Evaporation and Sublimation of Boric Acid: Application for Boron Purification from Organic Rich Solutions   总被引：1，自引：0，他引：1  

Jérôme Gaillardet  Damien Lemarchand  Christa Göpel  Gérard Manhès 《Geostandards and Geoanalytical Research》2001,25(1):67-75

We report in this paper a series of experiments whose purpose is to test the long held idea of boron volatility when neutral to acidic solutions containing traces of boron are evaporated. Boron recoveries have been measured precisely by isotopic dilution and boron isotopic ratios have also been determined. Most of the evaporations have been conducted at 60-65 °C. It was found that no loss of boric acid occurs when c. 1 μg of B is evaporated in water, HCl, HF and acetone solutions. At the same time, we did not observe any associated B isotopic fractionation. In contrast to previous studies on B volatilisation, it was not found necessary to use mannitol to prevent B losses during the evaporation of acidic solutions. Important losses of boron were observed from solutions of methanol, ethanol and organic-rich natural solutions. In the presence of methanol and ethanol, a volatile methyl (or ethyl) borate is likely to be formed. In contrast to these studies, we show that boron is highly volatile when the dried residues of an evaporation are heated further. The sublimation of boron that then occurs can be moderated by the use of mannitol, but a slight increase of the temperature allows B volatilisation. Despite the substantial losses of B by sublimation, no B isotopic fractionation was observed at 60-65 C. The property of boron to sublime was used to separate B from an organic matrix. A miniaturized sublimation apparatus, comprising a 5 ml Teflon beaker, and the associated microsublimation technique are described. The 100% boron recovery and the absence of B isotopic fractionation make this method suitable for extracting B from organic-rich samples.  相似文献   

Lead isotopic study of the Xigaze ophiolite (Tibet): the problem of the relationship between magmatites (gabbros,dolerites, lavas) and tectonites (harzburgites)     

Christa Göpel  Claude J. Allègre  Rong-Hua Xu 《Earth and Planetary Science Letters》1984,69(2):301-310

The Pb isotopic study of the Xigaze ophiolite (Tibet) shows that the tectonic (harzburgites) and magmatic (gabbros, dolerites, lavas) units bear different isotopic signatures, the harzburgitic rocks show much higher²⁰⁷Pb/²⁰⁴Pb values than the samples from the magmatic unit. Analyses of primary magmatic clinopyroxenes separated from the harzburgites confirmed that this difference is real and not due to secondary alteration processes. UPb analysis allowed determination of the crystallization age of the magmatites at 120 ± 10 m.y. This age is compatible with paleontological age determinations and thus demonstrates that UPb behaved more or less as a closed system since formation of the ophiolite. If an exchange with seawater has occurred, it must necessarily have happened shortly after crystallization of the Xigaze oceanic crust. Dolerite dykes crossing the harzburgites show similar Pb isotopic composition as the magmatites, indicating that they were emplaced when the ultramafic rocks were already brittle; however, the time difference of the emplacement was probably not larger than 280 m.y. This makes it evident that two sources with different isotopic signatures, one similar to normal MORB, the other with much higher²⁰⁷Pb/²⁰⁴Pb ratios, were active in the immediate neighborhood. One possible environment which can account for this association is a propagating ridge.  相似文献   

Exploring the application of topographic indices in urban areas as indicators of pluvial flooding locations     

Christa Kelleher  Lauren McPhillips 《水文研究》2020,34(3):780-794

In urban areas, the presence of impervious surfaces limits natural drainage and routes water to stormwater infrastructure with finite capacity, making these areas especially prone to flooding. Though large floods are responsible for endangering lives and causing extensive damage, there is growing evidence that more frequent floods with shallow water depths, termed nuisance flooding, can have a high cumulative cost and many direct and indirect damages. To determine whether locations of nuisance flooding may be linked to topography, we took a parsimonious, spatially distributed approach to explore whether high topographic index values co-occur with citizen-reported nuisance flooding. We obtained nuisance flood reports from the municipal data service 311 for several watersheds in New York City and Baltimore, USA. Our analysis tested two topographic indices (TI)—topographic wetness index (TWI) and sink depth—both calculated from high-resolution (~1 m) digital elevation models. Generally, our findings suggest that not all but many locations of reported flooding tend to coincide with deep sinks or large TWI. However, nuisance flooding reports most commonly coincided with deep sinks and high TWI when using a maximum, instead of coincident, TI value extracted around each reported location of flooding, an approach we used due to the uncertainty in location accuracy of flooding reports. Overall, our results show promise for application of topographic indices, typically applied in more natural settings, as indicators of nuisance flooding areas in urbanized environments. Although limitations to this approach exist, the application of TIs and crowd-sourced reporting in tandem could provide a useful starting point for mapping flood-prone areas in many cities with technologically adept community members and ample geospatial data.  相似文献   

