Calibration of the New Certified Reference Materials ERM‐AE633 and ERM‐AE647 for Copper and IRMM‐3702 for Zinc Isotope Amount Ratio Determinations     

Kirsten Moeller  Ronny Schoenberg  Rolf‐Birger Pedersen  Dominik Weiss  Shuofei Dong 《Geostandards and Geoanalytical Research》2012,36(2):177-199

The commonly used, but no longer available, reference materials NIST SRM 976 (Cu) and ‘JMC Lyon’ (Zn) were calibrated against the new reference materials ERM^®‐AE633, ERM^®‐AE647 (Cu) and IRMM‐3702 (Zn), certified for isotope amount ratios. This cross‐calibration of new with old reference materials provides a continuous and reliable comparability of already published with future Cu and Zn isotope data. The Cu isotope amount ratio of NIST SRM 976 yielded δ^65/63Cu values of ?0.01 ± 0.05‰ and ?0.21 ± 0.05‰ relative to ERM^®‐AE633 and ERM^®‐AE647, respectively, and a δ^66/64Zn_IRMM‐3702 value of ?0.29 ± 0.05‰ was determined for ‘JMC Lyon’. Furthermore, we separated Cu and Zn from five geological reference materials (BCR‐2, BHVO‐2, BIR‐1, AGV‐1 and G‐2) using a two‐step ion‐exchange chromatographic procedure. Possible isotope fractionation of Cu during chromatographic purification and introduction of resin‐ and/or matrix‐induced interferences were assessed by enriched ⁶⁵Cu isotope addition. Instrumental mass bias correction for the isotope ratio determinations by MC‐ICP‐MS was performed using calibrator‐sample bracketing with internal Ni doping for Cu and a double spike approach for Zn. Our results for the five geological reference materials were in very good agreement with literature data, confirming the accuracy and applicability of our analytical protocol.  相似文献   

Deposition of 1.88-billion-year-old Iron Formations as a Consequence of Rapid Crustal Growth     

Birger Rasmussen  Ian R. Fletcher  Andrey Bekker  Janet R. Muhling  Courtney J. Gregory  Alan M. Thorne 《Journal of the Geological Society of India》2012,80(1):147

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Transient creep of the lithosphere and its role in geodynamics   总被引：1，自引：0，他引：1  

B. I. Birger 《Izvestiya Physics of the Solid Earth》2012,48(6):496-503

Laboratory experiments with samples of rocks show that at small strains there is transient creep, at which the strain grows with time, and the strain rate decreases. Plate tectonics allows only small strains in the lithospheric plates, so that the lithosphere creep is transient. In geodynamics, the lithosphere is regarded as a cold boundary layer formed by mantle convection. If we assume that the lithosphere has a steady-state creep, which is described by power-law non-Newtonian rheological model, the low effective viscosity of the lower layers of the lithosphere, obtained by data on small-scale postglacial flows, is possible only at high strain rates in these layers. However, the high strain rates in the lithosphere induce large strains that contradict plate tectonics. Transient creep of the lithosphere leads to its mobility at small strains, removing the discrepancy between thermal convection in the mantle and plate tectonics, which holds in the case of power-law rheological model of the lithosphere.  相似文献   

Zirconolite and xenotime U–Pb age constraints on the emplacement of the Golden Mile Dolerite sill and gold mineralization at the Mt Charlotte mine,Eastern Goldfields Province,Yilgarn Craton,Western Australia     

Birger Rasmussen  Andreas G. Mueller  Ian R. Fletcher 《Contributions to Mineralogy and Petrology》2009,157(5):559-572

In situ SHRIMP U–Pb dating of magmatic zirconolite (CaZrTi₂O₇) in the Golden Mile Dolerite from the Mt Charlotte gold deposit (Yilgarn Craton, Australia) has yielded the first robust emplacement age (2,680 ± 9 Ma) for the principle host-rock of gold mineralization in the Kalgoorlie district. In contrast, co-magmatic zircon gave ages from ~2.68 Ga to ~2.17 Ga, reflecting isotopic resetting of high-U and -Th crystals. In situ SHRIMP analysis of hydrothermal xenotime (YPO₄), which co-exists with gold in alteration pyrite, provided a Pb/Pb isochron age of 2,655 ± 13 Ma. This date indicates that the youngest deposit in the Kalgoorlie district (Mt Charlotte) formed at ~2.65 Ga, and provides a new minimum age for the structurally older Golden Mile deposit. Our results indicate that gold mineralization at Mt Charlotte is ~50 million years older than indicated by recent ⁴⁰Ar/³⁹Ar dating and places new constraints on the timing of late-stage regional faulting (D₄) in the province.  相似文献   

Performance of a damage‐protected beam–column subassembly utilizing external HF2V energy dissipation devices     

Geoffrey W. Rodgers  Kevin M. Solberg  J. Geoffrey Chase  John B. Mander  Brendon A. Bradley  Rajesh P. Dhakal  Luoman Li 《地震工程与结构动力学》2008,37(13):1549-1564

