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991.
Second-Order Modelling of Turbulence in Katabatic Flows   总被引:1,自引:1,他引:0  
A complete one-dimensional second-order closure model is used to simulate katabatic flows observed on glaciers and ice caps. The model is tested with two different closure assumptions for the viscous dissipation, one based on a prognostic equation for and the other on a diagnostic buoyant length scale. Both formulations give quite similar results. Model simulations are compared to observations made over sloping ice surfaces during periods dominated by katabatic flow. In general, good agreement is found for both mean wind and temperature profiles as well as eddy correlation measurements. It is also found that the turbulent transport terms play an important role in katabatic flows as opposed to the classical stable boundary layer where these terms are usually ignored. Even the turbulent transport of temperature variance, which leads to the well-known countergradient term in unstable boundary layers, is relatively important for modelling the observed temperature profiles. The effect of these terms on the flux-profile relationships, using observed and simulated profiles, is also discussed.  相似文献   
992.
ABSTRACT

Traditionally, hydrological models are only calibrated to reproduce streamflow regime without considering other hydrological state variables, such as soil moisture and evapotranspiration. Limited studies have been performed on constraining the model parameters, despite the fact that the presence of a large number of parameters may provide large degree of freedom, resulting in equifinality and poor model performance. In this study, a multi-objective optimization approach is adopted, and both streamflow and soil moisture data are calibrated simultaneously for an experimental study basin in the Saskatchewan Prairies in western Canada. The results of this study show that the multi-objective calibration improves model fidelity compared to the single objective calibration. Moreover, the study demonstrates that single objective calibration performed against only streamflow can fairly mimic the streamflow hydrograph but does not yield realistic estimation of other fluxes such as evapotranspiration and soil moisture (especially in deeper soil layers).  相似文献   
993.
994.
Equilibria for several reactions in the system CaO-Al2O3-SiO2-CO2-H2O have been calculated from the reactions calcite+quartz=wollastonite+CO2 (5) and calcite+Al2SiO5+quartz=anorthite+CO2 (19) and other published experimental studies of equilibria in the systems Al2O3-SiO2-H2O and CaO-Al2O3-SiO2-H2O.The calculations indicate that the reactions laumontite+CO2=calcite+kaolinite+2 quartz+2H2O (1) and laumontite+calcite=prehnite+quartz+3H2O+CO2 (3) in the system CaO-Al2O3-SiO2-CO2-H2O, are in equilibrium with an H2O-CO2 fluid phase having -0.0075 for P fluid=P total=2000 bars.These calculations limit the stability of zeolite assemblages to low p CO2.Using the above reactions as model equilibria, several probelms of p CO2 in low grade metamorphism are discussed. (a) the problem of producing zeolitic minerals from metasedimentary assemblages of carbonate, clay mineral, quartz. (b) the significance of calcite (or aragonite) associated with zeolite (or lawsonite) in low grade metamorphism and hydrothermal alteration. (c) the reaction of zeolites (or lawsonite) with calcite (or aragonite) to produce dense Ca-Al-hydrosilicates (eg. prehnite, zoisite, grossular).  相似文献   
995.
An exceptional flood in January 1990 led to the formation of a large ephemeral lake on the Chott el Djerid, a salt playa in southern Tunisia. Repeated observations made during 1990 show that the ephemeral lake underwent four evolutionary stages: (1) initial flooding, (2) evaporative concentration of lake waters, (3) the movement of concentrated brine pools over the playa surface as a result of wind action, and (4) total desiccation of the lake by September 1990. During all four stages the brine chemistry of the lake was monitored. Water inflow into the Chott el Djerid basin was found to have a consistent Ca-SO4-Cl-rich and HCO3-CO3-poor chemistry, reflecting the recycling of homogeneous assemblages of Cretaceous, Mio—Pliocene and Quaternary evaporites within the catchment. As the ephemeral lake shrank, these waters produced an Na-Mg-K-Cl-SO4 brine which was similar to modern sea water. Mineral saturation data show that, during the desiccation of the lake, saturation with respect to both gypsum and halite was achieved and that the most concentrated brines were ultimately saturated with respect to potash phases. After the desiccation of the lake the main mineral phases found on the Chott included gypsum and halite. In addition, ephemeral deposits of carnallite (observed as carnallitite,3KMgCl6H20 + NaCl) were found. This assemblage is that which would be expected to form if the waters had undergone salt norm evaporation at 1 bar pressure at 25°C (SNORM) in the evaporation model proposed by Jones and Bodine (1987). The nature of both the brine chemistry and evaporite mineralogy provides a new and rare example of marine-like potash-bearing evaporites being formed in a contemporary continental playa.  相似文献   
996.
