Study on the kinetics of iron oxide leaching by oxalic acid   总被引：2，自引：0，他引：2  

Suong Oh Lee  Tam Tran  Yi Yong Park  Seong Jun Kim  Myong Jun Kim   《International Journal of Mineral Processing》2006,80(2-4):144-152

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.  相似文献   

Effect of polypropylene fibre and lime admixture on engineering properties of clayey soil   总被引：2，自引：0，他引：2  

Yi Cai  Bin Shi  Charles W.W. Ng  Chao-sheng Tang 《Engineering Geology》2006,87(3-4):230-240

In order to reduce the brittleness of soil stabilized by lime only, a recent study of a newly proposed mixture of polypropylene fibre and lime for ground improvement is described and reported in the paper. To investigate and understand the influence of the mixture of polypropylene fibre and lime on the engineering properties of a clayey soil, nine groups of treated soil specimens were prepared and tested at three different percentages of fibre content (i.e. 0.05%, 0.15%, 0.25% by weight of the parent soil) and three different percentages of lime (i.e. 2%, 5%, 8% by weight of the parent soil). These treated specimens were subjected to unconfined compression, direct shear, swelling and shrinkage tests. Through scanning electron microscopy (SEM) analysis of the specimens after shearing, the improving mechanisms of polypropylene fibre and lime in the soil were discussed and the observed test results were explained. It was found that fibre content, lime content and curing duration had significant influence on the engineering properties of the fibre–lime treated soil. An increase in lime content resulted in an initial increase followed by a slight decrease in unconfined compressive strength, cohesion and angle of internal friction of the clayey soil. On the other hand, an increase in lime content led to a reduction of swelling and shrinkage potential. However, an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. An increase in curing duration improved the unconfined compressive strength and shear strength parameters of the stabilized soil significantly. Based on the SEM analysis, it was found that the presence of fibre contributed to physical interaction between fibre and soil whereas the use of lime produced chemical reaction between lime and soil and changed soil fabric significantly.  相似文献   

萨拉乌苏河流域萨拉乌苏组沙丘砂沉积特征   总被引：7，自引：1，他引：7  

欧先交  李保生  靳鹤龄  吴正  温小浩  董光荣  曾兰华  欧阳椿陶  杨艺  刘宇飞 《地理学报》2006,61(9):965-975

萨拉乌苏河流域米浪沟湾剖面萨拉乌苏组含7层古流动沙丘砂、4层古固定-半固定沙丘砂.对这些沙丘砂的沉积构造观察以及粒度、扫描电镜和常量化学元素分析结果表明：（1）这些沙丘砂具有与现代沙丘砂相似的风成沉积构造特征;（2）粒度及其参数——Mz、σ、Sk和Kg,以及主要化学组分SiO2、Al2O3和TOFE也与现代沙丘砂相近;（3）Mz-σ、SiO2-Al2O3＋TOFE散点图和概率累积曲线显示这些沙丘砂与萨拉乌苏组中的河湖相、古土壤差别明显,而与现代沙丘砂一致;（4）石英砂颗粒具有良好的磨圆以及碟形坑、新月形坑、麻坑、上翻解理薄片、硅质沉淀和硅质裂纹等表面结构特征,反映其曾受持久的风力搬运作用.沉积构造、粒度、石英砂颗粒表面结构和化学元素等多个方面具备了与现代沙丘砂类似的风成特征,证明这些沙丘砂的成因是风成的.  相似文献   

柴达木盆地西部尕斯库勒油田E₃1油藏成藏条件与机制     

段毅  彭德华  张辉  吴保祥  郑朝阳  王传远 《沉积学报》2005,23(1):150-155

柴达木盆地西部原油为盐湖相未成熟-低成熟原油,属于典型的原油成因类型。尕斯库勒油田是柴达木盆地西部最大的油田。从油气生成运移、聚集成藏诸方面,较为系统地研究了该油田中E1₃ 油藏的形成条件,动态地探讨了油藏的形成机制,为该油藏的成因认识和进一步勘探开发提供了科学依据。  相似文献   

基于PGNAA技术在线分析系统的应用     

何伶俐  庹先国  穆克亮  曾旖  李向阳 《物探化探计算技术》2005,27(4):317-320

近年来,随着核探测与分析技术的日趋成熟,使复杂γ谱的获取、解析达到了在线测量的要求,从而使在线PGNAA(中子活化瞬发γ射线分析)技术获得了飞速的发展。它可对一些工业生产过程中的全物料进行在线测量,其分析精度、可靠性等皆能满足在线元素含量分析的需要,因而显示出巨大的发展潜力和广阔的市场前景。这里介绍了基于PGNAA技术的在线分析系统的基本原理、组成和发展,并概述了它在水泥、煤炭等行业的应用情况。  相似文献   

