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121.
Adverse effects of invasive alien species (IAS), or biological pollution, is an increasing problem in marine coastal waters, which remains high on the environmental management agenda. All maritime countries need to assess the size of this problem and consider effective mechanisms to prevent introductions, and if necessary and where possible to monitor, contain, control or eradicate the introduced impacting organisms. Despite this, and in contrast to more enclosed water bodies, the openness of marine systems indicates that once species are in an area then eradication is usually impossible. Most institutions in countries are aware of the problem and have sufficient governance in place for management. However, there is still a general lack of commitment and concerted action plans are needed to address this problem. This paper provides recommendations resulting from an international workshop based upon a large amount of experience relating to the assessment and control of biopollution.  相似文献   
122.
This 10-year field data study explores the relevance of water level fluctuations in driving the shift from a free-floating plant (FFP) to a phytoplankton dominated state in a shallow floodplain lake from the Lower Paraná River. The multi-year natural flood pulse pattern in the Lower Paraná River drove the ecosystem regime from a FFP-dominant state during very high waters (1998–1999) to absolute phytoplankton prevalence with blooms of nitrogen fixing Cyanobacteria during extreme low waters (2008–2009). Satellite images support the observed changes over the decade and show the decrease of the surface lake area covered by FFP as well as the modification of the spectral firm in open waters, which documents the significant increases in phytoplankton chlorophyll a concentrations. We discuss the possibility that, despite a slow eutrophication in these highly vegetated systems, water level changes and not nutrients account for the shift from a floating macrophyte community to phytoplankton dominance. Cyclic shifts may occur in response to the seasonal floodpulse, but more strongly, as indicated by our results, in association to the extreme drought and flood events related to the El Niño Southern Oscillation, which is linked to discharge anomalies in the Paraná River.  相似文献   
123.
124.
Bioavailability and toxicity of antimony   总被引:1,自引:0,他引:1  
Antimony (Sb) is a toxic trace element widely distributed in the lithosphere and mainly associated with arsenic. Sb compounds are considered to be pollutants of high interest, however, the biogeochemical behaviour of Sb is still largely unknown, especially compared to other well-known toxic elements. In particular, questions remain about the availability of Sb to vascular plants. In this work, we focused on the following problems: (i) Sb uptake by plants; (ii) the availability of Sb to plants and (iii) variations in uptake and distribution of essential plant nutrients and trace elements resulting from bioaccumulation of Sb in Triticum aestivum (wheat) seedlings. The seedlings were either germinated or grown in media enriched with Sb. By the end of germination, concentrations of Sb in the seedlings germinated in Sb-amended media increased significantly. Sb content was highest in the roots and lowest in the leaves of the seedlings. After transfer of the seedlings germinated in an Sb-free medium to Sb-enriched media, Sb concentration in the seedlings increased with time, especially in the roots. Bioaccumulation of Sb influenced concentrations of different macro- and trace elements in all parts of the plants. The least variations were observed in the leaves, probably because the increase of Sb concentration in leaves was not as significant as in the seeds and roots.  相似文献   
125.
1/f noise in the UV solar spectral irradiance   总被引:1,自引:1,他引:0  
The investigation of the intrinsic properties of the solar spectral irradiance as a function of the ultraviolet (UV) wavelength is attempted by exploiting rare observations performed at the Villard St. Pancrace station of the Lille University of Sciences and Technology ranging from 278 to 400 nm with a step of 0.05 nm every half an hour from nearly sunrise to sunset. To achieve this goal, the modern method of the detrended fluctuation analysis was applied on the solar spectral irradiance values versus wavelength. This analysis revealed that the solar incident flux at the top of the atmosphere and the solar spectral irradiance at the ground during two overcast sky days fluctuate with the UV wavelength exhibiting persistent long-range power-law behavior. More interestingly, the exponent of the power-law relationship between the fluctuations of the solar spectral irradiance versus UV wavelength at both the top of the atmosphere and the ground is consistently close to unity (of 1/f-type) throughout the day. This 1/f behavior has been detected in many complex dynamical systems, but despite much effort to derive a theory for its widespread occurrence in nature, it remains unexplained so far. According to the above-mentioned findings we speculate that the 1/f property of the incident solar UV flux at the top of the atmosphere could probably drive both the 1/f behavior depicted in the atmospheric components and the solar UV irradiance at the Earth's surface. The latter could influence the UV-sensitive biological ecosystems, giving rise to a 1/f-type variability in the biosphere, which has already been proven by recent observational data. We finally propose that Wien approximation could be multiplied by a 1/f function of wavelength (e.g., of the type of the fractional Brownian motion) in order to reproduce the aforementioned 1/f feature of the solar UV flux.  相似文献   
126.