The requirements for precise geoid models on local and regional scales have increased in recent years, primarily due to the ongoing developments in height determination by GPS on land, but also due to oceanographic requirements in using satellite altimetry for recovering dynamic sea-surface topography. Suitable methods for geoid computations from gravity data include Stokes integration, FFT methods, and least-squares collocation. Especially the FFT methods are efficient in handling large amounts of gravity data, and new variants of the methods taking earth curvature rigorously into account provide attractive methods for obtaining continental-scale, high-resolution geoid models. The accuracy of such models may be from 2–5 cm locally, to 50–100 cm on regional scales, depending on gravity data coverage, long wave-length gravity field errors, and datum problems. When approaching the cm-level geoid basic geoid definition questions (geoid or quasigeoid?) become very significant, especially in rugged areas. In the paper the geoid modelling methods and problems are reviewed, and some investigations on local data requirements for cm-level geoid prediction are presented. Some actual results are presented from Scandinavia, where a recent regional high-resolution geoid model yields apparent accuracies of 2–10 cm over GPS baselines of 50 to 2000 km.  相似文献   
997.
This paper presents the results of a unique field test on a curved highway overpass. In the test, large horizontal loads were applied to the superstructure of the bridge and quickly released, causing the bridge to vibrate. The resulting large-amplitude vibrations were intended to be similar to the vibrations caused by earthquakes (horizontal accelerations of up to 25 per cent of gravity were measured on the bridge deck). Well-defined lateral, longitudinal, vertical and torsional vibration modes were identified from the test data. The vibration modes were used to verify an analytical model of the bridge's dynamic response. For this paper, the model was verified using only the fundamental vibration mode, which was primarily a horizontal vibration mode. Using a system identification procedure, the dynamic response model was adjusted until its frequency and mode shape matched the measured frequency and mode shape. Parameters in the verified model were compared with the same parameters calculated from information in the structural drawings. Because the fundamental mode represents a horizontal mode, the bridge parameters identified in this paper were those parameters which strongly influence the horizontal response of the bridge.  相似文献   
998.
999.
The abundance of pyrite and other sulfide minerals in mine rock piles is a potentially significant if not a determinative factor in terms of the geochemical and geomechanical evolution of the dumps as oxidation produces acid solutions that drive hydrolysis reactions. A technique is presented here that supports the quantitative determination of pyrite abundance in mine rock dumps by heavy liquid mineral separation to concentrate pyrite for powder X-ray diffraction and then Rietveld method refinement of the diffraction data on a large number of samples using commonly available laboratory equipment. In order to improve and constrain the accuracy of XRD results, binary (pyrite-quartz) and 6-part mineral mixtures (pyrite and rock-forming andesite minerals) spanning a wide range of pyrite concentrations were prepared gravimetrically and run as standards. These standards were then used to minimize errors in pyrite abundance data by constraining key input parameters in the Rietveld refinement. A new polynomial relationship was derived between diffracting crystallite size and the Brindley microabsorption correction input size. This method provides a means to determine uncertainties in pyrite abundance, whereas conventional Rietveld refinement techniques done without the use of standards yield only statistical measures of the least-squares fit, rather than absolute uncertainties in mineral constituent weight percentages. The technique was applied to a number of mine rock pile samples and the uncertainty in the results determined by applying the relationship derived from the 6-part gravimetric standards to the results of the Brindley corrected Rietveld refinements. Uncertainties determined by this method are found to be on the order of ±10% for samples with pyrite content greater than 10 wt% and ±30% for samples with pyrite content less than 10 wt%. In order to evaluate the technique’s improvement upon traditional visual mineral abundance estimation the quantitative results are compared to manual volumetric estimates.  相似文献   
1000.
A principal task of evaluating large wildfires is to assess fire's effect on the soil in order to predict the potential watershed response. Two types of soil water repellency tests, the water drop penetration time (WDPT) test and the mini-disk infiltrometer (MDI) test, were performed after the Hayman Fire in Colorado, in the summer of 2002 to assess the infiltration potential of the soil. Remotely sensed hyperspectral imagery was also collected to map post-wildfire ground cover and soil condition. Detailed ground cover measurements were collected to validate the remotely sensed imagery and to examine the relationship between ground cover and soil water repellency. Percent ash cover measured on the ground was significantly correlated to WDPT (r = 0.42; p-value < 0.0001), and the MDI test (r = − 0.37; p-value < 0.0001). A Mixture Tuned Matched Filter (MTMF) spectral unmixing algorithm was applied to the hyperspectral imagery, which produced fractional cover maps of ash, soil, and scorched and green vegetation. The remotely sensed ash image had significant correlations to the water repellency tests, WDPT (r = 0.24; p-value = 0.001), and the MDI test (r = − 0.21; p-value = 0.005). An iterative threshold analysis was also applied to the ash and water repellency data to evaluate the relationship at increasingly higher levels of ash cover. Regression analysis between the means of grouped data: MDI time vs. ash cover data (R2 =0.75) and vs. Ash MTMF scores (R2 = 0.63) yielded significantly stronger relationships. From these results we found on-the-ground ash cover greater than 49% and remotely sensed ash cover greater than 33% to be indicative of strongly water repellent soils. Combining these results with geostatistical analyses indicated a spatial autocorrelation range of 15 to 40 m. Image pixels with high ash cover (> 33%), including pixels within 15 m of these pixel patches, were used to create a likelihood map of soil water repellency. This map is a good indicator of areas where soil experienced severe fire effects—areas that likely have strong water repellent soil conditions and higher potential for post-fire erosion.  相似文献   
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