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81.
A.W. Gerhard Kunze 《Physics of the Earth and Planetary Interiors》1974,8(4):375-387
The settling trends of 318 lunar mare craters are compared with predictions of numerical finite-element models in order to determine the creep response of the upper lunar mare crust. No settling is evident in craters smaller than 5 km in diameter. Settling rates of larger craters increase as function of crater size in a manner suggesting a non-linear lunar creep response corresponding to the power law where έ is the strain rate and σ is the differential stress. However, the observed nonlinearity is probably an apparent nonlinearity resulting from the temperature induced viscosity decrease with depth due to a lunar crustal temperature gradient of 3° C/km and a creep activation energy of 20 kcal/mole. It is concluded that creep in the lunar medium is essentially Newtonian, and that the effective viscosity of the upper lunar mare crust is (1.6 ± 0.3) · 1025 poise. 相似文献
82.
A new 2 \(\frac{1}{2}\) -octahedral sheet silicate, NaMg2.5 Si4O10 (OH)2, has been synthesized from oxide mixtures in the temperature range 500–600°C at pressures between 1 and 5 kb. The lattice parameters are a 0 = 5.298 Å, b 0 = 9.047 Å, c 0 = 9.479 Å and ß=99.55°. X-ray data are given in the text. At temperatures above 605° C/1 kb and 630° C/5 kb, it decomposes to magnesiorichterite plus quartz. 相似文献
83.
Giancarlo Bellucci Joern Helbert Francesca Altieri Dennis Reiss Jean-Pierre Bibring Stephan van Gasselt Harald Hoffmann Yves Langevin Gerhard Neukum Franois Poulet 《Icarus》2007,192(2):361-377
In this paper we report about a small region on the northern scarp of Olympus Mons showing an increase of the 3 μm hydration band in the OMEGA spectra, together with low superficial temperatures. Although water ice clouds can occurs on the flank of big martian volcanoes, radiative transfer modeling indicates that atmospheric water ice alone cannot justify the shape of the observed band. A fit of the 1.9–3 μm absorption features is obtained by hypothesizing that the study region consists of a mixture of dust and water ice covered by an optically thin (τ=0.08 at 3 μm) layer of dust. Thermal modeling also suggests that water ice in this region may be stable during most of the martian year due to the saturation of the atmosphere. If water ice is responsible for the observed spectral behavior, it might consist of a number of ice or snow patches possibly deposited in small depressions. 相似文献
84.
85.
Antonie Haas Crispin T.S. Little Heiko Sahling Gerhard Bohrmann Tobias Himmler Jörn Peckmann 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(2):283-293
Vestimentiferan tube worms are prominent members of modern methane seep communities and are totally reliant as adults on symbiotic sulphide-oxidizing bacteria for their nutrition. The sulphide is produced in the sediment by a biochemical reaction called the anaerobic oxidation of methane (AOM). A well-studied species from the Gulf of Mexico shows that seep vestimentiferans ‘mine’ sulphide from the sediment using root-like, thin walled, permeable posterior tube extensions, which can also be used to pump sulphate and possibly hydrogen ions from the soft tissue back into the sediment to increase the local rate of AOM. The ‘root-balls’ of exhumed seep vestimentiferans are intimately associated with carbonate nodules, which are a result of AOM. We have studied vestimentiferan specimens and associated carbonates from seeps at the Kouilou pockmark field on the Congo deep-sea fan and find that some of the posterior ‘root’ tubes of living specimens are enclosed with carbonate indurated sediment and other, empty examples are partially or completely replaced by the carbonate mineral aragonite. This replacement occurs from the outside of the tube wall inwards and leaves fine-scale relict textures of the original organic tube wall. The process of mineralization is unknown, but is likely a result of post-mortem microbial decay of the tube wall proteins by microorganisms or the precipitation from locally high flux of AOM derived carbonate ions. The aragonite-replaced tubes from the Kouilou pockmarks show similar features to carbonate tubes in ancient seep deposits and make it more likely that many of these fossil tubes are those of vestimentiferans. These observations have implications for the supposed origination of this group, based on molecular divergence estimates. 相似文献
86.
87.
