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61.
Diamond in metasedimentary crustal rocks from Pohorje,Eastern Alps: a window to deep continental subduction 下载免费PDF全文
M. Janák N. Froitzheim K. Yoshida V. Sasinková M. Nosko T. Kobayashi T. Hirajima M. Vrabec 《Journal of Metamorphic Geology》2015,33(5):495-512
We report the first finding of diamond and moissanite in metasedimentary crustal rocks of Pohorje Mountains (Slovenia) in the Austroalpine ultrahigh‐pressure (UHP) metamorphic terrane of the Eastern Alps. Microscopic observations and Raman spectroscopy show that diamond occurs in situ as inclusions in garnet, being heterogeneously distributed. Under the optical microscope, diamond‐bearing inclusions are of cuboidal to rounded shape and of pinkish, yellow to brownish colour. The Raman spectra of the investigated diamond show a sharp, first order peak of sp3‐bonded carbon, in most cases centred between 1332 and 1330 cm?1, with a full width at half maximum between 3 and 5 cm?1. Several spectra show Raman bands typical for disordered graphitic (sp2‐bonded) carbon. Detailed observations show that diamond occurs either as a monomineralic, single‐crystal inclusion or it is associated with SiC (moissanite), CO2 and CH4 in polyphase inclusions. This rare record of diamond occurring with moissanite as fluid‐inclusion daughter minerals implies the crystallization of diamond and moissanite from a supercritical fluid at reducing conditions. Thermodynamic modelling suggests that diamond‐bearing gneisses attained P–T conditions of ≥3.5 GPa and 800–850 °C, similar to eclogites and garnet peridotites. We argue that diamond formed when carbonaceous sediment underwent UHP metamorphism at mantle depth exceeding 100 km during continental subduction in the Late Cretaceous (c. 95–92 Ma). The finding of diamond confirms UHP metamorphism in the Pohorje Mountains, the most deeply subducted part of Austroalpine units. 相似文献
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Jan Leitner Knut Metzler Christian Vollmer Christine Floss Pierre Haenecour Jnos Kodolnyi Dennis Harries Peter Hoppe 《Meteoritics & planetary science》2020,55(6):1176-1206
We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in 17O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in 17O and significantly depleted in 18O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced 18O/16O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca2Mg[Si2O7]) or a an åkermanite‐diopside (MgCaSi2O6) intergrowth. 相似文献
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Marcus Schulz Jan Priegnitz Jörg Klasmeier Stefan Heller Stefan Meinecke Michael Feibicke 《水文研究》2012,26(2):272-280
In several empirical and modelling studies on river hydraulics, dispersion was negatively correlated to surface roughness. In this study, it was aimed to investigate the influence of surface roughness on longitudinal dispersion under controlled conditions. In artificial flow channels with a length of 104 m, tracer experiments with variations in channel bed material were performed. By use of measured tracer breakthrough curves, average flow velocity, mean longitudinal dispersion, and mean longitudinal dispersivity were calculated. Longitudinal dispersion coefficients ranged from 0·018 m2 s?1 in channels with smooth bed surface up to 0·209 m2 s?1 in channels with coarse gravel as bed material. Longitudinal dispersion was linearly related to mean flow velocity. Accordingly, longitudinal dispersivities ranged between 0·152 ± 0·017 m in channels with smooth bed surface and 0·584 ± 0·015 m in identical channels with a coarse gravel substrate. Grain size and surface roughness of the channel bed were found to correlate positively to longitudinal dispersion. This finding contradicts several existing relations between surface roughness and dispersion. Future studies should include further variation in surface roughness to derive a better‐founded empirical equation forecasting longitudinal dispersion from surface roughness. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
66.
Ricardo Sánchez‐Murillo Ana M. Durán‐Quesada Christian Birkel Germain Esquivel‐Hernández Jan Boll 《水文研究》2017,31(4):956-967
The last 2014‐16 El Niño event was among the three strongest episodes on record. El Niño considerably changes annual and seasonal precipitation across the tropics. Here, we present a unique stable isotope data set of daily precipitation collected in Costa Rica prior to, during, and after El Niño 2014‐16, in combination with Lagrangian moisture source and precipitation anomaly diagnostics. δ2H composition ranged from ‐129.4 to +18.1 (‰) while δ18O ranged from ‐17.3 to +1.0 (‰). No significant difference was observed among δ18O (P=0.186) and δ2H (P=0.664) mean annual compositions. However, mean annual d‐excess showed a significant decreasing trend (from +13.3 to +8.7 ‰) (P<0.001) with values ranging from +26.6 to ‐13.9 ‰ prior to and during the El Niño evolution. The latter decrease in d‐excess can be partly explained by an enhanced moisture flux convergence across the southeastern Caribbean Sea coupled with moisture transport from northern South America by means of an increased Caribbean Low Level Jet regime. During 2014‐15, precipitation deficit across the Pacific domain averaged 46% resulting in a very severe drought; while a 94% precipitation surplus was observed in the Caribbean domain. Understanding these regional moisture transport mechanisms during a strong El Niño event may contribute to a) better understanding of precipitation anomalies in the tropics and b) re‐evaluate past stable isotope interpretations of ENSO events in paleoclimatic archives within the Central America region. 相似文献
67.
