Phase changes and thermodynamic properties of CaTiO3. Spectroscopic data,vibrational modelling and some insights on the properties of MgSiO3 perovskite     

Philippe Gillet  François Guyot  Geoffrey D. Price  Benoit Tournerie  Andrée Le Cleach 《Physics and Chemistry of Minerals》1993,20(3):159-170

The effect of pressure (up to 21 GPa at room temperature) and temperature (up to 1570 K at room pressure) on the Raman spectrum of CaTiO₃ is presented. No significant changes, which could be attributed to a major structural change, are observed in the spectra up to 22 GPa. The pressure shifts of the Raman modes can be related to a significant compression of the Ti-O bond. Discontinuous changes in the spectra upon heating may be related to phase changes observed by calorimetry and X-ray diffraction. The important temperature shifts of some low-frequency modes can be related to an increase in the Ti-O-Ti angle in agreement with the X-ray data showing a decrease of the structural distortion with increasing temperature. These data are compared to those available for MgSiO₃-perovskite and show that CaTiO₃ is a good structural analogue for MgSiO₃-perovskite. The present spectroscopic data are used to calculate the specific heat and entropy of CaTiO₃. The role of the low frequency modes in the calculations is emphasized. Good agreement is observed between calculated and experimentally determined values in the 0–1300 K temperature range. A similarly defined model is proposed for MgSiO₃-perovskite. It is found that the entropy lies between 57 and 64 J/mol/K at 298 K and between 190 and 200 J/mol/K at 1000 K in agreement with the values inferred from experimental equilibrium data. Finally we briefly discuss the values of the Grüneisen parameters of both perovskites inferred from macroscopic and microscopic data.  相似文献   

Experimental calibration of lake-sediment spectral reflectance to chlorophyll a concentrations: methodology and paleolimnological validation   总被引：1，自引：0，他引：1  

Alexander P. Wolfe  Rolf D. Vinebrooke  Neal Michelutti  Benoit Rivard  Biplob Das 《Journal of Paleolimnology》2006,36(1):91-100

Chlorophyll a preserved in lake sediments reflects, in part, past primary production. This study assesses the spectral properties of sedimentary chlorophyll a using visible-near infrared reflectance (VNIR) spectroscopy, with the objective of establishing a new, non-destructive paleolimnological proxy. Reflectance spectra were determined from a dilution series (n = 10) involving incremental additions of pulverized modern algae to a lake sediment matrix of low organic content. This enabled an assessment of the development of sediment reflectance spectra in relation to different sediment chlorophyll a concentrations, and subsequent regression of spectral features against measured concentrations of chlorophyll a and derivatives obtained by high performance liquid chromatography (HPLC). The experiment demonstrates that ubiquitous troughs in sediment reflectance near 675 nm are attributable to chlorophyll a and derivative compounds. A significant correlation (r ² = 0.98, P < 0.01) was obtained between the area of the reflectance trough in the 650–700 nm interval and summed concentrations of chlorophyll a, all derivative isomers, and degradational pheopigments. A simple linear inference model derived from this experiment was applied to a down-core sequence of VNIR spectra from a productive prairie lake (Alberta, Canada), where it produced inferred sediment chlorophyll a concentrations in concordance with HPLC measurements. Although a larger training set is desirable to further refine the inference model, the analyses reported here demonstrate that reflectance spectroscopy provides a rapid, semi-quantitative method for assessing the chlorophyll a content of lake sediments.  相似文献   

Lithospheric controls on the formation of provinces hosting giant orogenic gold deposits   总被引：10，自引：0，他引：10  

Frank P. Bierlein  David I. Groves  Richard J. Goldfarb  Benoit Dubé 《Mineralium Deposita》2006,40(8):874-886

Ages of giant gold systems (>500 t gold) cluster within well-defined periods of lithospheric growth at continental margins, and it is the orogen-scale processes during these mainly Late Archaean, Palaeoproterozoic and Phanerozoic times that ultimately determine gold endowment of a province in an orogen. A critical factor for giant orogenic gold provinces appears to be thickness of the subcontinental lithospheric mantle (SCLM) beneath a province at the time of gold mineralisation, as giant gold deposits are much more likely to develop in orogens with subducted oceanic or thin continental lithosphere. A proxy for the latter is a short pre-mineralisation crustal history such that thick SCLM was not developed before gold deposition. In constrast, orogens with protracted pre-mineralisation crustal histories are more likely to be characterised by a thick SCLM that is difficult to delaminate, and hence, such provinces will normally be poorly endowed. The nature of the lithosphere also influences the intrinsic gold concentrations of potential source rocks, with back-arc basalts, transitional basalts and basanites enriched in gold relative to other rock sequences. Thus, segments of orogens with thin lithosphere may enjoy the conjunction of giant-scale fluid flux through gold-enriched sequences. Although the nature of the lithosphere plays the crucial role in dictating which orogenic gold provinces will contain one or more giant deposits, the precise siting of those giants depends on the critical conjunction of a number of province-scale factors. Such features control plumbing systems, traps and seals in tectonically and lithospherically suitable terranes within orogens.  相似文献   