Laboratory studies of methane and ethane adsorption and nucleation onto organic particles: Application to Titan's clouds     

Daniel B. Curtis  Courtney D. Hatch  Christa A. Hasenkopf  Owen B. Toon  Margaret A. Tolbert  Christopher P. McKay 《Icarus》2008,195(2):792-801

Titan, Saturn's largest moon, has a thick nitrogen/methane atmosphere. The temperature and pressure conditions in Titan's atmosphere are such that the methane vapor should condense near the tropopause to form clouds. Several ground-based measurements have observed sparse cloud-like features in Titan's atmosphere, while the Cassini mission to Saturn has provided large scale images of the clouds. However, Titan's cloud formation conditions remain poorly constrained. Heterogeneous nucleation (from the vapor phase onto a solid or liquid aerosol surface) greatly enhances cloud formation relative to homogeneous nucleation. In order to elucidate the cloud formation mechanism near the tropopause, we have performed laboratory measurements of the adsorption of methane and ethane onto solid organic particles (tholins) representative of Titan's photochemical haze. We find that monolayers of methane adsorb onto tholin particles at saturation ratios less than unity. We also find that solid methane nucleates onto the adsorbed methane at a saturation ratio of S=1.07±0.008. This implies that Titan's methane clouds should form easily. This is consistent with recent measurements of the column of methane ruling out excessive methane supersaturation. In addition, we find ethane adsorbs onto tholin particles in a metastable phase prior to nucleation. However, ethane nucleation onto the adsorbed ethane occurs at a relatively high saturation ratio of S=1.36±0.08. These findings are consistent with the recent report of polar ethane clouds in Titan's lower stratosphere.  相似文献   

Impact of beaver dam analogues on hydrology in a semi-arid floodplain     

Casey Pearce  Philippe Vidon  Laura Lautz  Christa Kelleher  Julianne Davis 《水文研究》2021,35(7):e14275

Natural beaver ponds help connect the stream to the floodplain, maintain late summer low flows and reduce peak flow during high flow events by offering temporary surface water (SW) storage. When beavers are extirpated from the landscape, stream degradation often ensues. This study assesses the impact of beaver dam analogues (BDA) as a stream restoration technique to help maintain low flow water levels and enhance stream-floodplain interactions on a seasonal basis in Red Canyon Creek, Lander, WY. BDAs increased SW and groundwater (GW) levels, favoured the occurrence of flow reversals (i.e., stream-to-floodplain GW flow) during high flow events associated with mid-winter and early-spring thaw events, and reduced the groundwater-to-stream hydraulic gradient on an annual basis. Although GW temperatures varied seasonally, relatively cooler GW temperatures were observed in the BDA impacted reach compared to the control reach away from BDA influence. BDAs however did not significantly impact stream temperatures. Overall, results suggest that when installed in sequence, BDA complexes can successfully reconnect the stream to its floodplain, and ultimately increase SW-GW exchange at the floodplain scale by allowing flow reversals to occur and by reducing the GW to stream hydraulic gradient. Although BDAs built with fence posts, willow branches, sediments and small boulders are naturally porous and require regular maintenance, this study also highlights the viability of small BDAs as a restoration practice to enhance landscape resilience to drought and high flow events in deeply incised channels where beavers would not come back naturally.  相似文献   

Comment on ‘Shang S. 2012. Calculating actual crop evapotranspiration under soil water stress conditions with appropriate numerical methods and time step. Hydrological Processes 26: 3338–3343. DOI: 10.1002/hyp.8405’          下载免费PDF全文

Soni Yatheendradas  Balachandrudu Narapusetty  Christa Peters‐Lidard  Christopher Funk  James Verdin 《水文研究》2014,28(11):3833-3840