Characterising the dependence between extremes of wave spectral parameters such as significant wave height (HS) and spectral peak period (TP) is important in understanding extreme ocean environments and in the design and assessment of marine structures. For example, it is known that mean values of wave periods tend to increase with increasing storm intensity. Here we seek to characterise joint dependence in a straightforward manner, accessible to the ocean engineering community, using a statistically sound approach.Many methods of multivariate extreme value analyses are based on models which assume implicitly that in some joint tail region each parameter is either independent of or asymptotically dependent on other parameters; yet in reality the dependence structure in general is neither of these. The underpinning assumption of multivariate regular variation restricts these methods to estimation of joint regions in which all parameters are extreme; but regions where only a subset of parameters are extreme can be equally important for design. The conditional approach of Heffernan and Tawn (2004), similar in spirit to that of Haver (1985) but with better theoretical foundation, overcomes these difficulties.We use the conditional approach to characterise the dependence structure of HS and TP. The key elements of the procedure are: (1) marginal modelling for all parameters, (2) transformation of data to a common standard Gumbel marginal form, (3) modelling dependence between data for extremes of pairs of parameters using a form of regression, (4) simulation of long return periods to estimate joint extremes. We demonstrate the approach in application to measured and hindcast data from the Northern North Sea, the Gulf of Mexico and the North West Shelf of Australia. We also illustrate the use of data re-sampling techniques such as bootstrapping to estimate the uncertainty in marginal and dependence models and accommodate this uncertainty in extreme quantile estimation.We discuss the current approach in the context of other approaches to multivariate extreme value estimation popular in the ocean engineering community. 相似文献
68.
Moving boulders in flash floods and estimating flow conditions using boulders in ancient deposits 下载免费PDF全文
Boulders moving in flash floods cause considerable damage and casualties. More and bigger boulders move in flash floods than predicted from published theory. The interpretation of flow conditions from the size of large particles within flash flood deposits has, until now, generally assumed that the velocity (or discharge) is unchanging in time (i.e. flow is steady), or changes instantaneously between periods of constant conditions. Standard practice is to apply theories developed for steady flow conditions to flash floods, which are however inherently very unsteady flows. This is likely to lead to overestimates of peak flow velocity (or discharge). Flash floods are characterised by extremely rapid variations in flow that generate significant transient forces in addition to the mean‐flow drag. These transient forces, generated by rapid velocity changes, are generally ignored in published theories, but they are briefly so large that they could initiate the motion of boulders. This paper develops a theory for the initiation of boulder movement due to the additional impulsive force generated by unsteady flow, and discusses the implications. 相似文献
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Convective and stratiform precipitation characteristics in an ensemble of regional climate model simulations 总被引:1,自引:0,他引:1
We apply a recently proposed algorithm for disaggregating observed precipitation data into predominantly convective and stratiform, and evaluate biases in characteristics of parameterized convective (subgrid) and stratiform (large-scale) precipitation in an ensemble of 11 RCM simulations for recent climate in Central Europe. All RCMs have a resolution of 25 km and are driven by the ERA-40 reanalysis. We focus on mean annual cycle, proportion of convective precipitation, dependence on altitude, and extremes. The results show that characteristics of total precipitation are often better simulated than are those of convective and stratiform precipitation evaluated separately. While annual cycles of convective and stratiform precipitation are reproduced reasonably well in most RCMs, some of them consistently and substantially overestimate or underestimate the proportion of convective precipitation throughout the year. Intensity of convective precipitation is underestimated in all RCMs. Dependence on altitude is also simulated better for stratiform and total precipitation than for convective precipitation, for which several RCMs produce unrealistic slopes. Extremes are underestimated for convective precipitation while they tend to be slightly overestimated for stratiform precipitation, thus resulting in a relatively good reproduction of extremes in total precipitation amounts. The results suggest that the examined ensemble of RCMs suffers from substantial deficiencies in reproducing precipitation processes and support previous findings that climate models’ errors in precipitation characteristics are mainly related to deficiencies in the representation of convection. 相似文献