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41.
The degree to which the hydrologic water balance in a snow-dominated headwater catchment is affected by annual climate variations is difficult to quantify, primarily due to uncertainties in measuring precipitation inputs and evapotranspiration (ET) losses. Over a recent three-year period, the snowpack in California's Sierra Nevada fluctuated from the lightest in recorded history (2015) to historically heaviest (2017), with a relatively average year in between (2016). This large dynamic range in climatic conditions presents a unique opportunity to investigate correlations between annual water availability and runoff in a snow-dominated catchment. Here, we estimate ET using a water balance approach where the water inputs to the system are spatially constrained using a combination of remote sensing, physically based modelling, and in-situ observations. For all 3 years of this study, the NASA Airborne Snow Observatory (ASO) combined periodic high-resolution snow depths from airborne Lidar with snow density estimates from an energy and mass balance model to produce spatial estimates of snow water equivalent over the Tuolumne headwater catchment at 50-m resolution. Using observed reservoir inflow at the basin outlet and the well-quantified snowmelt model results that benefit from periodic ASO snow depth updates, we estimate annual ET, runoff efficiency (RE), and the associated uncertainty across these three dissimilar water years. Throughout the study period, estimated annual ET magnitudes remained steady (222 mm in 2015, 151 mm in 2016, and 299 mm in 2017) relative to the large differences in basin input precipitation (547 mm in 2015, 1,060 mm in 2016, and 2,211 mm in 2017). These values compare well with independent satellite-derived ET estimates and previously published studies in this basin. Results reveal that ET in the Tuolumne does not scale linearly with the amount of available water to the basin, and that RE primarily depends on total annual snowfall proportion of precipitation.  相似文献   
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Naphthalene (C10H8), several other hydrocarbons, mostly derivates of naphthalene, and bromine oxide (BrO) were analyzed for narrow band (0.01 nm) absorption lines in the wavelength range between 307.7 and 308.3 nm to study their potential impact on OH radical measurements by differential absorption spectroscopy.Only naphthalene showed narrow band absorption lines in this wavelength region. From nine naphthalene lines the differential absorption cross-section was determined.The strongest naphthalene line at 308.002 nm is close to the Q 1(2) OH line, but about a factor of 200 weaker (=(65.2±15.3)×10-20 cm2/molec). The corresponding detection limit for naphthalene is about 15 ppt. We re-evaluated some spectra of our OH measurement campaign in July 1987 with respect to naphthalene and obtained an upper limit of 30 ppt for its concentration.BrO was recorded in the larger wavelength interval between 307.7 and 308.7 nm. Structured absorptions were only observed at wavelengths above 308.2 nm and no significant structures were found in the vicinity of the Q 1(2) and Q 1(3) OH lines.  相似文献   
44.
Ice-rafted debris (IRD) (>2 mm), input in eight sediment cores along the Eurasian continental margin (Arctic Ocean), have been studied over the last two glacial/interglacial cycles. Together with the revised chronologies and new micropaleontological data of two cores from the northern Barents Sea (PS2138) and northeastern Kara Sea (PS2741) spanning Marine Isotope Stages (MIS) 6 to 1, the IRD data give new insights into the glacial history of northern Eurasian ice-sheets over the last 150 ka. The chronologies of the cores are based on stable isotope records, AMS 14C datings, paleomagnetic and biostratigraphic data.Extensive episodes of northern Barents Sea ice-sheet growth, probably to the shelf edge, occurred during the late Weichselian (MIS 2) and the Saalian (MIS 6). Major IRD discharge at the MIS 4/3-transition hints to another severe glaciation, probably onto the outer shelf, during MIS 4. IRD-based instabilities of the marine-based ice margin along the northern Barents Sea between MIS 4 and 2 are similar in timing with North Atlantic Heinrich events and Nordic Seas IRD events, suggesting similar atmospheric cooling over a broad region or linkage of ice-sheet fluctuations through small sea-level events.In the relatively low-precipitation areas of eastern Eurasia, IRD peak values during Termination II and MIS 4/3-transition suggest a Kara Sea ice-sheet advance onto the outer shelf, probably to the shelf edge, during glacial MIS 6 and 4. This suggests that during the initial cooling following the interglacials MIS 5, and possibly MIS 7, the combined effect of sustained inflow of Atlantic water into the Arctic Ocean and penetration of moisture-bearing cyclones into easterly direction supported major ice build-up during Saalian (MIS 6) and Mid-Weichselian (MIS 4) glaciation. IRD peak values in MIS 5 indicate at least two advances of the Severnaya Semlya ice-sheet to the coast line during the Early Weichselian. In contrast, a distinct Kara Sea ice advance during the Late Weichselian (MIS 2) is not documented by the IRD records along the northeastern Kara Sea margin.  相似文献   
45.
