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1.
Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg0, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   
2.
Structural sliding stability of gravity dams is generally quantified using deterministic factor of safety, FSdet. Large FSdet (e.g. 3 in normal condition), are used in existing guidelines to guard against material and load uncertainties. Some guidelines allow an arbitrary reduction in FSdet (e.g. 2) when the knowledge in strength parameters increases from material test data. Yet, those reduced FSdet are not based on a rational consideration of uncertainties. Propagation of uncertainties could be done using probabilistic analyses, such as Monte-Carlo simulations (MC) which are complex and challenging for practical use. There is thus a need to develop simplified reliability based safety assessment procedures that could rationalise the adjustment of FSdet. This paper presents a progressive analysis methodology using four safety evaluation formats of increasing complexity: (i) deterministic, (ii) semi-probabilistic (partial coefficient), (iii) reliability based Adjustable Factor of Safety (AFS), and (iv) probabilistic. Comprehensive comparisons are made for the sliding safety evaluation of a 80 m gravity dam. Results are presented in terms of sliding factors of safety, allowable water levels, and demand/capacity ratios. It is shown that the AFS formulation, using direct integration, is simple and practical to use in complement to existing dam safety guidelines before undertaking MC simulations.  相似文献   
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The Dominican Republic has a high level of seismic activity, and a new seismic network has been installed to improve the detection of earthquakes. The network has been operated by Instituto Politécnico Loyola since 2012. It uses six new stations of its own, as well as 17 other stations publically available. In this study, we investigate in particular the south-west of the country where no seismic stations have been operating before. We find an area, SE of the Enriquillo Plantain Garden fault (responsible for the 2010 Haiti M7.0 earthquake), with a high seismic activity (M?=?2–4) compared to the surrounding area. This shallow seismicity (except two events around 40 km depth) is not seen in any global catalogs, and it does not seem to be associated with any known faults. However, the region has been under rapid recent uplift since margins between hills and valleys are filled with massive alluvial fans. We made 24 new fault plane solutions using P-polarities and S/P amplitude ratios. The solutions show mainly reverse mechanisms and the P-axis directions are mainly NNE oriented, which is in agreement with a published strain direction from GPS measurements. We conclude that the main cause of the seismicity in our study area is the push of the Beata Ridge against Enriquillo basin and the rest of the Gonave microplate, reflected in the mainly reverse focal mechanisms.  相似文献   
5.
We have organised afield study of ocean tide loading in the northwestern part of France, where tidal amplitudes are known to be among the highest in the world. GPS and gravimetric techniques have already proved their capability to measure such weak and high-frequency signals. In this study, these classical observations are complemented with less usual techniques, such as tiltmeter and Satellite Laser Ranging (SLR) measurements. We present here the preliminary results for a common period of observations spanning from 12–19 May 2004. Additional measurements from the French Transportable Laser Ranging Station (FTLRS) were available during September and October 2004. Observation residuals are computed as the difference between the observed and the predicted time signals. We obtain small RMS residuals for GPS measurements (2.5/3.1/4.5 mm for the eastward, northward and upward components), for absolute and relative gravimetry (9 nm/s2 and 13 nm/s2) and for tiltmeters (0.05 μrad for EW component). We also fit the amplitude of the main M2 tidal constituent to FTLRS observations and we find a value of 3.731 cm, which is comparable to the theoretical value.  相似文献   
6.
One of the two objectives of the Vemanaute cruise of the French deep submersible Nautile, was the geological study of the eastern intersection area between the Mid-Atlantic Ridge (MAR) and the Vema Fracture Zone in the equatorial Atlantic. Fourteen dives were conducted that allowed detailed geological survey and sampling of the main morphostructural units of this area: the northern and southern walls of the fracture zone, the median ridge, the northern and southern troughs and the nodal basin. In situ observations of recent tectonic features such as furrows, ridges and circular depressions, concentrated within the southern trough, allowed us to establish the location and the size of the present-day displacement zone. Geological investigations have shown that the nodal basin is entirely floored by basalts thus contrasting with other equivalent areas such as the Kane and Oceanographer fracture zone-MAR eastern intersections. Finally, this study stresses the great opposition between the relatively old and tectonically inactive northern part of the fracture, and the southern part which shows active tectonics and recent volcanic activity.  相似文献   
7.
Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate.Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related?The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.  相似文献   
8.
As marine spatial planning is developing, prompted by the European Union through common principles prescribed in a road map, it is important to disseminate and analyse what has been put forward as the French experience in this field. Hence, the experience of the schémas de mise en valeur de la mer immediately proves to be original in its framework and deeply rooted in French specificities. However, a further analysis of this procedure implemented over several decades highlights the perspectives that would be worth integrating into French and European considerations. This paper thus provides information referring to the SMVM experience, presents an analysis of its results, and attempts to draw lessons from it with regard to recent developments in French marine policy.  相似文献   
9.
The use of shake maps in terms of macroseismic intensity in earthquake early warning systems as well as intensity based seismic hazard assessments provides a valuable supplement to typical studies based on recorded ground motion parameters. A requirement for such applications is ground motion prediction equations (GMPE) in terms of macroseismic intensity, which have the advantages of good data availability and the direct relation of intensity to earthquake damage. In the current study, we derive intensity prediction equations for the Vrancea region in Romania, which is characterized by the frequent occurrence of large intermediate depth earthquakes giving rise to a peculiar anisotropic ground shaking distribution. The GMPE have a physical basis and take the anisotropic intensity distribution into account through an empirical regional correction function. Furthermore, the relations are easy to implement for the user. Relations are derived in terms of epicentral, rupture and Joyner–Boore distance and the obtained relations all provide a new intensity estimate with an uncertainty of ca. 0.6 intensity units.  相似文献   
10.
This article focuses on modeling the strain hardening‐softening response of statically compacted silty sand as observed from a comprehensive series of suction‐controlled, consolidated‐drained triaxial tests accomplished in a fully automated, double‐walled triaxial test system via the axis‐translation technique. The constitutive model used in this work is based on the theory of Bounding Surface (BS) plasticity and is formulated within a critical state framework. The essential BS model parameters are calibrated using the full set of triaxial test results and then used for predictions of compacted silty sand response at matric suction states varying from 50 to 750 kPa. Complementary simulations using the Barcelona Basic Model have also been included, alongside BS model predictions, in order to get further enlightening insights into some of the main limitations and challenges facing both frameworks within the context of the experimental evidence resulting from the present research effort. In general, irrespective of the value of matric suction applied, the Barcelona Basic Model performs relatively well in predicting response at peak and critical state failure under low net confining pressure while the Bounding Surface Model performs relatively well under high net confining pressures.  相似文献   
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