Submicron scale imaging of soil organic matter dynamics using NanoSIMS - From single particles to intact aggregates     

Carsten W. Mueller  Angelika KölblCarmen Hoeschen  François HillionKatja Heister  Anke M. HerrmannIngrid Kögel-Knabner 《Organic Geochemistry》2012,42(12):1476-1488

The specific features of the nano-scale secondary ion mass spectrometry (NanoSIMS) technology with the simultaneous analysis of up to seven ion species with high mass and lateral resolution enables us to perform multi-element and stable isotope measurements at the submicron scale. To elucidate the power of this technique, we performed an incubation experiment with soil particles of the fine silt and clay fractions (from an Albic Luvisol), with occluded particulate organic material and intact soil aggregates (from a Haplic Chernozem), using a ¹³C and ¹⁵N labelled amino acid mixture as tracer. Before and during 6-day incubation after the addition of the label, samples were consecutively prepared for NanoSIMS analysis. For this purpose, two different sample preparation techniques were developed: (i) wet deposition and (ii) the sectioning of epoxy resin embedded samples. Single soil particles (fine silt/clay fraction) showed an enrichment of ¹³C and ¹⁵N after label addition that decreased over time. On aggregates of particulate organic matter, re-aggregated during the 6-day incubation experiment, we could show a spatially heterogeneous enrichment of ¹³C and ¹⁵N on the particle surface. The enrichment in ¹⁵N demonstrated the diffusion of dissolved organic matter into intact soil aggregate interiors. The prospects of NanoSIMS for three dimensional studies of stable C and N isotopes in organo-mineral associations is demonstrated by the recorded depth profiles of the organic matter distribution on mineral particles.  相似文献   

The Influence of Wellbore Inflow on Electromagnetic Borehole Flowmeter Measurements     

by Tom Clemo  Warren Barrash  Edward C. Reboulet  Timothy C. Johnson  Carsten Leven 《Ground water》2009,47(4):515-525

This paper describes a combined field, laboratory, and numerical study of electromagnetic borehole flowmeter measurements acquired without the use of a packer or skirt to block bypass flow around the flowmeter. The most significant finding is that inflow through the wellbore screen changes the ratio of flow through the flowmeter to wellbore flow. Experiments reveal up to a factor of two differences in this ratio for conditions with and without inflow through the wellbore screen. Standard practice is to assume the ratio is constant. A numerical model has been developed to simulate the effect of inflow on the flowmeter. The model is formulated using momentum conservation within the borehole and around the flowmeter. The model is embedded in the MODFLOW-2000 ground water flow code.  相似文献   

Evaluation of Combined Direct-Push Methods Used for Aquifer Model Generation   总被引：4，自引：0，他引：4  

by Ralf Köber  Götz Hornbruch  Carsten Leven  Lars Tischer  Jochen Großmann  Peter Dietrich  Holger Weiß  Andreas Dahmke 《Ground water》2009,47(4):536-546

Most established methods to characterize aquifer structure and hydraulic conductivities of hydrostratigraphical units are not capable of delivering sufficient information in the spatial resolution that is desired for sophisticated numerical contaminant transport modeling and adapted remediation design. With hydraulic investigation methods based on the direct-push (DP) technology such as DP slug tests, DP injection logging, and the hydraulic profiling tool, it is possible to rapidly delineate hydrogeological structures and estimate their hydraulic conductivity in shallow unconsolidated aquifers without the need for wells. A combined application of these tools was used for the investigation of a contaminated German refinery site and for the setup of hydraulic aquifer models. The quality of DP investigation and the models was evaluated by comparisons of tracer transport simulations using these models and measured breakthroughs of two natural gradient tracer tests. Model scenarios considering the information of all tools together showed good reproduction of the measured breakthroughs, indicating the suitability of the approach and a minor impact of potential technical limitations. Using the DP slug tests alone yielded significantly higher deviations for the determined hydraulic conductivities compared to considering two or three of the tools. Realistic aquifer models developed on basis of such combined DP investigation approaches can help optimize remediation concepts or identify flow regimes for aquifers with a complex structure.  相似文献   

Determination of High Field Strength Elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ Levels in Geological Reference Materials by Magnetic Sector ICP-MS after HF/HClO₄ High Pressure Digestion     

