Restoring Halite Fluid Inclusions as an Accurate Palaeothermometer: Brillouin Thermometry Versus Microthermometry     

Emmanuel Guillerm  Vronique Gardien  Daniel Ariztegui  Frdric Caupin 《Geostandards and Geoanalytical Research》2020,44(2):243-264

Halite traps inclusions of the mother fluid when precipitating. When unchanged, the density of these fluid inclusions (FIs) records the water temperature T_f at the time of crystal formation. As halite is ubiquitous on Earth and geological time, its FIs possess a high potential as temperature archives. However, the use of FIs in halite as an accurate palaeothermometer has been hampered due to limitations of microthermometry, the most commonly used analytical method. Here, we show how Brillouin spectroscopy in halite FIs bypasses these limitations and allows recovering T_f to within 1 °C or less. To demonstrate this, we measured samples synthesised at 24.6 ± 0.5 °C and 33 ± 1 °C, and obtained 24.8 ± 0.4 °C and 31.9 ± 0.4 °C, respectively. This novel approach thus provides an accurate palaeothermometer for lacustrine and marine environments. Moreover, Brillouin spectroscopy solves the long‐standing debate on damage of halite fluid inclusions through quantifying the acceptable temperature excursion for preserving elastic behaviour: [l/(1 µm)]^?0.64 × (90 °C), where l is the FI size. This threshold is lower for FIs close to the surface of the host crystal or to another FI. We also list ‘best practices’ for applying both microthermometry and Brillouin thermometry.  相似文献   

Theoretical investigation of interstellar C–C–O and C–O–C bonding backbone molecules     

Emmanuel E. Etim  Prasanta Gorai  Ankan Das  Elangannan Arunan 《Astrophysics and Space Science》2018,363(1):6

There are numerous complex organic molecules containing carbon and oxygen atoms which show either C–C–O or C–O–C bonding backbone. This paper examines altogether 51 C–C–O and C–O–C bonding backbone molecules from ten different isomeric groups (C₂H₂O, C₃H₂O, C₂H₄O, C₂H₄O₂, C₃H₄O, C₂H₆O, C₂H₆O₂, C₃H₆O, C₃H₆O₂, C₃H₈O) to summarize the present astronomical status of these molecules. Accurate calculations of enthalpy of formation of these molecules show that the isomers with C–C–O backbone are more stable than the C–O–C backbone. Interestingly, a detailed analysis of relevant astromolecules indicates that most of the observed astromolecules have the C–C–O backbone. As a matter of fact, of all the molecules examined in this study, 80% of the astronomically observed species have the C–C–O backbone while only 20% have the C–O–C backbone. In general, interstellar abundance of a molecule is controlled by some factors such as kinetics, formation and destruction pathways,thermodynamics etc. A proper consideration of these factors could explain the observed abundances of these molecules. All these possible key factors are discussed in this paper.  相似文献   

Influence of food supply on the δ13C signature of mollusc shells: implications for palaeoenvironmental reconstitutions     

Franck Lartaud  Laurent Emmanuel  Marc de Rafelis  Stephane Pouvreau  Maurice Renard 《Geo-Marine Letters》2010,30(1):23-34

Compared to oxygen isotopes, the carbon isotope composition of biogenic carbonates is less commonly used as proxy for palaeoenvironmental reconstructions because shell δ¹³C is derived from both dissolved inorganic (seawater) and organic carbon sources (food), and interactions between these two pools make it difficult to unambiguously identify any independent effect of either. The main purpose of this study was to demonstrate any direct impact of variable food supply on bivalve shell δ¹³C signatures, using low/high rations of a ¹³C-light mixed algal diet fed to 14-month-old (adult) cultured Japanese Crassostrea gigas under otherwise essentially identical in vitro conditions during 3 summer months (May, June and July 2003, seawater temperature means at 16, 18 and 20 °C respectively) in experimental tanks at the Argenton laboratory along the Brittany Atlantic coast of France. At a daily ration of 12% (versus 4%) oyster dry weight, the newly grown part of the shells (hinge region) showed significantly lower δ¹³C values, by 3.5‰ (high ration: mean of −5.8  ± 1.1‰, n = 10; low ration: mean of −2.3  ± 0.7‰, n = 6; ANOVA Scheffe’s test, p < 0.0001). This can be explained by an enhanced metabolic activity at higher food supply, raising ¹³C-depleted respiratory CO₂ in the extrapallial cavity. Based on these δ¹³C values and data extracted from the literature, and assuming no carbon isotope fractionation between food and shell, the proportion of shell metabolic carbon would be 26  ± 7 and 5  ± 5% for the high- and low-ration C. gigas shells respectively; with carbon isotope fractionation (arguably more realistic), the corresponding values would be 69  ± 14 and 24  ± 9%. Both groups of cultured shells exhibited lower δ¹³C values than did wild oysters from Marennes-Ol éron Bay in the study region, which is not inconsistent with an independent influence of diet type. Although there was no significant difference between the two food regimes in terms of δ¹⁸O shell values (means of 0.1  ± 0.3 and 0.4  ± 0.2‰ at high and low rations respectively, non-significant Scheffe’s test), a positive δ¹³C vs. δ¹⁸O relationship recorded at high rations supports the interpretation of a progressive temperature-mediated rise in metabolic activity fuelled by higher food supply (in this case reflecting increased energy investment in reproduction), in terms not only of δ¹³C (metabolic signal) but also of δ¹⁸O (seawater temperature signal). Overall, whole-shell δ¹⁸O trends faithfully recorded summer/winter variations in seawater temperature experienced by the 17-month-old cultured oysters.  相似文献   

