Doklady Earth Sciences - The concentrations of seven heavy metals (HMs) in tissues of bivalve mollusks of the families Unionidae (genera Ensidens, Scabies, Kunashiria) and Cyrenidae (genus... 相似文献
To precisely determine the abundances of fifty‐two elements found within natural water samples, with mass fractions down to fg g?1 level, we have developed a method which combines freeze‐drying pre‐concentration (FDC) and isotope dilution internal standardisation (ID‐IS). By sublimation of H2O, the sample solution was reduced to < 1/50 of the original volume. To determine element abundance with accuracy better than 10%, we found that for solutions being analysed by mass spectrometry the HNO3 concentration should be > 0.3 mol l?1 to avoid hydrolysis. Matrix‐affected signal suppression was not significant for the solutions with NaCl concentrations lower than 0.2 and 0.1 cg g?1 for quadrupole ICP‐MS and sector field ICP‐MS, respectively. The recovery yields of elements after FDC were 97–105%. The detection limits for the sample solutions prepared by FDC were ≤ 10 pg g?1, except for Na, K and Ca. Blanks prepared using FDC were at pg‐levels, except for eleven elements (Na, Mg, Al, P, Ca, Mn, Fe, Co, Ni, Cu and Zn). The abundances of fifty‐two elements in bottled drinking water were determined from five different geological sources with mass fractions ranging from the fg g?1 to μg g?1 level with high accuracy. 相似文献
Usually, one can explain the orthogonal distribution of first movement by the dislocation model of seismic sources, namely a uniform slip. However, other representations may be obtained if the normal component of the dislocation is present. When this component is less than 0.6 times the tangential one, we obtain conical distributions. Some models which simulate a volume phenomenon provide analogous results. We show that they could agree with some observations. 相似文献
Enzyme induced carbonate precipitation (EICP) is an emerging soil improvement method using free urease enzyme for urea hydrolysis. This method has advantages over the commonly used microbially induced carbonate precipitation (MICP) process as it does not involve issues related to bio-safety. However, in terms of efficiency of calcium carbonate production, EICP is considered lower than that of MICP. In this paper, a high efficiency EICP method is proposed. The key of this new method is to adopt a one-phase injection of low pH solution strategy. In this so-called one-phase-low-pH method, EICP solution consisting of a mixture of urease solution of pH?=?6.5, urea and calcium chloride is injected into soil. The test results have shown that the one-phase-low-pH method can improve significantly the calcium conversion efficiency and the uniformity of calcium carbonate distribution in the sand samples as compared with the conventional two-phase EICP method. Furthermore, the unconfined compressive strength of sand treated using the one-phase-low-pH method is much higher than that using the two-phase method and the one-phase-low-pH method is also simpler and more efficient as it involves less number of injections.
Geotectonics - This paper presents analysis of geomorphological indices for predicting the maximum observed earthquake (MOb?Max) in research region, conducted in three steps: (i)... 相似文献
Natural Hazards - The mechanical processes involved in movements of earth or rock masses under the effect of gravity—a landslide—may include several phases where the failure of one... 相似文献
Despite being a simple and inexpensive pretreatment technology, the cost-effectiveness of riverbank filtration (RBF) depends on complex hydrogeological and hydrogeochemical variables. One of the most important issues for decision makers regarding RBF is optimal site selection. Therefore, a methodology for multicriteria site evaluation for large-scale RBF schemes is offered. The methodology is primarily designed as a prescreening method, applied over a wide area, but can also serve as a guide for evaluating individual RBF sites. To facilitate further discussion about improvements on the methodology, the reasoning behind each relevant factor and its weight in the evaluation is presented. The methodology is divided into three sequential steps through which a site can be assessed. The first step is to establish the existence of connectivity between the river and aquifer. This is termed the essential criterion, and is a binary determination of site suitability. If the site is determined to be suitable, it is then assessed via a set of quantity criteria, which measure the aquifer capacity and amount of bank filtrate that can be effectively abstracted. Lastly, water quality criteria are assessed by means of surface-water and groundwater quality. The quantity and quality criteria form a result expressed as the site suitability index (SSI), which ranges from 0 to 1, where higher scores represent increased suitability. Finally, the methodology is applied to evaluate existing sites of large-scale RBF application as a demonstration of its applicability. The success of these existing sites is compared to the calculated SSI value and discussed.
This study synthesizes two different methods for estimating hydraulic conductivity (K) at large scales. We derive analytical approaches that estimate K and apply them to the contiguous United States. We then compare these analytical approaches to three-dimensional, national gridded K data products and three transmissivity (T) data products developed from publicly available sources. We evaluate these data products using multiple approaches: comparing their statistics qualitatively and quantitatively and with hydrologic model simulations. Some of these datasets were used as inputs for an integrated hydrologic model of the Upper Colorado River Basin and the comparison of the results with observations was used to further evaluate the K data products. Simulated average daily streamflow was compared to daily flow data from 10 USGS stream gages in the domain, and annually averaged simulated groundwater depths are compared to observations from nearly 2000 monitoring wells. We find streamflow predictions from analytically informed simulations to be similar in relative bias and Spearman's rho to the geologically informed simulations. R-squared values for groundwater depth predictions are close between the best performing analytically and geologically informed simulations at 0.68 and 0.70 respectively, with RMSE values under 10 m. We also show that the analytical approach derived by this study produces estimates of K that are similar in spatial distribution, standard deviation, mean value, and modeling performance to geologically-informed estimates. The results of this work are used to inform a follow-on study that tests additional data-driven approaches in multiple basins within the contiguous United States. 相似文献
