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31.
Accretionary lapilli are common in fine-grained pyroclastic flow and surge deposits and related co-ignimbrite/co-surge ash layers of Laacher See volcano. Two morphologically different types are distin-guished: (1) Rim-type lapilli are composed of a coarse-grained core surrounded by a fine-grained rim. Rims are internally graded or made up of several layers of alternating fine and very-fine grained ash. (2) Core-type lapilli lack fine-grained rims. Field relationships, internal, and grain-size characteristics are specific to accretionary lapilli from different types of tephra deposits. Accretionary lapilli may therefore be a helpful tool to infer the origin of tephra of different origin. In co-ignimbrite ashfall, accretionary lapilli are generally concentrated at the base, whereas pyroclastic flow and surge deposits contain lapilli in the upper parts of individual, thin-bedded layers. Rim-type lapilli are found in pyroclastic flow and surge deposits up to 4 km from the source. Core-type lapilli occur at greater distances or are associated with vesiculated tuffs where they are within 1 km from the vent. Accretionary lapilli from co-ignimbrite/co-surge ash show open framework textures and edge-to-face contacts of individual ash particles. Vesicularity is generally low but the overall porosity of 40% to 50% results in an average density of 1200 kg/m3. Accretionary lapilli in pyroclastic flow and surge deposits are more densely packed and platy particles are often in face-to-face contacts. Vesicularity of those from pyroclastic flow deposits is significantly higher; the overall porosity is about 30% to 40% and the average density 1600 kg/m3. Grain-size analyses show that the accretionary lapilli in co-ignimbrite/co-surge ashfall deposits are the most fine-grained with a median (Md) of 20 to 30 m and a maximum grain size of 250 to 350 m. Accretionary lapilli from pyroclastic flow deposits have intermediate Md-values of 30 to 50 m and a maximum grain size of 350 to 500 m. Those of surge deposits are the coarsest grained with Md-values of 30 to >63 m and a maximum grain size up to 2 mm.  相似文献   
32.
During the EU project BEEP a battery of biomarkers was applied in flounder (Platichthys flesus) and the blue mussel (Mytilus edulis) collected at three locations off the Lithuanian coast (Baltic Sea) in June and September 2001 and 2002. The elevated biomarker responses in specimens sampled in September 2001 were apparently related to the extensive dredging activities in the Klaipeda port area and subsequent dumping of contaminated sediments. High concentrations of organic pollutants (organochlorines and PBDEs) were also measured in the tissues of both indicator species. In addition, response levels of genotoxicity, cytotoxicity, immunotoxicity as well as concentrations of PAH metabolites in the bile of flounder showed elevations in 2002 after an oil spill in the Būtinge oil terminal in November 2001. In flounder, biomarker measurements 10 months after the spill indicated recovery processes but in mussels a high level of genotoxicity could still be observed 22 months later. The present study illustrates the usefulness of the multi-biomarker approach in the detection of biological effects of pollution in this region of the Baltic Sea.  相似文献   
33.
Results are presented of a study on liver histopathology in Baltic flounder (Platichthys flesus) carried out in 2001 and 2002 in four coastal sampling areas of the Baltic Sea: Kv?d?fj?rden (Swedish east coast, reference area), Klaipeda-Butinge (Lithuanian coast), Gulf of Gdansk (Polish coast), and Wismar Bay (German coast) within the framework of the EU-funded BEEP project. Liver lesions were diagnosed and categorised using standardised methodologies and, for a spatial and temporal assessment of the prevalence and types of lesions detected, a scoring system was applied, involving the calculation of mean histopathology lesion scores. 83.0% of the 436 female flounder examined (size range: 20-43 cm total length, age range: 2-8 years) were affected by liver lesions, out of which 74.3% were assigned to the category of non-specific, 3.4% to the category of early toxicopathic non-neoplastic, 4.6% to the category of pre-neoplastic and 0.7% to the category of neoplastic lesions. Mean lesions scores were highest in the areas at the Lithuanian and Swedish coast and there is indication of an impact of the age structure of the flounder populations studied, the sampling season as well as of contaminant effects.  相似文献   
34.