Atmospheric rivers(ARs)are an important component of the hydrological cycle linking moisture sources in lower latitudes to the Antarctic surface mass balance.We investigate AR signatures in the atmospheric vertical profiles at the Dronning Maud Land coast,East Antarctica,using regular and extra radiosonde measurements conducted during the Year of Polar Prediction Special Observing Period November 2018 to February 2019.Prominent AR events affecting the locations of Neumayer and Syowa cause a strong increase in specific humidity extending through the mid-troposphere and a strong low-level jet(LLJ).At Neumayer,the peak in the moisture inversion(up to 4 g kg^?1)is observed between 800 and 900 hPa,while the LLJ(up to 32 m s^?1)is concentrated below 900 hPa.At Syowa the increase in humidity is less pronounced and peaks near the surface,while there is a substantial increase in wind speed(up to 40 m s?1)between 825 and 925 hPa.Moisture transport(MT)within the vertical profile during the ARs attains a maximum of 100 g kg?1 m s?1 at both locations,and is captured by both ERA-Interim and ERA5 reanalysis data at Neumayer,but is strongly underestimated at Syowa.Composites of the enhanced MT events during 2009?19 show that these events represent an extreme state of the lower-tropospheric profile compared to its median values with respect to temperature,humidity,wind speed and,consequently,MT.High temporal-and vertical-resolution radiosonde observations are important for understanding the contribution of these rare events to the total MT towards Antarctica and improving their representation in models.  相似文献   
127.
Organic matter in cobalt-rich crust(CRC) from the Marcus–Wake Seamounts of the western Pacific Ocean, Sample CM1D03, has been analyzed to understand the source, geochemistry and mineralization of organic matter, and the mineralization environment. Biomarkers, including n-alkanes, isoprenoids, terpanes and sterols, have been detected in various layers of the CRC sample, using gas chromatography(GC) and gas chromatography–mass spectrometry(GC–MS). The content of organic carbon(OC) and its stable isotope(δ13C), and the combined features of the biomarkers show that the mineralized organic matter in CM1D03 CRC was mainly derived from microorganisms and lower plankton(e.g., bacteria and algae, respectively) from marine surface water, with some terrestrial higher plant components. The ratio of chloroform bitumen "A": OC was high in the CRC, between 10.51 and 20.66, showing significant migration characteristics of n-alkanes. Four mineralization categories of organic matter were recognized based on GC chromatograms of n-alkane molecules:(1) primitive type(bacteria and algae), which is characterized by moderately mature of n-alkanes preserving the original characteristics of the organic matter from microorganisms and lower plankton;(2) microbial degradation type, which is characterized by low contents of n-alkanes and rising baseline in the chromatogram, with the "bulge" being the products of organic matter by biodegradation;(3) organic matter migration type, which is characterized by low carbon number of n-alkanes with n C18 as the main peak carbon, without odd even predominance, and low concentrations of isoprenoids and hydrocarbons with high carbon number; and(4) organic matter hydrothermal type, which is characterized by relatively low concentration of small molecular weight n-alkanes, pristane, and phytane, accompanied by higher concentration of n-alkanes with carbon number greater than n C18. This study shows that biomarkers can record controlling factors of mineralization and their variation.  相似文献   
128.
