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211.
Two clay-rich coastal sediment samples have been characterised together with three pure clays identified as major components of the sediment samples. The mineralogy of the sediments was determined by X-ray diffraction, and their bulk properties measured (organic carbon content, leachable iron and manganese, surface area and cation exchange capacity). A simple approach is used to model the properties of the sediments from those of their pure clay components. Good agreement is found for cation exchange capacity and specific surface area indicating that the clay minerals are the most important constituents influencing the sediments' surface properties. Particle size distributions were assessed by conventional grain size analysis, and also by Sedimentation Field-Flow Fractionation (SedFFF). These two approaches yield sharply differing size distributions; in particular, conventional grainsize analysis indicates a much greater proportion of submicron particles. Similar results are obtained from analysis of pure clays. The most likely reason for this is artifacts introduced in the unavoidable 1 m prefractionation used for SedFFF.  相似文献   
212.
Detailed facies analysis of the Neogene successions of the Pishin Belt (Katawaz Basin) has enabled documentation of successive depositional systems and paleogeographic settings of the basin formed by the collision of the northwestern continental margin of the Indian Plate and the Afghan Block. During the Early Miocene, subaerial sedimentation started after the final closure of the Katawaz Remnant Ocean. Based on detailed field data, twelve facies were recognized in Neogene successions exposed in the Pishin Belt. These facies were further organized into four facies associations i.e. channels, crevasse splay, natural levee and floodplain facies associations. Facies associations and variations provided ample evidence to recognize a number of fluvial architectural components in the succession e.g., low‐sinuosity sandy braided river, mixed‐load meandering, high‐sinuosity meandering channels, single‐story sandstone and/or conglomerate channels, lateral accretion surfaces (point bars) and alluvial fans. Neogene sedimentation in the Pishin Belt was mainly controlled by active tectonism and thrusting in response to the oblique collision of the Indian Plate with the Afghan Block of the Eurasian Plate along the Chaman‐Nushki Fault. Post Miocene deformation of these formations successively caused them to contribute as an additional source terrain for the younger formations.  相似文献   
213.
Climate change is expected to have a negative impact on the power system of the Iberian Peninsula; changes in river runoff are expected to reduce hydropower generation, while higher temperatures are expected to increase summer electricity demand, when water resources are already limited. However, these impacts have not yet been evaluated at the peninsular level. We coupled a hydrological model with a power market model to study three impacts of climate change on the current Iberian power system: changes in hydropower production caused by changes in precipitation and temperature, changes in temporal patterns of electricity demand caused by temperature changes, and changes in irrigation water use caused by temperature and precipitation changes. A stochastic dynamic programming approach was used to develop operating rules for the integrated system given hydrological uncertainty. We found that changes in precipitation will reduce runoff, decrease hydropower production (with accompanying increases in thermal generation), and increase irrigation water use, while higher temperatures will shift power demand from winter to summer months. The combined impact of these effects will generally make it more challenging to balance agricultural, power, and environmental objectives in the operation of Iberian reservoirs, though some impacts could be mitigated by better alignment between temporal patterns of irrigation and power demands.  相似文献   
214.
ABSTRACT

Due to more frequent extreme rainfall incidents in recent years, many large cities are considering the construction of new drainage systems to cope with rainfall in the order of 100-year events. In such cases, T-year point rainfall events should be supplemented with areal reduction factors (ARF) to avoid overdesign. To facilitate an initial design, a procedure based on using Chicago Design Storms (CDS) in combination with intensity–duration–area (IDA) curves was developed to produce CDS-ARF input rainfall. By means of the time of concentration, a specific instantaneous unit hydrograph (IUH) was obtained for each subcatchment. Combination of CDS-ARF rains and the subcatchment IUHs using convolution integrals was used to produce inflow hydrographs to the drainage system. A sequential design procedure that successively includes subcatchments for the entire drainage system in the downstream direction is implemented and exemplified ensuring a consistent initial design.  相似文献   
215.