A previous study analyzed errors in the numerical calculation of actual crop evapotranspiration (ET_a) under soil water stress. Assuming no irrigation or precipitation, it constructed equations for ET_a over limited soil‐water ranges in a root zone drying out due to evapotranspiration. It then used a single crop‐soil composite to provide recommendations about the appropriate usage of numerical methods under different values of the time step and the maximum crop evapotranspiration (ET_c). This comment reformulates those ET_a equations for applicability over the full range of soil water values, revealing a dependence of the relative error in numerical ET_a on the initial soil water that was not seen in the previous study. It is shown that the recommendations based on a single crop‐soil composite can be invalid for other crop‐soil composites. Finally, a consideration of the numerical error in the time‐cumulative value of ET_a is discussed besides the existing consideration of that error over individual time steps as done in the previous study. This cumulative ET_a is more relevant to the final crop yield. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

Kentucky's Frontier Highway: Historical Landscapes Along the Maysville Road. By Karl Raitz and Nancy O'Malley. ix and 411 pp.; maps,ills., bibliog., index. Lexington: University Press of Kentucky, 2012. $40.00 (cloth), ISBN 9780813136646.     

Christa A. Smith 《Geographical review》2013,103(4):592-594

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Advances in landslide nowcasting: evaluation of a global and regional modeling approach     

Dalia Bach Kirschbaum  Robert Adler  Yang Hong  Sujay Kumar  Christa Peters-Lidard  Arthur Lerner-Lam 《Environmental Earth Sciences》2012,66(6):1683-1696

The increasing availability of remotely sensed data offers a new opportunity to address landslide hazard assessment at larger spatial scales. A prototype global satellite-based landslide hazard algorithm has been developed to identify areas that may experience landslide activity. This system combines a calculation of static landslide susceptibility with satellite-derived rainfall estimates and uses a threshold approach to generate a set of ‘nowcasts’ that classify potentially hazardous areas. A recent evaluation of this algorithm framework found that while this tool represents an important first step in larger-scale near real-time landslide hazard assessment efforts, it requires several modifications before it can be fully realized as an operational tool. This study draws upon a prior work’s recommendations to develop a new approach for considering landslide susceptibility and hazard at the regional scale. This case study calculates a regional susceptibility map using remotely sensed and in situ information and a database of landslides triggered by Hurricane Mitch in 1998 over four countries in Central America. The susceptibility map is evaluated with a regional rainfall intensity–duration triggering threshold and results are compared with the global algorithm framework for the same event. Evaluation of this regional system suggests that this empirically based approach provides one plausible way to approach some of the data and resolution issues identified in the global assessment. The presented methodology is straightforward to implement, improves upon the global approach, and allows for results to be transferable between regions. The results also highlight several remaining challenges, including the empirical nature of the algorithm framework and adequate information for algorithm validation. Conclusions suggest that integrating additional triggering factors such as soil moisture may help to improve algorithm performance accuracy. The regional algorithm scenario represents an important step forward in advancing regional and global-scale landslide hazard assessment.  相似文献   

Spin-driven tidal pumping: tidally driven changes in planetary spin coupled with secular interactions between planets     

Richard Greenberg  Christa Van Laerhoven  Rory Barnes 《Celestial Mechanics and Dynamical Astronomy》2013,117(4):331-348

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Ecotoxicity assessment of natural attenuation effects at a historical dumping site in the western Baltic Sea     

Leipe T  Kersten M  Heise S  Pohl C  Witt G  Liehr G  Zettler M  Tauber F 《Marine pollution bulletin》2005,50(4):446-459

During the late 1950s and early 1960s of the past century, industrial waste material highly enriched in various contaminants (heavy metals, PAHs) was dumped in the inner Mecklenburg Bay, western Baltic Sea. Large-scale shifts in the spatial distribution of heavy metals in surface sediments were mapped by geochemical monitoring in the mid-1980s and 12 years later in 1997. A further study in 2001 was designed to investigate the small-scale spatial distribution of contaminants inside, on top of, and around the historical dumping ground and to examine possible effects to benthic organisms (Arctica islandica, microbiological toxicity tests). The site is located within an area characterized by a discontinuous deposition of fine sediments, but net sedimentation rate of about 3mm/y led ultimately to a gradual coverage of the dumped material. During the first decades after the dumping, about half of the originally dumped material was already spread over the surrounding area as a result of sediment dynamics and re-suspension processes. Recent sediments of the historical dump site are still significantly enriched in heavy metals and PAHs. Microbiological toxicity test results were positive, though uptake of contaminants in mussels was found to deviate only slightly from that of a non-contaminated reference station due to a gradual dilution and decrease in bioavailability of the contaminants.  相似文献