Zongshou Yu  Philip Robinson  Ashley T. Townsend  Carsten Mnker  Anthony J. Crawford 《Geostandards and Geoanalytical Research》2000,24(1):39-50

Six low abundance rock reference materials (basalt BIR-1, dunite DTS-1, dolerite DNC-1, peridotite PCC-1, serpentine UB-N and basalt TAFAHI) have been analysed for high field strength elements (Zr, Nb, Hf, Ta, Th and U), Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels (in rock) by magnetic sector inductively coupled plasma-mass spectrometry after HF/HClO₄ high pressure decomposition. The adopted method uses only indium as an internal standard. Detection limits were found to be in the range of 0.08 to 16.2 pg ml⁻¹ in solution (equivalent to 0.08 to 16.2 ng g⁻¹ in rock). Our data for high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi for the six selected low abundance geological reference materials show general agreement with previously published data. Our Ta values in DTS-1 and PCC-1 (1.3 and 0.5 ng g⁻¹) are lower than in previously published studies, providing smooth primitive mantle distribution patterns. Lower values were also found for Tl in BIR-1, DTS-1 and PCC-1 (2, 0.4 and 0.8 ng g⁻¹). Compared with quadrupole ICP-MS studies, the proposed magnetic sector ICP-MS method can generally provide better detection limits, so that the measurement of high field strength elements, Rb, Sr, Mo, Sb, Cs, Tl and Bi at ng g⁻¹ levels can be achieved without pre-concentration, ion exchange separation or other specialised techniques.  相似文献   

Isoprene and Its Oxidation Products Methyl Vinyl Ketone, Methacrolein, and Isoprene Related Peroxides Measured Online over the Tropical Rain Forest of Surinam in March 1998   总被引：2，自引：0，他引：2  

C. Warneke  R. Holzinger  A. Hansel  A. Jordan  W. Lindinger  U. Pöschl  J. Williams  P. Hoor  H. Fischer  P. J. Crutzen  H. A. Scheeren  J. Lelieveld 《Journal of Atmospheric Chemistry》2001,38(2):167-185

Airborne measurements of volatile organic compounds (VOC) were performed overthe tropical rainforest in Surinam (0–12 km altitude,2°–7° N, 54°–58° W) using the proton transferreaction mass spectrometry (PTR-MS) technique, which allows online monitoringof compounds like isoprene, its oxidation products methyl vinyl ketone,methacrolein, tentatively identified hydroxy-isoprene-hydroperoxides, andseveral other organic compounds. Isoprene volume mixing ratios (VMR) variedfrom below the detection limit at the highest altitudes to about 7 nmol/molin the planetary boundary layer shortly before sunset. Correlations betweenisoprene and its product compounds were made for different times of day andaltitudes, with the isoprene-hydroperoxides showing the highest correlation.Model calculated mixing ratios of the isoprene oxidation products using adetailed hydrocarbon oxidation mechanism, as well as the intercomparisonmeasurement with air samples collected during the flights in canisters andlater analysed with a GC-FID, showed good agreement with the PTR-MSmeasurements, in particular at the higher mixing ratios.Low OH concentrations in the range of 1–3 × 10⁵molecules cm^-3 averaged over 24 hours were calculated due to lossof OH and HO₂ in the isoprene oxidation chain, thereby stronglyenhancing the lifetime of gases in the forest boundary layer.  相似文献   

Sedimentological and geochemical responses of Lake Żabińskie (north-eastern Poland) to erosion changes during the last millennium     

Alicja Bonk  Małgorzata Kinder  Dirk Enters  Martin Grosjean  Carsten Meyer-Jacob  Wojciech Tylmann 《Journal of Paleolimnology》2016,56(2-3):239-252

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Filter-feeding ascidians (Ciona intestinalis) in a shallow cove: Implications of hydrodynamics for grazing impact     

Hans Ulrik Riisgård  Carsten Jürgensen  Torben Clausen 《Journal of Sea Research》1996,35(4):293-300

