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31.
Small, self‐recording temperature sensors were installed at several heights along a metal rod at five locations in a case study catchment. For each sensor, the presence or absence of snow cover was determined on the basis of its insulating effect and the resulting reduction of the diurnal temperature oscillations. Sensor coverage was then converted into a time series of snow height for each location. Additionally, cold content was calculated. Snow height and cold content provide valuable information for spring flood prediction. Good agreement of estimated snow heights with reference measurements was achieved and increased discharge in the study catchment coincided with low cold content of the snow cover. The results of the proposed distributed assessment of snow cover and snow state show great potential for (i) flood warning, (ii) assimilation of snow state data and (iii) modelling snowmelt process. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
32.
Previous studies have used models of three-dimensional (3D) Boussinesq convection in a rotating spherical shell to explain the zonal flows on the gas giants, Jupiter and Saturn. In this paper we demonstrate that this approach can also generate flow patterns similar to those observed on the ice giants, Uranus and Neptune. The equatorial jets of Uranus and Neptune are often assumed to result from baroclinic cloud layer processes and have been simulated with shallow layer models. Here we show that vigorous, 3D convection in a spherical shell can produce the retrograde (westward) equatorial flows that occur on the ice giants as well as the prograde (eastward) equatorial flows of the gas giants. In our models, the direction of the equatorial jet depends on the ratio of buoyancy to Coriolis forces in the system. In cases where Coriolis forces dominate buoyancy, cylindrical Reynolds stresses drive prograde equatorial jets. However, as buoyancy forces approach and exceed Coriolis forces, the cylindrical nature of the flow is lost and 3D mixing homogenizes the fluid's angular momentum; the equatorial jet reverses direction, while strong prograde jets form in the polar regions. Although the results suggest that conditions involving strong atmospheric mixing are responsible for generating the zonal flows on the ice giants, our present models require roughly 100 and 10 times the internal heat fluxes observed on Uranus and Neptune, respectively.  相似文献   
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34.
Sulfurous acid (H2SO3) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H2SO3 within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H2SO3 at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H2SO3 presumably require cryogenic SO2 or SO2/H2O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H2SO3 which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H2SO3 is present on Io and probably but to a smaller extent on Europa.  相似文献   
35.
Zusammenfassung Eine uns vom Naturhistorischen Museum in Wien freundlicherweise zur Verfügung gestellte Probe des Meteoriten von Steinbach wurde mit einem Elektronenstrahl-Mikroanalysator vom Typ CAMECA qualitativ und quantitativ auf die chemische Zusammensetzung der einzelnen Phasen untersucht.Besonders eingehend wurde dabei die Metallphase analysiert, da diese sich durch die Anwesenheit einer gut ausgebildeten Widmanstättenschen Struktur in Gegenwart von Tridymit als Druckindikator auszeichnet.Die nichtmetallischen Phasen wurden ebenfalls quantitativ bestimmt und ergeben leicht abweichende Ergebnisse von den Analysen vonN. Story-Maskelyne, O. Winkler undF. Heide. Interessant sind vor allem der relativ hohe Mangangehalt in Bronzit und Chromit sowie der Chromgehalt des Troilits.Die Anwendung der neuen Berechnungen über die Abkühlungsgeschichte der Meteoritenmutterkörper vonWood auf unsere quantitativen Analysen ergab eine Abkühlungsgeschwindigkeit von 10°/Million Jahre, was einem Mutterkörper von ca. 50–90 km Durchmesser und einem Zentraldruck von 200 b entspricht.