River profile evolution by plucking in lithologically heterogeneous landscapes: Uniform uplift vs. tilting     

Emmanuel J. Gabet 《地球表面变化过程与地形》2020,45(7):1579-1588

Recent studies provide a theoretical framework for understanding the incision of bedrock rivers by plucking. These studies motivated the development of a numerical model that simulates plucking to explore the evolution of channel profiles in lithologically diverse terrain. In the main governing equation, the incision rate is calculated as a function of the difference between the boundary shear stress and a threshold shear stress needed to entrain blocks from the bed. Because an earlier study suggested that plucking is the primary incisional process in the northern Sierra Nevada (CA), the model was calibrated to approximate the conditions in the region. The profiles of the simulated rivers are stair-stepped, with sharp breaks-in-slope at lithological boundaries. This characteristic is common to rivers draining the northern Sierra Nevada, suggesting that the size of blocks available for plucking, as mediated by the fracture density, may be the primary control on their gradients. Moreover, the numerical experiments highlight the role of threshold shear stresses in the post-orogenic persistence of steep reaches and relict terrain. Finally, comparisons of profiles evolved under tilting or uniform uplift scenarios provide insights into how these different uplift modes affect profile evolution. For example, whereas uniform uplift generates a single migrating knickpoint at the range front, multiple migrating knickpoints can form simultaneously along a river in a tilting landscape. © 2020 John Wiley & Sons, Ltd.  相似文献   

Absolute calibration of a photoelectric condensation nucleus counter at low values of nucleus concentration     

Marion B. Emmanuel  Patrick Squires 《Pure and Applied Geophysics》1969,72(1):268-283

Summary A new absolute condensation nucleus counter was constructed to investigate the accuracy of the calibration widely used with the Pollak-Nolan photoelectric condensation nucleus counter. An attempt was made to standardize the conditions affecting calibration and, using the new counter, to recalibrate the photoelectric counter at values of extinction less than 16%.Over this extinction range, the present work indicates nucleus concentrations which are higher by about 30% than those given by the calibration ofPollak andMetnieks [8]³). In view of the great natural variability of Aitken nucleus concentrations, this discrepancy, if real, is of little meteorological importance.  相似文献   

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)     

Emmanuel Skourtsos  Daniel Vachard  Alexandra Zambetakis-Lekkas  Rossana Martini  Louisette Zaninetti 《Comptes Rendus Geoscience》2002,334(12):925-931

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

Functioning of the avalanche starting zones which undergo snow-transport by wind: Field observations and computer modeling     

F. Sivardière  T. Castelle  G. Guyomarc'h  L. Mérindol  L. Buisson 《Surveys in Geophysics》1995,16(5-6):729-741

For two years, three French and Swiss laboratories have been making field observations and measurements on two high altitude slopes in a Northern French Alps site. The aim of this work is to study the functioning of the avalanche sites which, in their starting zones, undergo snow-transport by wind. The experimental site is located in the French Alps, at 2,800 m, above Grenoble. It is an open area, equipped with an automatic meteorological station and an altitude laboratory. The two slopes that are studied face East. One of them is artificially released but the other has a natural avalanche activity. The investigations concern:

-snow deposition in avalanche starting zones;

-temporal evolution of the snowpack characteristics;

-avalanche release.

For the field observations and measurements, continuous recording of the meteorological conditions on the site, photogrammetrical techniques and two snow depth profiles, as well as stratigraphical snow profiles and video are used. The computer modeling is based on existing computer models developed by the CEMAGREF-Nivologie (ELSA) and the CEN/Météo-France (SAFRAN-CROCUS-MEPRA), which analyse the snowpack and its stability. The field observations and measurements aim at improving snow-transport by wind modeling modules, in order to improve their whole analysis.  相似文献   

Distribution of mercury and methylmercury in deep-sea surficial sediments of the Mediterranean Sea     

Nives Ogrinc  Mathilde Monperrus  Jože Kotnik  Vesna Fajon  Klara Vidimova  David Amouroux  David Kocman  Emmanuel Tessier  Suzana Žižek  Milena Horvat 《Marine Chemistry》2007

  相似文献   

Potential of Argo Drifters for Estimating Biological Production within the Water Column     

SeungHyun Son  Emmanuel Boss  Jae Hoon Noh 《Ocean Science Journal》2006,41(2):121-124

Argo drifters provide information of the vertical structure in the water column and have a potential for the improvement of understanding phytoplankton primary production and biogeochemical cycles in combination with ocean color satellite data, which can obtain the horizontal distribution of phytoplankton biomass in the surface layer. Our examples show that using Argo drifters with satellite-measured horizontal distribution of phytoplankton biomass at the sea surface allow an improved understanding of the development of the spring bloom. The other possible uses of Argo drifter are discussed.  相似文献   

On ionospheric disturbances caused by the solar activity of November 1960     

Michael Anastassiades  Demetrius Ilias  Emmanuel Tsagakis 《Pure and Applied Geophysics》1962,51(1):142-146

Summary On November 1960 a special solar activity occured, producing characteristic disturbances in the ionosphere. Athens center followed this activity by vertical sounding and by Riometer recordings. They are evidences for proton events producing deep absorption in the ionosphere and aurora extending till 38° latitude. Some observations concerning July 1961 solar activity are reported. World wide decrease of the maximum electron density reported during the November period was observed also in Athens. Ionospheric disturbances following vertical sounding observations are of «negative» type.  相似文献