克鲁伦凹陷大磨拐河组沉积体系演化与赋铀性     

张志杰  于兴河  陈占坤  郭庆银  罗毅  张传恒 《铀矿地质》2005,21(1):23-29

克鲁伦凹陷下白垩统大磨拐河组是海拉尔盆地寻找可地浸砂岩型铀矿的目的层。大磨拐河组主要发育冲积扇、扇三角洲和湖相 3种沉积体系。根据沉积环境和沉积物特征 ,可将冲积扇划分为扇根、扇中和扇端 3种亚相 ;扇三角洲划分为上扇三角洲平原、下扇三角洲平原、扇三角洲前缘和前扇三角洲亚相。凹陷北缘发育两个扇体 ,扇三角洲体系和冲积扇体系之间在不同时期可相互转化。区内的陆源粗碎屑沉积岩为铀的富集创造了有利条件 ,扇三角洲和冲积扇的主河道和分流河道是最有利于铀聚集的部位。  相似文献   

昆明市山地灾害风险分区及防治对策   总被引：2，自引：0，他引：2  

张云霞  朱杰勇  刘益 《云南地质》2005,24(1):114-121

通过地质灾害调查，认为昆明市地质灾害以泥石流、滑坡、崩塌为主。分析地质灾害时空分布及形成条件，从致灾因子角度，给出昆明市地质灾害风险区划，提出地质灾害防治对策。  相似文献   

青藏高原北部温泉活动沉积盆地的沉积特征及其地质意义     

段志明  李勇  李亚林  张毅  王谋  黎兵 《沉积与特提斯地质》2005,25(1):180-188

晚新生代温泉沉积盆地，是青藏高原腹地在南北向挤压、东西向伸展的构造背景下，沿南北向边界走滑断层，经边界正断层和内部张剪断层的进一步发展而形成的近南北向单断单剪楔形半地堑活动沉积盆地。它可能代表了晚新生代青藏高原第三期强烈挤压隆升事件，是侧向向东剪切挤出的结果。笔者以盆地充填序列和TL、ESR测年资料为主要依据，推测唐古拉山在300～250ka前后全面进入冰冻圈；而以温泉活动沉积盆地为代表的中更新世晚期(224．0～150．2ka)的冰碛一冰水堆积则对应于青藏高原第三期隆升的断陷盆地发育阶段；中更新世晚期一晚更新世中期(144．0～56ka)为湖相沉积；晚更新世中期至今(35～0ka)对应于高原缓慢隆升与夷平发育阶段。长江溯源在35ka切割通天河盆地，形成通天河；而在16kat浸蚀切穿雁石坪一温泉兵站峡谷，形成布曲河。  相似文献   

青藏高原唐古拉山口第四纪冰碛层划分及其地质环境意义   总被引：4，自引：1，他引：4       下载免费PDF全文

段志明  李勇  李亚林  张毅王谋 《中国地质》2005,32(1):128-134

在对唐古拉山口现代冰川和古冰川考察研究的基础上，结合定位观测资料和TL、^10B-^26Al-^21Ne及^14C测年数据，对区内第四纪冰川遗迹进行了深入讨论，划分出二次冰期(即中更新世晚期的倒数第二次冰期、晚更新世中一晚期的末次冰期)和二次全新世冰进(即新冰期和小冰期)。提出在早更新世时，由于山体未达到当时冰川发育的雪线高度，所以未发育冰川。但在唐古拉山口地区，截止目前还未找到中更新世早期的倒数第三次冰期的冰川遗迹，由于高原隆升的滞后性和冰川发育的延滞效应及“亚洲干极”的耦合，推测仍只发育局部冰川作用。进一步研究表明，古今雪线由高原边缘向腹地升高，唐古拉山地区高出边缘1500m左右，生动表现了“亚洲干极”的作用；广泛分布的湖群说明羌塘地区是一个大江大河尚未伸入的内流地区，意味着青藏高原是个年青的高原。由于青藏高原的隆升，对高原腹地引起的干旱化过程和水分严重不足，使唐古拉山地区的冰川自倒数第二次冰期以来，冰川规模一次比一次明显地减小。  相似文献   

北京城近郊区土壤中Cd的释放、形态转化与演变趋势     

李志萍  黄怀曾冯流  迟宝明黄毅 《地质通报》2005,24(10):957-961

在对北京城近郊区主要类型土壤（潮土和褐土）中Cd形态分析的基础上，研究pH与土壤中Cd的释放量及其形态转化的关系。结果表明：潮土和褐土中Cd的释放量曲线都呈下凹的弧形，在pH=6～7之间释放量最低。pH对土壤中Cd释放的影响，其本质是土壤中Cd的化学形态发生了变化，各形态间的转化以水溶态为中介体。所有的形态转化中，pH对交换态和碳酸盐结合态影响最大，且这两者之间的转化对生物有效量起决定性作用。进而根据北京城近郊区土壤中生物有效Cd的分布状况，结合北京市近12年监测的大气pH值，对北京城近郊区土壤Cd污染进行预警。  相似文献