Polarized Fourier-transform infrared and Raman spectra were acquired on an elbaite sample previously characterized by electron- and ion microprobe analysis, X-ray diffraction and structure refinement. Spectra from the two vibrational spectroscopy techniques reveal a close similarity in the OH-stretching region, with three main absorption bands strongly polarized in the c-axis direction. By means of bond-valence theory arguments, the observed OH bands are interpreted and assigned to specific local cation arrangements around the O1 (≡W) and O3 (≡V) anion sites. In combination with the relatively simple composition of the studied sample, bond-valence constraints are used to identify stable anion-cation arrangements, which permit the occurrence of short-range ordering to be assessed. Evidence for nearly complete short-range order at the O1 site, with the stable arrangements Y(LiAlAl)0.6W(OH)0.6 and Y(LiLiAl)0.4W(F)0.4, are presented. These two local arrangements can be further expanded to obtain the larger ordered clusters [W(OH)–Y(LiAl2)–V(OH)3Z(Al)6]0.6 and [W(F)–Y(Li2Al)–V(OH)3Z(Al)6]0.4.  相似文献   
216.
The thermally induced reductive decomposition of a natural near end-member almandine [VIII(Fe2.85Mg0.11Ca0.05Mn0.02)VI(Al1.99)IV(Si2.99)O12] and possible hydrogen diffusion into its structure have been carried out at temperatures up to 1,200°C, monitored by simultaneous thermogravimetric analysis and differential scanning calorimetry (DSC), infrared and 57Fe Mössbauer spectroscopy and X-ray powder diffraction. Below 1,000°C, evidence for hydrogen diffusion into almandine structure was not observed. At temperatures above 1,000°C, reductive decomposition sets in, as displayed by a sharp endothermic peak at 1,055°C on the DSC curve accompanied by a total mass loss of 3.51%. We observe the following decomposition mechanism: almandine + hydrogen → α-Fe + cristobalite + hercynite + water. At higher temperatures, fayalite and sekaninaite are formed by consecutive reaction of α-Fe with cristobalite and water, and cristobalite with hercynite, respectively. The metallic α-Fe phase forms spherical and isolated particles (~1 μm).  相似文献   
217.
In Sweden, knowledge of the location and timing of glacially induced faulting and seismicity is critical to effective engineering of a long-term nuclear disposal facility. To improve understanding and modeling of the complex ice-induced and tectonic stresses associated with glacially induced faulting, field studies detailing the location and timing of movement of such structures are required. Although the fault has not been confirmed in the bedrock, multi-proxy surficial geologic evidence indicates that the recently discovered scarp in Bollnäs is such a structure. Machine-excavated trenches across the scarp reveal landsliding down the scarp and, in one location, faulted and vertically offset fine-grained glacial sediments. The presence of water-escape structures in trenches excavated on a topographic high strongly suggests a co-seismic origin derived from earthquake magnitudes >5.5. Numerous landslides in till exist in the region as well. Four slopes with landslides were examined in detail, and the factors of safety for these slopes indicate stable conditions and suggest a seismic trigger. Basal radiocarbon dates from peat bogs located stratigraphically above the landslides provide minimum limiting ages for the co-seismic landslides. The oldest date indicates sliding prior to 10,180 calendar years before the present. The proposed Bollnäs Fault is 400 km south of the so called Lapland Fault Province. To date, it is the southernmost confirmed glacially induced fault in Sweden. The results of this study are consistent with existing modeling results that indicate fault instability in this region of central Sweden following deglaciation.  相似文献   
218.
Fifty interconnecting loops (ILs) that are induced by new-born active regions are investigated. The formation period of four ILs including two same-hemisphere interconnecting loops (HILs) and two transequatorial loops (TLs) are analyzed. The magnetic flux related with these loops is studied. Considering the active region pairs related with the IL as a magnetic system, the total magnetic flux has a tendency of increasing for this system, the signs of net magnetic flux tend to be opposite for the active region pairs. There is no difference between HILs and TLs in this aspect.  相似文献   
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