The Sarikavak Tephra from the central Galatean Volcanic Province (Turkey) represents the deposit of a complex multiple phase plinian eruption of Miocene age. The eruptive sequence is subdivided into the Lower-, Middle-, and Upper Sarikavak Tephra (LSKT, MSKT, USKT) which differ in type of deposits, lithology and eruptive mechanisms.The Lower Sarikavak Tephra is characterised by pumice fall deposits with minor interbedded fine-grained ash beds in the lower LSKT-A. Deposits are well stratified and enriched in lithic fragments up to >50 wt% in some layers. The upper LSKT-B is mainly reversely graded pumice fall with minor amounts of lithics. It represents the main plinian phase of the eruption. The LSKT-A and B units are separated from each other by a fine-grained ash fall deposit. The Middle Sarikavak Tephra is predominantly composed of cross-bedded ash-and-pumice surge deposits with minor pumice fall deposits in the lower MSKT-A and major pyroclastic flow deposits in the upper MSKT-B unit. The Upper Sarikavak Tephra shows subaerial laminated surge deposits in USKT-A and subaqueous tephra beds in USKT-B.Isopach maps of the LSKT pumice fall deposits as well as the fine ash at the LSKT-A/B boundary indicate NNE–SSW extending depositional fans with the source area in the western part of the Ovaçik caldera. The MSKT pyroclastic flow and surge deposits form a SW-extending main lobe related to paleotopography where the deposits are thickest.Internal bedding and lithic distribution of the LSKT-A result from intermittent activity due to significant vent wall instabilities. Reductions in eruption power from (partial) plugging of the vent produced fine ash deposits in near-vent locations and subsequent explosive expulsion of wall rock debris was responsible for the high lithic contents of the lapilli fall deposits. A period of vent closure promoted fine ash fall deposition at the end of LSKT-A. The subsequent main plinian phase of the LSKT-B evolved from stable vent conditions after some initial gravitational column collapses during the early ascent of the re-established eruption plume. The ash-and-pumice surges of the MSKT-A are interpreted as deposits from phreatomagmatic activity prior to the main pyroclastic flow formation of the MSKT-B.  相似文献   
35.
36.
The Greens Creek polymetallic massive sulphide deposit is hosted in a typical polyphase deformed lower greenschist facies orogenic setting. The structure of the host rocks is well constrained, exhibiting a series of three superimposed ductile deformations followed by two brittle episodes. The ore is found both in fold hinges where early-formed depositional features are preserved and in fold limbs where primary features are typically strongly modified or obliterated. Samples from both settings have been investigated using electron backscatter diffraction (EBSD) coupled with forescatter orientation contrast (OC) imaging in order to observe the effects of deformation and lower greenschist facies metamorphism on pyrite. Results suggest that colloform pyrite may preserve information relevant to palaeoenvironment, that apparently simple textures are generally more complex, and that pyrite can deform plastically by dislocation glide and creep processes at lower temperatures and/or strain rates than generally accepted. This analysis indicates that EBSD and OC imaging provide powerful tools for observing textural relationships in pyrite that are not shown by more traditional methods. They should become routine tools for pyrite texture analysis.Editorial handling: D. Lentz  相似文献   
37.
Pliocene to recent uplift and shortening in the southern Rhinegraben is documented by deformation of Pliocene fluvial gravels, deposited on a nearly planar surface, as well as by progressive deflection and capture of rivers. This deformation is suggested to result from thick-skinned tectonic movements as evidenced by observations on seismic records, which demonstrate a spatial coincidence between en-échelon anticlines at the surface and faults located in the crystalline basement. These findings contradict the often invoked thin-skinned tectonism in the recent tectonic history of the Rhinegraben. In particular the transfer zone between the Rhinegraben and the Bressegraben is very suitable for reactivation under the present day stress field. Thick-skinned reactivation of faults in the basement is also expressed by focal plane mechanisms of recent earthquakes showing strike-slip- rather than reverse faulting characteristics. This is of importance for the densely populated and industrialised southern Rhinegraben, previously affected by large earthquakes in historical times (e.g. Basel 1356).  相似文献   
38.