The conversion gain of optical and infrared focal plane CMOS hybrid arrays is a fundamental parameter, whose value computes into the derivation of other parameters characterizing the performance of a detector. The widespread “noise squared versus signal” method used to obtain the conversion gain can overestimate the nodal capacitance of the detector pixel by more than 20% for infrared arrays and by more than 100% for Si-PIN diode arrays. This is because this method does not take account of the capacitive coupling between neighboring pixels. A simple technique has been developed to measure the nodal capacitance directly by comparing the voltage change of an external calibrated capacitor with the voltage change on the nodal capacitor of the detector pixel. The method is elaborated in detail and has been verified with a Si-PIN diode array hybridized to a Hawaii-2RG multiplexer using an Fe 55 X-ray source. It is also in good agreement with a stochastic method based on 2D autocorrelation.  相似文献   
46.
Rock varnish has a long history of study in Australia. Although Australian varnishes have biological, chemical and morphological similarities to varnishes in other continents, rock varnishes in arid Australia tend to be less stable than in other drylands. Still, with careful sampling, radiocarbon and cation‐ratio dating of rock varnish has been used to constrain the age of Henbury Meteor Craters, Northern Territory, and rock engravings in South Australia and New South Wales, as well as to assess the geomorphic surface stability of Ayers Rock, Northern Territory, and the slopes of Pepuarta Bluff in the Olary Province of South Australia.  相似文献   
47.
Li, Be, B and δ7Li SIMS analyses of plagioclase phenocrysts from the 1040–1941 Niki dacite lava (Nea Kameni, Santorini, Greece) exhibit varied processes. From their anorthite contents alone, the crystals may be segregated into four main types: type-N shows the normal decline in An during crystallisation (An62–40); type-O has only oscillatory zoning accompanied by resorption surfaces (An58–39); type-C is complex with high-An cores (subtype C1: An64–58, subtype C2: An88–73) and normal rims (An55–42). Type-A plagioclase with high An content (An92–82) is found within mafic enclaves. On the basis of their Li concentrations, type-O crystals may be subdivided into subtype O1 with flat Li concentration profiles and subtype O2 with decreasing Li concentration from core to rim. The concentrations of Be and B of all four types show a negative correlation with anorthite content (An), but Li concentration profiles differ amongst the different plagioclase types. Types N and O1, and the cores of type-C, are equilibrated in Li concentration. Types O2 and A, and the mantles of type-C display an initial enrichment in Li, probably from volatile influx into the melt. Consistent with the propensity towards equilibrium with the melt, these crystals display dramatic rim-ward declines in Li concentration. All analysed plagioclase crystals, except for the xenocrystic type-A, have nearly the same Li, Be and B concentrations at their rims. These coincide with the composition of plagioclase microlites in the groundmass, thereby affording estimates of plagioclase-melt partitioning for the light elements: K Li = 0.19–0.28, K Be = 0.24–0.38 and K B = 0.007–0.009. δ7Li profiles in type-O2 and type-A phenocrysts manifest an unmistakable inverse relation to Li concentration, with variations of up to ~39 ‰, revealing preferential kinetic diffusion. This may have been driven by Li loss from the melt, most likely through degassing during decompression, perhaps in the course of magma ascent to subsequent eruption. Considering the rapid diffusion of Li in plagioclase, in situ phenocryst analyses may yield useful information about processes leading up to, or even causing, eruptions.  相似文献   
48.