Summary A sample of the meteorite of Steinbach, made available by the Naturhistorisches Museum at Vienna, has been analyzed qualitatively and quantitatively by a CAMECA electron-beam microanalyzer.Detailed examination has been made on the structure of the metal phase, as the presence of a well-grown Widmanstätten-structure in contact with trydimite as a pressure-indicator is a direct proof for the formation of the Widmanstätten-structure without pressure.The nonmetallic phases have been analyzed quantitatively and the results are slightly different from those ofStory-Maskelyne, Winkler andHeide. Very interesting is the relatively high content of manganese in bronzite and chromite, also the chromium content of troilite.The application of the new computations ofWood, dealing with the cooling history of meteorite-parentbodies to our quantitative analyses indicate a cooling rate of 10° C/Million years, according to a parentbody of appr. 50–90 km diameter and a central pressure of appr. 200 b.


Mit 8 Textabbildungen

Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet.  相似文献   
36.
This study presents a meta-analysis of radiocarbon ages for the environs of Göbekli Tepe – one of the oldest monumental structures worldwide – using cumulative probability functions to diachronically assess phases of geomorphodynamic activity as controlled by natural or anthropogenic drivers. We employ sediment cascades as a heuristic framework to study the complex responses of the geomorphological system to various triggers at local to supra-regional scales. Possible triggers include climatic variability as documented by supra-regional hydroclimatic proxy data, regional demographic trends, and local to regional socioeconomic developments such as the emergence of sedentism or the introduction and dispersal of livestock herding. Our results show that phases of intensified geomorphodynamic activity occurred between ca. 7.4–7.0 and 5.8–3.3 ka BP. These phases roughly coincide with phases of population growth in southern Turkey and climatic variations in Turkey and the Levant. The phase between ca. 5.8–3.3 ka BP also corresponds to the time when organized agriculture and the seeder plough were introduced. Also, the identified phases are in agreement with the general trend of varying geomorphodynamic activity in the Eastern Mediterranean as driven by human impact and climatic change. However, neither the Younger Dryas–Holocene transition nor the development of herding during the Pre-Pottery Neolithic left a clear signature. We demonstrate how the different depositional environments in the studied landscape compartments vary with respect to their spatiotemporal coverage and discuss challenges when trying to understand processes that once shaped landscapes of past societies. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   
37.
The production of coarse sediment in mountain landscapes depends mainly on the type and activity of geomorphic processes and topographic and natural conditions (e.g. vegetation cover) of these catchments. The supply of sediment from these slopes to mountain streams and its subsequent transport lead to sediment connectivity, which describes the integrated coupled state of these systems. Studies from the Northern Calcareous Alps show that the size of the sediment contributing area (SCA), a subset of the drainage area that effectively delivers sediment to the channel network, can be used as a predictor of sediment delivery to mountain streams. The SCA concept is delineated on a digital elevation model (DEM) using a set of rules related to the steepness and length of slopes directly adjacent to the channel network, the gradient of the latter and the vegetation cover. The present study investigates the applicability of this concept to the Western Alps to identify geomorphologically active areas and to estimate mean annual sediment yield (SY) in mainly debris-flow-prone catchments. We use a statistical approach that shows a parameter optimisation and a linear regression of SY on SCA extent. We use a dataset of ~25 years of assessed coarse sediment accumulation in 35 sediment retention basins. In the investigated catchments, sediment transport is governed by several factors, mainly by the extent of vegetation-free areas with a minimum slope of 23° that is coupled to the channel network with a very low gradient of the latter. With our improved framework, we can show that the SCA approach can be applied to catchments that are widely distributed, in a large spatial scale (hectare area) and very heterogeneous in their properties. In general, the investigated catchments show high connectivity, resulting in significant correlations between long-term average yield and the size of the SCA.  相似文献   
38.