On a Non-local Parameterisation for Shear Turbulence and the Uniqueness of its Solutions     

Benoit Cushman-Roisin  Alastair D. Jenkins 《Boundary-Layer Meteorology》2006,118(1):69-82

A non-local parameterisation of shear turbulence is proposed, which includes a dimensionless multiplicative constant as the sole tunable parameter. Analytical and numerical solutions in the case of plane Couette flow exhibit sheared velocity profiles with logarithmic behaviour near the boundaries, and the classical logarithmic flow profile is reproduced for a semi-infinite domain. We also prove that the families of analytical solutions obtained are locally unique: if the velocity is a strictly-increasing function of the distance from the boundary, a small perturbation of the velocity profile must be of the same functional form as the basic flow.  相似文献   

Observations of the Sunyaev–Zel''dovich effect at high angular resolution towards the galaxy clusters A665, A2163 and CL0016+16     

F.-X. Désert  A. Benoit  S. Gaertner  J.-P. Bernard  N. Coron  J. Delabrouille  P. de Marcillac  M. Giard  J.-M. Lamarre  B. Lefloch  J.-L. Puget  A. Sirbi 《New Astronomy》1998,3(8):1073-669

We report on the first observation of the Sunyaev–Zel'dovich (SZ) effect, a distortion of the Cosmic Microwave Background radiation (CMB) by hot electrons in clusters of galaxies, with the Diabolo experiment at the IRAM 30 m telescope. Diabolo is a dual-channel 0.1 K bolometer photometer dedicated to the observation of CMB anisotropies at 2.1 and 1.2 mm. A significant brightness decrement in the 2.1 mm channel is detected in the direction of three clusters (Abell 665, Abell 2163 and CL0016+16). With a 30 arcsec beam and 3 arcmin beamthrow, this is the highest angular resolution observation to date of the SZ effect. Interleaving integrations on targets and on nearby blank fields have been performed in order to check and correct for systematic effects. Gas masses can be directly inferred from these observations.  相似文献   

Hyperspectral core logging for fire reconstruction studies     

Antonin Van Exem  Maxime Debret  Yoann Copard  Boris Vannière  Pierre Sabatier  Stephane Marcotte  Benoit Laignel  Jean-Louis Reyss  Marc Desmet 《Journal of Paleolimnology》2018,59(3):297-308

Lacustrine sediments contain a wide range of proxies that enable paleoenvironmental reconstructions. For instance, charcoal can be used to document past fire regime changes. In order to analyse high-temporal- and spatial-resolution records, however, it is necessary to develop fast, low-cost and high-stratigraphic-resolution methods. We developed a new paleo-fire proxy by studying a lacustrine core from the Esterel Massif, SE France, an area affected by two recent fire events, in AD 1987 and 2003. For this purpose, we searched for charcoal deposited and preserved in the lake sediments by combining a number of complementary methods, including: classic macrocharcoal tallying, scanning spectrophotometry, scanning hyperspectral imaging and high pressure liquid chromatography analyses. Macrocharcoal quantification is efficient, but time-consuming, and only provides intermediate-resolution data (cm scale). Spectrophotometry, used classically to quantify colour, is very fast, provides high-resolution data (4 mm) and is non-destructive (core preservation). Hyperspectral data have the same advantages as spectrophotometry, but offer higher spatial resolution (64-µm pixel size) and higher spectral resolution (6 nm) for core logging applications. The main result of this research is based on hyperspectral analysis at very high stratigraphic resolution using the I-band index. This index usually measures reflectance values at [660, 670 nm] corresponding to the trough in red reflectance produced by Chlorophyll a and its diagenetic products. This [660, 670 nm] reflectance trough, however, is also affected by the presence of altered organic matter and decreases with altered organic matter such as charcoal particles. Charcoal effect on the reflectance of Chlorophyll a and its diagenetic products is identified on first derivative spectra by a characteristic pattern around 675 nm, which is also in agreement with the Chlorophyll a concentrations measured by high-pressure liquid chromatography and charcoal particles. The I-band index is hence suitable for detecting burned organic matter, by quantifying the dilution of the chlorophyll signal by the charcoal signal. Thus, this adaptation of the I-band index can be applied in fire reconstruction studies.  相似文献   

The Kansas University meteorit     

D. m. Schneider  P. h. Benoit  D. w. g. Sears  A. j. t. Jull 《Meteoritics & planetary science》1997,32(Z4):A149-A150

Abstract— A new 2.8 kg meteorite find from the United States, Kansas University, is classified as an L6 (S3) chondrite based on optical microscopy and electron microprobe analysis of mafic minerals. Natural thermo-luminescence (TL) and ¹⁴C measurements suggest that the Kansas University meteorite has a short terrestrial age compared to other meteorite finds from this area and is not paired with the other local meteorite finds, Densmore (1879), Lawrence, Kansas and Long Island, Kansas.  相似文献   