The diffusion of Ni and Co was measured at atmospheric pressure in synthetic monocrystalline forsterite (Mg2SiO4) from 1,200 to 1,500 °C at the oxygen fugacity of air, along [100], with the activities of SiO2 and MgO defined by either forsterite + periclase (fo + per buffer) or forsterite + protoenstatite (fo + en buffer). Diffusion profiles were measured by three methods: laser-ablation inductively-coupled-plasma mass-spectrometry, nano-scale secondary ion mass spectrometry and electron microprobe, with good agreement between the methods. For both Ni and Co, the diffusion rates in protoenstatite-buffered experiments are an order of magnitude faster than in the periclase-buffered experiments at a given temperature. The diffusion coefficients D M (M = Ni or Co) for the combined data set can be fitted to the equation:
$$\log \,D_{\text{M}} \,\left( {{\text{in}}\,{\text{m}}^{2} \,{\text{s}}^{ - 1} } \right) = - 6.77( \pm 0.33) + \Delta E_{\text{a}} (M)/RT + 2/3\log a_{{SiO_{2} }}$$
with Ea(Ni) = ? 284.3 kJ mol?1 and Ea(Co) = ? 275.9 kJ mol?1, with an uncertainty of ±10.2 kJ mol?1. This equation fits the data (24 experiments) to ±0.1 in log D M. The dependence of diffusion on \(a_{{{\text{SiO}}_{2} }}\) is in agreement with a point-defect model in which Mg-site vacancies are charge-balanced by Si interstitials. Comparative experiments with San Carlos olivine of composition Mg1.8Fe0.2SiO4 at 1,300 °C give a slightly small dependence on \(a_{{{\text{SiO}}_{2} }}\), with D \(\propto\) (\(a_{{{\text{SiO}}_{2} }}^{0.5}\)), presumably because the Mg-site vacancies increase with incorporation of Fe3+ in the Fe-bearing olivines. However, the dependence on fO2 is small, with D \(\propto\) (fO2)0.12±0.12. These results show the necessity of constraining the chemical potentials of all the stoichiometric components of a phase when designing diffusion experiments. Similarly, the chemical potentials of the major-element components must be taken into account when applying experimental data to natural minerals to constrain the rates of geological processes. For example, the diffusion of divalent elements in olivine from low SiO2 magmas, such as kimberlites or carbonatites, will be an order of magnitude slower than in olivine from high SiO2 magmas, such as tholeiitic basalts, at equal temperatures and fO2.
  相似文献   
129.
“Zernov’s Phyllophora field” is a unique habitat located in the northwestern Black Sea. At the site, there is a dense stand of agarophytes (red algae) and a high diversity of associated fauna. On November 21 2008, the president of Ukraine (Victor Yuschenko) declared this area a botanical reserve of state-wide importance; it was established to protect and restore a unique natural environment. “Zernov’s Phyllophora field” is the first offshore, fully marine MPA in the Black Sea, and it is the largest. The total area is 402,500 ha, covering 12.5% of the northwestern shelf of the Black Sea. The Ukrainian Scientific Centre for the Ecology of Sea has developed a program for (1) preservation, (2) restoration and (3) further rational use of biological resources at the site. It contains three conforming and interdependent sub-programs that put forward a series of measures for implementing the objectives (preservation, restoration, sustainable resource use).The northwestern Black Sea was heavily impacted by anthropogenic loading in the period 1970–1980, and Zernov’s Phyllophora field was considerably degraded and reduced in area. During recent years the perimeter of the Phyllophora field has slightly extended, and restoration of the benthic phytocoenosis has begun. Assigning this area the status of a marine reserve (Marine Protected Area) will further promote processes of restoring faunal and floristic biodiversity to historically healthy levels.  相似文献   
130.
We find a new Tully–Fisher-like relation for spiral galaxies holding at different galactocentric radii. This radial Tully–Fisher relation allows us to investigate the distribution of matter in the optical regions of spiral galaxies. This relation, applied to three different samples of rotation curves of spiral galaxies, directly proves that: (i) the rotation velocity of spirals is a good measure of their gravitational potential and both the rotation curve's amplitudes and profiles are well predicted by galaxy luminosity, (ii) the existence of a dark component, less concentrated than the luminous one, and (iii) a scaling law, according to which, inside the disc optical size:   M dark/ M lum= 0.5( L B /1011 L B )−0.7  .  相似文献   
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