The Rocabruna and Coll de Pal barite deposits, located in the eastern Pyrenees of Spain, fill karstic cavities within carbonate rocks of Cambrian and Devonian age, respectively. The deposits contain barite, chalcopyrite, tetrahedrite, pyrite and minor sphalerite and galena with saddle dolomite and quartz as gangue. Fluid inclusion data from Coll de Pal quartz and dolomite indicate that the mineralizing fluid was a polysaline CaCl2-rich brine, with temperatures between 125 and 150 °C. C and O isotopic compositions of carbonates in both deposits are consistent with a progressive increase in temperature during deposition. The 34S values of barite, which range from 14.2 to 15.9‰ in Coll de Pal, and from 13.9 to 19.3‰ in Rocabruna, together with 87Sr/86Sr ratios ranging from 0.7118 to 0.7168 in Rocabruna, and from 0.7115 to 0.7136 in Coll de Pal, indicate two different fluid sources. We propose that these deposits formed as a result of mixing between a Ba-rich, sulfate-poor hot fluid, and sulfate-rich solutions of surficial origin. The different Sr isotope ratios in the deposits indicate that the hot Ba-rich fluids involved in each deposit were equilibrated with different rock types (carbonates and shales), in agreement with the geology of the two areas. Received: 22 October 1997 / Accepted: 24 March 1998  相似文献   
39.
A shale split in the well-studied Foord Seam (Upper Carboniferous), Stellarton Basin, Nova Scotia, provides a rare opportunity to study little known siderite concretions with anatomically preserved plants from a limnic basin. Siderite concretions occur throughout the split, commonly as sheet-like, inter-connected lepidodendrid logs, or less frequently as spherical masses; they are typically vuggy. A sample of 14 stratigraphically oriented concretions in the split shows that primary siderite varies from 45% to 80% (wt.%) due to selective replacement by 5% to 40% ferroan dolomite or ankerite in plant tissues. These two minerals show large Mg/Fe and Mg/Ca variability and are Fezoned. Clay content ranges from trace to 20%, and quartz from 5% to 10%. Partial cell-wall destruction by erosion and changeable oxic/anoxic conditions, prior to siderite permineralization, resulted in preservation mainly of the more resistant plant tissues. On average, carbon from siderite is isotopically heavier (+4.8±1.9 0/00) than that from ‘dolomite' (−7.2±1.1 0/00). The distribution of and the positive correlation between δ13C and δ18O probably reflects the two fractionation processes associated with methanogenesis and ‘dolomitization', respectively, in the genetic history of the siderite concretions in the split. Siderite concretions formed diagenetically early from bicarbonate under reducing conditions in a slightly alkaline freshwater environment that precluded calcite deposition.  相似文献   
40.
We investigate magnetic phase (trans)formation in the presence of petroleum hydrocarbons and its relation to bacterial activity, in particular in the zone of remediation driven fluctuating water levels at a former military air base in the Czech Republic. In a previous study an increase of magnetite concentration from the groundwater table towards the top of the groundwater fluctuation zone (GWFZ) was reported, however with limited reliability as there was no control on small-scale effects. To recognize statistically significant magnetic signatures versus depth, we obtained multiple sediment cores from three locations in January 2011 and April 2012, penetrating the unsaturated zone, the GWFZ and the uppermost one meter below the groundwater level (~2.3 m depth at the time of sampling). Magnetic concentration variation versus depth was determined by measuring magnetic susceptibility (MS) and remanence parameters. Small-scale features were identified and eliminated by statistical processing of multiple cores. A trend of increasing MS values from the lowermost position of the groundwater table upward was verified and highest magnetic concentration was found at the top of the GWFZ. Magnetic mineralogy indicates that newly formed fine-grained magnetite in the single domain to small pseudo-single domain range is responsible for the MS enhancement confirming previous results. There is no correlation with the depth variation of hydrocarbon (HC) concentrations; however, total organic carbon is linked to MS and may represent a degradation product of HC that is bioavailable for microorganisms. Bacterial activity is likely responsible for magnetite formation as indicated by most probable number (MPN) results of iron-metabolizing bacteria. The comparison of our results with an earlier study conducted at the same site revealed that magnetic concentration clearly decreased since remediation was terminated in 2008, possibly due to dissolution of magnetite.  相似文献   
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