The grazing impact by a dense population of filter-feeding ascidians Ciona intestinalis on horizontally flowing water (driven by density circulation) in a shallow cove (Kertinge Nor, Denmark) has been described and quantified by means of a simple one-dimensional numerical model. The agreement between observations and modelled predictions was satisfactory. The applied numerical model has the following analytical solution in the idealized case: Cx = C₀e^−(fx/Y₂), where C_x = algal concentration at a downstream distance x, C₀ = initial concentration, f = F/v_c; F = area specific population filtration rate; v_c = current velocity; Y₂ = depth of mixed layer below halocline. The numerical model quantifies the actual grazing impact while the analytical model illustrates the governing physics in well-known terms. To describe situations with no current (i.e. stagnant water), we performed simulation studies in the laboratory and measured vertical profiles of algal cells over filter-feeding C. intestinalis. The results showed that phytoplankton became reduced in a near-bottom water layer of 20–30 cm thickness. Such water layers may develop in stagnant water (calm days and no advective currents), thus uncoupling the pelagic food and the filter feeders which within a short time will experience extremely meagre food conditions.  相似文献   

Boninites as windows into trace element mobility in subduction zones   总被引：3，自引：0，他引：3  

Stephan König  Carsten Münker  Stephan Schuth  Ambre Luguet  Jonathan Kuduon 《Geochimica et cosmochimica acta》2010,74(2):684-338

Boninites are subduction-related rocks originating from re-melting of highly depleted mantle sources left after extraction of tholeiitic melts. Due to their depleted nature, the incompatible trace element inventory of boninites is virtually entirely inherited from slab components without a significant contribution from the refractory mantle wedge. Thus, boninites constitute an excellent window into processes controlling trace element mobilization at the slab-mantle wedge interface. In order to constrain the behaviour of trace elements in subduction zones with a special emphasis on high field strength elements, we analyzed low-Ca boninites and associated tholeiitic basalts from Cape Vogel, Papua New Guinea (PNG) and compare them with compositions of high-Ca boninites and associated tholeiitic basalts from Cyprus. High-precision HFSE (Nb, Ta, Zr, Hf, W) concentration data of the boninites and associated tholeiitic basalts were obtained by isotope dilution. Major, trace element, and Sr-Nd-Hf-Pb isotope compositions clearly document a significant contribution of slab-derived melts involved in the petrogenesis of the PNG boninites, whereas only fluid-like subduction components were involved in the petrogenesis of the PNG basalts and the Cyprus suite. Low-Ca boninites from PNG are derived from a more refractory mantle source (∼21% depletion) than the high-Ca boninites from Cyprus (∼11% depletion) and their respective tholeiitic precursors (<10% depletion). In agreement with the more depleted nature of their mantle source, boninites exhibit a significantly stronger overprint by slab components. High-precision HFSE data indicate that, in comparison to LILE, a somewhat lower but measurable mobilization of all investigated HFSE in both slab-derived fluids and melts is evident. Modelling calculations demonstrate that the subduction components dominate the LILE budget and also largely control LREE and HFSE abundances in the boninite sources. Notably, the increasing influence of slab-derived fluids results in a decrease of the negative Nb-Ta anomaly, most likely reflecting a similar mobility of Nb-Ta and LREE at higher pressures near the critical point of fluid-melt miscibility. Ratios of Zr/Hf and Nb/Ta in the melt-like slab components dominating in the sources of the PNG boninites were probably fractionated in equilibrium with garnet-amphibolitic mafic oceanic crust. HFSE ratios in the Cyprus boninites are best explained by dehydration of subducted pelagic sediments in the absence of Ti-rich phases such as rutile. Our results also confirm previous assertions that the mobility of HFSE decreases in the order Sb > W-Mo > Nb-Ta > Zr-Hf. Furthermore, Mo-W systematics may provide a potential novel tracer for the amount, composition and redox state of subducted pelagic sediments that contribute to the geochemical budget of intra-oceanic arc systems.  相似文献   

Retracing the development of raw water quality in water works applying reactive controlled material flux analyses     

Carsten?HansenEmail author  Wolfgang?van Berk 《Aquatic Sciences - Research Across Boundaries》2004,66(1):60-77

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International Handbook of Earthquake and Engineering Seismology     

Carsten Riedel 《Journal of Seismology》2006,10(3):389-391

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