Ductile‐jointed connections, which generally require some form of supplementary energy dissipation to alleviate displacement response, typically employ mild steel energy dissipation devices. These devices run the risk of low‐cycle fatigue, are effective only for peak cycles that exceed prior displacements, are prone to buckling, and may require replacement following an earthquake. This study presents an experimental investigation employing an alternative to mild steel: a high force‐to‐volume (HF2V) class of damper‐based energy dissipation devices. Tests are performed on a near full‐scale beam–column joint subassembly utilizing externally mounted compact HF2V devices. Two configurations are considered: an exterior joint with two seismic beams and one gravity beam framing into a central column, and a corner joint with only one seismic beam and one gravity beam framing into a column. Quasi‐static tests are performed to column drifts up to 4%. The experiments validate the efficacy of the HF2V device concept, demonstrating good hysteretic energy dissipation, and minimal residual device force, allowing ready re‐centring of the joint. The devices dissipate energy consistently on every cycle without the deterioration observed in the yielding steel bar type of devices. The effectiveness of the HF2V devices on structural hysteretic behavior is noted to be sensitive to the relative stiffness of the anchoring elements, indicating that better efficiency would be obtained in an embedded design. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Sea ice winter severity in the german baltic in a greenhouse gas experiment     

Birger Tinz 《Ocean Dynamics》1998,50(1):33-45

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Making the EU Emissions Trading System: The European Commission as an entrepreneurial epistemic leader     

Jon Birger Skjærseth  Jørgen Wettestad 《Global Environmental Change》2010,20(2):314-321

The EU has developed the first and largest international emissions trading system in the world. This development is puzzling due to the EU's scepticism to international emissions trading in greenhouse gases (GHGs) in the run-up to the 1997 Kyoto Protocol. This article analyses how the EU ETS was initiated in the first place mainly from the perspectives of Liberal intergovernmentalism (LI) and multi-level governance (MLG). LI emphasises change in the positions of the EU member states as the key to understand what happened and why, whereas MLG opens up for change in the position of supranational entrepreneurial leaders as the key explanation. The main conclusion is that entrepreneurial epistemic leadership exercised by the European Commission was crucial for making the EU ETS. The principal means of leadership involved building up independent expertise on how an EU ETS could be designed, and mobilizing support from state and non-state actors at various levels of decision-making. This type of leadership may be needed more generally to deal with challenges characterized by high scientific uncertainty and social complexity in which learning is pertinent, such as climate change.  相似文献   

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents     

Davide Lenaz  Vanni Lughi  Diego Perugini  Maurizio Petrelli  Gianluca Turco  Birger Schmitz 《Meteoritics & planetary science》2019,54(12):3089-3100

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.  相似文献   

Flow through nets and trawls of low porosity     

Svein Helge Gjøsund  Birger Enerhaug 《Ocean Engineering》2010,37(4):345-354

In trawls intended for harvesting marine zooplankton the mesh size and twine thickness may be as small as O(10⁻⁴ m), the porosity less than 0.5 and the appropriate Reynolds number O(10⁰−10²). The flow locally through the meshes varies strongly with the Reynolds number in this range, and the entire flow field, filtered volume and drag of such nets therefore depend strongly on the net parameters and towing velocity.This paper presents a simplified model for the flow through and forces on inclined permeable screens based on pressure drop considerations. For conical nets the model provides simple expressions for the filtration efficiency and drag as functions of twine diameter, mesh opening, porosity, taper angle and flow (towing) velocity. Comparisons with test tank measurements of typical plankton nets show good agreement.  相似文献   

Barium, SiO₂ (excess), and P₂O₅ as proxies of biological productivity in the Middle East during the Palaeocene and the latest Palaeocene benthic extinction event     

Birger Schmitz  Stella D. Charisi  Elisabet I. Thompson  Robert P. Speijer 《地学学报》1997,9(2):95-99

The distribution of barium and other elements related to biological productivity has been studied in two Palaeocene sections from the Middle East. In the bathyal Ben Gurion section, Israel, Ba* (= Ba/Al₂O₃× 15%) concentrations are low, in the range 0.04% to 0.3% in the lower Palaeocene, and very high, 1% to 2%, throughout most of the upper Palaeocene. In the neritic Gebel Aweina section in Egypt Ba* values are low, < 0.1%, throughout the entire Palaeocene. The Ba* enrichments at Ben Gurion and their correlations with increases in P₂O₅ and opaline silica, and local and global δ¹³C maxima, indicate that upwelling and high productivity were important in this region during the late Palaeocene. The absence of Ba* enrichments in the shallower Gebel Aweina section probably reflects the strong depth dependence of biobarium deposition. In the uppermost Palaeocene, at the level where the global benthic extinction event is registered, Ba* concentrations in the Ben Gurion section increase to anomalous 6%. which suggests that upwelling and possibly wind strengths intensified during this event. The results speak against deep-water formation in this region since downwelling and not upwelling is required.  相似文献