Galgenbergite-(Ce) from the type locality, the railroad tunnel Galgenberg between Leoben and St. Michael, Styria, Austria, was investigated. There it occurs in small fissures of an albite-chlorite schist as very thin tabular crystals building rosette-shaped aggregates associated with siderite, ancylite-(Ce), pyrite and calcite. Electron microprobe analyses gave CaO 9.49, Ce2O3 28.95, La2O3 11.70, Nd2O3 11.86, Pr2O3 3.48, CO2 30.00, H2O 3.07, total 98.55 wt.%. CO2 and H2O calculated by stoichiometry. The empirical formula (based on Ca + REE ∑3.0) is $ \mathrm{C}{{\mathrm{a}}_{1.00 }}{{\left( {\mathrm{C}{{\mathrm{e}}_{1.04 }}\mathrm{L}{{\mathrm{a}}_{0.42 }}\mathrm{N}{{\mathrm{d}}_{0.42 }}\mathrm{P}{{\mathrm{r}}_{0.12 }}} \right)}_{2.00 }}{{\left( {\mathrm{C}{{\mathrm{O}}_3}} \right)}_4}\cdot {{\mathrm{H}}_2}\mathrm{O} $ , and the simplified formula is $ \mathrm{CaC}{{\mathrm{e}}_2}{{\left( {\mathrm{C}{{\mathrm{O}}_3}} \right)}_4}\cdot {{\mathrm{H}}_2}\mathrm{O} $ . According to X-ray single crystal diffraction galgenbergite-(Ce) is triclinic, space group $ P\overline{1},a=6.3916(5) $ , b?=?6.4005(4), c?=?12.3898(9) Å, α?=?100.884(4), β?=?96.525(4), γ?=?100.492(4)°, V?=?483.64(6) Å3, Z?=?2. The eight strongest lines in the powder X-ray diffraction pattern are [d calc in Å/(I)/hkl]: 5.052/(100)/011; 3.011/(70)/0-22; 3.006/(66)/004; 5.899/(59)/-101; 3.900/(51)/1-12; 3.125/(46)/-201; 2.526/(42)/022; 4.694/(38)/-102. The infrared absorption spectrum reveals H2O (OH-stretching mode at 3,489 cm?1, HOH bending mode at 1,607 cm?1) and indicates the presence of distinctly non-equivalent CO3-groups by double and quadruple peaks of their ν1, ν2, ν3 and ν4 modes. The crystal structure of galgenbergite-(Ce) was refined with X-ray single crystal data to R1?=?0.019 for 2,448 unique reflections (I?>?2σ(I)) and 193 parameters. The three cation sites of the structure Ca(1), Ce(2) and Ce(3) have a modest mixed site occupation by Ca and small amount of REE (Ce, La, Pr, Nd) and vice versa. The structure is based on double layers parallel to (001), which are composed of Ca(1)Ce(2)(CO3)2 single layers with an ordered chessboard like arrangement of Ca and Ce, and with a roof tile-like stacking of the CO3 groups. Perpendicular to (001) the double layers are connected to a triclinic framework structure with good cleavage parallel to (001) by a differently organized and more open part of the structure formed by Ce(3)(CO3)2(H2O). Based on the topology of the CaCe(CO3)2 single layer in galgenbergite-(Ce), structural relationships to rutherfordine, to aragonite and ancylite type minerals, and to lanthanite are outlined.  相似文献   
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Saxicolous species of lichens are able to induce and accelerate weathering of their rock substrate, and effects of lichens on substrate can be attributed to both physical and chemical causes. This paper is focused on biotic weathering actions of epilithic and endolithic species on the different rock types (sandstones and volcanogenic rocks) in Antarctica. The patterns, mechanisms, processes and neoformations of rock-weathering resulting from lichen colonization are expounded in detail. Furthermore, it is pointed out that, for a better understanding of the impacts of lichens on environments, the studies on the rate of biotic weathering and the comprehensive involvement of the lichen effects on weathering of natural rocks remain to be carried out in Antarctica.  相似文献   
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