Previous studies of mid-Ordovician limestone in Sweden have shown that over a stratigraphic interval representing a few million years there is a two orders-of-magnitude enrichment in fossil L-chondritic meteorites (Ø = 1-21 cm) and sediment-dispersed extraterrestrial chromite (EC) grains (>63 μm). This has been interpreted as a dramatic increase in the flux of L-chondritic matter to Earth following the breakup of the L-chondrite parent body, which based on Ar-Ar gas retention ages (470 ± 6 Ma) of recently fallen meteorites occurred at about this time. Here we show that the general trend in the distribution of sediment-dispersed EC grains can be reproduced in the Puxi River section in central China. A total of 288 kg of limestone was searched for chrome spinels. In samples spanning the lower 8 m of the section, representing the Paroistodus originalis and Lenodus antivariabilis conodont zones, a total of 110 kg of limestone yielded only one EC grain. Similarly to the Swedish sections, EC grains begin to be common in the overlying L. variabilis Zone and remain common throughout the upper 9 m of the section, representing the L. variabilis, Yangtzeplacognathus crassus and L. pseudoplanus zones. In this part of the section 178 kg of limestone yielded 290 EC grains, with an average chemical composition very similar to chromite from recent L chondrites. In most of the beds over this interval one finds 1-4 EC grains per kilogram rock, a clear two orders-of-magnitude enrichment relative to the lower part of the section. Small bed-by-bed variations in the EC content over the upper interval most likely reflect small variations in sedimentation rates. The Puxi River section contains only very rare terrestrial chrome spinel grains, which can be distinguished already by their rounded, abraded appearance compared to the angular, pristine extraterrestrial spinels. In the mid-Ordovician, based on paleoplate reconstructions, the Puxi River site was positioned at mid-latitudes on the southern hemisphere a couple of thousand kilometers east of the Swedish sites. The prominent enrichment of EC grains over the same stratigraphic interval in China and Sweden is supporting evidence for a dramatic increase in the flux of L-chondritic matter to Earth shortly after the disruption of the L-chondrite parent body in the asteroid belt. 相似文献
88.
In most natural sedimentary systems labile and refractory organic material (OM) occur concomitantly. Little, however, is known on how different kinds of OM interact and how such interactions affect early diagenesis in sediments. In a simple sediment experiment, we investigated how interactions of OM substrates of different degradability affect benthic nitrogen (N) dynamics. Temporal evolution of a set of selected biogeochemical parameters was monitored in sandy sediment over 116 days in three experimental set-ups spiked with labile OM (tissue of Mytilus edulis), refractory OM (mostly aged Zostera marina and macroalgae), and a 1:1 mixture of labile and refractory OM. The initial amounts of particulate organic carbon (POC) were identical in the three set-ups. To check for non-linear interactions between labile and refractory OM, the evolution of the mixture system was compared with the evolution of the simple sum of the labile and refractory systems, divided by two. The sum system is the experimental control where labile and refractory OM are virtually combined but not allowed to interact. During the first 30 days there was evidence for net dissolved-inorganic-nitrogen (DIN) production followed by net DIN consumption. (Here ‘DIN’ is the sum of ammonium, nitrite and nitrate.) After 30 days a quasi steady state was reached. Non-linear interactions between the two types of OM were reflected by three main differences between the early-diagenetic evolutions of nitrogen dynamics of the mixture and sum (control) systems: (1) In the mixture system the phases of net DIN production and consumption commenced more rapidly and were more intense. (2) The mixture system was shifted towards a more oxidised state of DIN products [as indicated by increased (nitrite + nitrate)/(ammonium) ratios]. (3) There was some evidence that more OM, POC and particulate nitrogen were preserved in the mixture system. That is, in the mixture system more particulate OM was preserved while a higher proportion of the decomposed particulate N was converted into inorganic N. It can be concluded that during the first days and weeks of early diagenesis the magnitude and composition of the flux of decompositional dissolved N-compounds from sediments into the overlying water was influenced by non-linear interactions of OM substrates of different degradability. Given these experimental results it is likely that the relative spatial distributions of OM of differing degradability in sediments control the magnitude and composition of the return flux of dissolved N-bearing compounds from sediments into the overlying water column. 相似文献
89.
Thomas Pape André Bahr Janet Rethemeyer John D. Kessler Heiko Sahling Kai-Uwe Hinrichs Stephan A. Klapp William S. Reeburgh Gerhard Bohrmann 《Chemical Geology》2010,269(3-4):350-363
Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C1–C4, CO2]). Molecular ratios of LMWHC (C1/[C2 + C3] > 1000) and stable isotopic compositions of methane (δ13C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C1/C2+ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C1–C4, CO2]) relative to the other gas types and the virtual lack of 14C–CH4 indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C1–C4, CO2)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of 14C–CH4 (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area. 相似文献
90.
Friedrich Lucassen Peter Dulski Rainer Abart Gerhard Franz Dieter Rhede Rolf L. Romer 《Contributions to Mineralogy and Petrology》2010,160(2):279-295
Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry. 相似文献