and an improved model of the terrain during Roman/Medieval times including geotechnical parameters of the subsurface. Five locations with different damage patterns, including a Roman sewer, the octagonal central part of the Praetorium, a section with strongly inclined massive walls, a 13 m deep deformed well, a collapsed hypocaust, and damages in the Medieval mikveh are analyzed in detail. We use site-specific synthetic strong ground motion seismograms to test the possibility of earthquake-induced ground failures as a cause for the observed damage. This subsurface model is also used to test the possibility of hydraulically-induced damages by seepage and erosion of fine-grained material from stray sand. Heavy rainstorms can induce a direct stream of surface water through the fine sand layers to the ground water table. Simulated ground motion for assumed worst-case earthquake scenarios do not provoke slope instability at the level necessary to explain the structural damages.  相似文献   

Source distribution of ocean microseisms and implications for time-dependent noise tomography     

Sharon Kedar 《Comptes Rendus Geoscience》2011,343(8-9):548-557

A qualitative analysis of ocean microseism source distribution observed in North America during fall and winter months was carried out. I review the theory of the origin of ocean microseisms and show that it can be used in conjunction with wave-wave interaction maps to quantify the source distribution anisotropy. It is demonstrated that microseisms generation in the North Atlantic and in the North Pacific Oceans are inherently different. North Atlantic microseisms are generated predominantly in the deep ocean, while North Pacific microseisms are dominated by coastal reflections. In spite of these differences both result from repeated ocean wave patterns that give rise to an anisotropic noise pattern, which cannot be randomized by time averaging. Considering time-varying ambient noise imaging, which aims to resolve a fraction of a percent changes in the crust over short distances, the source anisotropy would introduce a relatively significant error that needs to be accounted for.  相似文献   

Effect of excavation stages on stress and pore pressure changes for an underground nuclear repository   总被引：2，自引：0，他引：2  

A. K. Verma  M. S. Saini  T. N. Singh  Avi Dutt  R. K. Bajpai 《Arabian Journal of Geosciences》2013,6(3):635-645

This paper provides a brief overview of evolution of deformations, stresses, and pore pressures due to different excavation stages during construction of an URL. Excavation of a rockmass develops damage zone of finite width around the excavated zone which is associated with changes in permeability and affect the fluid flow mechanism. In this study, a coupled hydromechanical (HM) analysis for a water saturated porous rock mass has been done which is caused by sequential excavation and backfill of vertical disposal pit of an URL. For this purpose, an Atomic Energy of Canada Limited’s in-floor concept for a deep geologic repository suitable for Indian condition has been used. Changes in rock deformations, stresses, strains and mechanically induced pore pressure in an undrained condition, during excavation, as well as those caused by mechanically induced rock deformations after backfill of the disposal pit have been modeled. A three-dimensional finite difference tool FLAC^3D (Itasca Consulting Group Inc. FLAC-3D 1997) has been used for the analysis.  相似文献