If clays are subjected to flows of fluid, electrical charge, chemicals, or heat, in most cases, flows of different types occur simultaneously, even if only one driving force is acting. These are so-called coupled flows. Examples of coupling phenomena are streaming potential and electroosmosis, induced by the flows of fluid and electrical charge, respectively.

Since the 1960s, laboratory devices have been constructed to measure streaming potentials and/or electroosmosis in clays or clayey soils. Due to their mechanical and hydraulic properties, clays are not easy to work with. Consequently, laboratory devices have to deal with various complications. A new design for an experimental set-up is proposed. Contrary to earlier devices, the clay sample is mounted in a flexible wall permeameter, which avoids sidewall leakage caused by the possible swell or shrink of the clay. Gold-coated gauze electrodes completely cover the surfaces of the sample, which are in contact with the solution reservoirs that ensure one-dimensional flow. In addition, the thickness of the sample is monitored during the experiment. The chemical composition of the reservoir fluids is controlled during the experiment. The device is flexible with respect to changing the solutions of both reservoirs independently, applying different hydraulic gradients, and measuring or applying electrical potentials. Finally, it is possible to mount undisturbed clay samples in the set-up, keeping them in situ during the whole experiment.

With this set-up, an extensive program of measurements of coupling phenomena like streaming potentials, electroosmosis, and membrane potentials in a sodium montmorillonite is started. Preliminary results of streaming potential measurements are presented and demonstrate that the build-up of a streaming potential due to a hydraulic gradient is a reproducible process that influences the water flow through the clay, and that the extent of the streaming potential depends on the salt concentration of the permeating solution.  相似文献   

39.
Lamellar nigerite is found in Zn-rich spinel from a sample that contains chiefly anthophyllite + spinel + cordierite, lesser amounts of quartz and chlorite, as well as sphalerite, pyrite, pyrrhotite, and galena, and rare cassiterite and rutile. Nigerite can be described as interlayering of spinel-like (R2+Al2O4) and nolanite-like ((Sn, Ti)Al4O8) structures. In nigerite, the spinel-like part is also compositionally related to spinel, but in the nolanite-like part only the structural analogy exists. Stoichiometric assumptions that relate the anhydrous cation sum to the amount of R4+ cations present, allow Fe3+ estimates from microprobe analyses, and a representative analysis gives the following anhydrous formula: Mg1.30Fe 0.65 2+ Zn3.03Mn0.03Al11.65Fe 0.35 3+ Sn0.32Ti0.18O24.The nigerite is Zn-rich with a Zn ratio (Zn/(Zn+Mg+ Fe2+)) of about 0.59, and the Sn ratio (Sn/(Sn+Ti)) that ranges from about 0.63 to 0.41. The Fe3+ content in these samples ranges from 0.35 to 0.52 (24 oxygen basis).Textures suggest that the nigerite could have formed by the breakdown of R 2 2+ (Sn, Ti)O4 and R2+Al2O4 spinel components during more complex reactions. An experimental investigation of the MgAl2O4-Mg2SnO4 join indicates that the solubility of Mg2SnO4 component in spinel over the T interval 500 to 900° C is about 0.5 to 3.0 mole %. This, coupled with the increased solubility expected from the presence of Ti, gives good agreement with the 2.4 to 2.6 mole % R 2 2+ (Sn, Ti)O4 component in spinel that is estimated to be the maximum necessary to form the compositions and amounts of observed nigerite.  相似文献   
40.
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