Complete metamorphic cycle and long-lived anatexis in the c. 2.1 Ga Mistinibi Complex,Canada     

Antoine Godet  Carl Guilmette  Loic Labrousse  Donald W. Davis  Matthijs A. Smit  Jamie A. Cutts  Marc-Antoine Vanier  Isabelle Lafrance  Benoit Charette 《Journal of Metamorphic Geology》2020,38(3):235-264

Secular changes in the architecture, thermal state, and metamorphic style of global orogens are thought to have occurred since the Archean; however, despite widespread research, the driving mechanisms for such changes remain unclear. The Paleoproterozoic may prove to be a key era for investigating secular changes in global orogens, as it marks the earliest stage of an eon that saw the onset of modern-style global tectonics. The 2.1 Ga granulite-facies Mistinibi-Raude Domain (MRD), located in the Southeastern Churchill Province, Canada, offers a rare exposure of Paleoproterozoic high metamorphic grade supracrustal sequences (Mistinibi Complex, MC). Rocks from this domain were subjected to petrochronological investigations to establish P–T–t–X evolutions and to provide first order thermal state, burial and exhumation rates, and metamorphic gradients for the transient Paleoproterozoic times. To obtain comprehensive insight into the P–T–t–X evolution of the MRD, we used multi-method geochronology—Lu–Hf on garnet and U–Pb on zircon and monazite—integrated with detailed petrography, trace element chemistry, and phase equilibria modelling. Despite the extensive use of zircon and monazite as geochronometers, their behaviour in anatectic conditions is complex, leading to substantial ambiguity in interpreting the timing of prograde metamorphism. Our results indicate a clockwise metamorphic path involving significant melt extraction from the metasedimentary rocks, followed by cooling from >815°C to ~770°C at ~0.8 GPa. The timing of prograde burial and cooling from supra- to subsolidus conditions is constrained through garnet, monazite, and zircon petrochronology at 2,150–2,120 Ma and at 2,070–2,080 Ma, respectively. These results highlight long-lived residence of the rocks at mid-crustal supra-solidus conditions (55–70 Ma), with preserved prograde and retrograde supra-solidus monazite and zircon. The rocks record extremely slow burial rates (0.25–0.30 km/Ma) along a high metamorphic gradient (900–1,000°C/GPa), which appears symptomatic of Paleoproterozoic orogens. The MC did not record any significant metamorphism after 2,067 Ma, despite having collided with terranes that record high-grade metamorphism during the major 1.9–1.8 Ga Trans-Hudson orogeny. The MC would therefore represent a remnant of a local early Paleoproterozoic metamorphic infrastructure, later preserved as superstructure in the large hot Trans-Hudson orogen.  相似文献   

NMR relaxation of neritic carbonates: An integrated petrophysical and petrographical approach     

Benoit Vincent  Marc Fleury  Yannick Santerre  Benjamin Brigaud 《Journal of Applied Geophysics》2011,74(1):38-58

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Trophic importance of diatoms in an intertidal Zostera noltii seagrass bed: Evidence from stable isotope and fatty acid analyses     

Benoit Lebreton  Pierre Richard  Robert Galois  Gilles Radenac  Camille Pfléger  Gaël Guillou  Françoise Mornet  Gérard F. Blanchard 《Estuarine, Coastal and Shelf Science》2011

A current predominant paradigm emphasizes the role of epiphytic algae for invertebrates in most seagrass food webs. However, in some intertidal Zostera noltii beds, epiphyte biomass is very low compared to microphytobenthos and seagrass biomasses. We assessed the role of microphytobenthos in a temperate intertidal Z. noltii bed by combining stable isotope and fatty acid (FA) analyses on primary producers, composite sources — suspended particulate organic matter (SPOM) and sediment surface organic matter (SSOM) — and the main macrofaunal consumers. Z. noltii showed high δ¹³C (−9.9‰) and high 18:2(n-6) and 18:3(n-3) contents. Microphytobenthos was slightly more ¹³C-depleted (−15.4‰) and had high levels of diatom markers: 14:0, 16:1(n-7)c, 20:5(n-3). Low mean δ¹³C (−22.0‰) and large amounts of diatom and bacteria (18:1(n-7)c) markers indicated that SPOM was mainly composed of a mixture of fresh and decayed pelagic diatoms. Higher mean δ¹³C (−17.9‰) and high amounts of diatom FAs were found in SSOM, showing that microphytobenthic diatoms dominate. Very low percentages of 18:2(n-6) and 18:3(n-3) in consumers indicated a low contribution of Z. noltii material to their diets. Grazers, deposit and suspension-deposit feeders had δ¹³C close to microphytobenthos and high levels of diatom FAs, confirming that microphytobenthos represented the main part of their diet. Lower δ¹³C and higher amounts of flagellate FAs – 22:6(n-3) and 16:4(n-3) – in suspension feeders indicated that their diet resulted from a mixture of SPOM and microphytobenthos. These results demonstrate that invertebrates do not consume high amounts of seagrass and highlight the main role of benthic diatoms in this intertidal seagrass bed.  相似文献