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91.
The paper presents the results of experimental rock-magnetic, paleomagnetic and palynologic study of Paleolithic sediments sampled along two profiles in the Akhshtyrskaya cave, situated in the vicinity of Black Sea shore. In the upper part of profiles, some magnetite was observed; in the middle and lower parts, strongly oxidized non-stoichiometric magnetite and hematite prevail. Thin maghemite covers on the surface of fine magnetite grains are present in the majority of specimens. Natural remanence has one characteristic component (CHRM), mostly of chemical origin, although in few specimens containing magnetite it may be sedimentary. Directions of CHRM obtained by standard paleomagnetic methods revealed anomalous pattern only in layer 3/2, which is slightly older than the overlying layer 3/1 whose age was established as (35±2)×103 years BP by the U-Th method. This suggests that this paleomagnetic anomaly (PMA) can be correlated with Kargapolovo excursion dated on about (45−39)×103 years BP. In the remaining overlying and underlying layers, directions of CHRM are grouped around the present geomagnetic field. Depth distributions of scalar magnetic parameters generally coincide with the lithological division of the profiles. Palynologic study revealed the presence of 22 pollen zones. Five thermomers separated with colder periods were found in the middle and lower parts of profile. The non-magnetite composition of magnetic fraction of the majority of studied sediments — oxidized nonstoichiometric magnetite and hematite — resulted in the lack of correlations between paleoclimatic and scalar magnetic characteristics.  相似文献   
92.
A 3D structural model for the entire southwestern Baltic Sea and the adjacent onshore areas was created with the purpose to analyse the structural framework and the sediment distribution in the area. The model was compiled with information from several geological time-isochore maps and digital depth maps from the area and consists of six post-Rotliegend successions: The Upper Permian Zechstein; Lower Triassic; Middle Triassic; Upper Triassic–Jurassic; Cretaceous and Cenozoic. This structural model was the basis for a 3D backstripping approach, considering salt flow as a consequence of spatially changing overburden load distribution, isostatic rebound and sedimentary compaction for each backstripping step in order to reconstruct the subsidence history in the region. This method allows determination of the amount of tectonic subsidence or uplifting as a consequence of the regional stress field acting on the basin and was followed by a correlation with periods of active salt movement. In general, the successions above the highly deformed Zechstein evaporites reveal a thickening trend towards the Glückstadt Graben, which also experienced the highest amount of tectonic subsidence during the Mesozoic and Cenozoic. Two periods of accelerating salt movement in the area has been correlated with the E–W directed extension during the Late Triassic–Early Jurassic and later by the Late Cretaceous–Early Cenozoic inversion, suggesting that the regional stress field plays a key role in halokinesis. The final part of this work dealt with a neotectonic forward modelling in an attempt to predict the future topography when the system is in a tectonic equilibrium. The result reveals that many of the salt structures in the region are still active and that future coastline will run with a WNW–ESE trend, arguing that the compressional stresses related to the Alpine collision are the prime factor for the present-day landscape evolution.  相似文献   
93.
94.
The diagenetic history of the Ediacaran sedimentary rocks in the East European Craton (EEC) over the area extending from Arkhangelsk (Russia) in the north to Podolia (Ukraine) in the south was revealed by means of the XRD characterization and K–Ar dating of clay fractions, mudstone porosity measurements and organic geochemistry investigations. Mudstone porosity measurements produced direct evidence of shallow maximum burial of the Ediacaran sediments on the craton (Russia, Lithuania, Belarus, Volyn), not exceeding 1.5 km, and much deeper burial at the cratonic margin, in Podolia and Poland. In general, illitization of smectite and biomarker indices indicates more advanced diagenesis at the cratonic margin. K–Ar dating of authigenic illite–smectite and aluminoceladonite revealed the Palaeozoic age of mineral diagenesis (ca. 450–300 Ma) both on the craton and its margin, with older ages generally observed in the north. When the maximum palaeotemperatures were evaluated from illite–smectite and biomarkers, based on the calibrations from the conventional burial diagenetic sections, a major mismatch was detected for the cratonic area: 100°C–130°C from illite––smectite and tens of oC lower from the lipid biomarkers. This diagenetic pattern was interpreted as the result of short‐lasting (in ky scale) pulses of potassium‐bearing hot fluids migrating from the Caledonian and Variscan orogens deep in the craton interior, effectively promoting illitization in porous rocks without altering the organic matter. Analogous short pulses of fluids were responsible for numerous diagenetic phenomena, including Mississippi Valley‐Type ore deposits, in the American Midwest, in front of the Appalachians. K–Ar dating indicates that the entire Proterozoic sedimentary cover of the Great Unconformity on the EEC remained untouched by measureable post‐sedimentary changes until the early Palaeozoic, thus for over 1000 My, which is an unprecedented finding.  相似文献   
95.
A 3D backstripping approach considering salt flow as a consequence of spatially changing overburden load distribution, isostatic rebound and sedimentary compaction for each backstripping step is used to reconstruct the subsidence history in the Northeast German Basin. The method allows to determine basin subsidence and the salt-related deformation during Late Cretaceous–Early Cenozoic inversion and during Late Triassic–Jurassic extension. In the Northeast German Basin, the deformation is thin-skinned in the basinal part, but thick-skinned at the basin margins. The salt cover is deformed due to Late Triassic–Jurassic extension and Late Cretaceous–Early Cenozoic inversion whereas the salt basement remained largely stable in the basin area. In contrast, the basin margins suffered strong deformation especially during Late Cretaceous–Early Cenozoic inversion. As a main question, we address the role of salt during the thin-skinned extension and inversion of the basin. In our modelling approach, we assume that the salt behaves like a viscous fluid on the geological time-scale, that salt and overburden are in hydrostatical near-equilibrium at all times, and that the volume of salt is constant. Because the basement of the salt is not deformed due to decoupling in the basin area, we consider the base of the salt as a reference surface, where the load pressure must be equilibrated. Our results indicate that major salt movements took place during Late Triassic to Jurassic E–W directed extension and during Late Cretaceous–Early Cenozoic NNE–SSW directed compression. Moreover, the study outcome suggests that horizontal strain propagation in the salt cover could have triggered passive salt movements which balanced the cover deformation by viscous flow. In the Late Triassic, strain transfer from the large graben systems in West Central Europe to the east could have caused the subsidence of the Rheinsberg Trough above the salt layer. In this context, the effective regional stress did not exceed the yield strength of the basement below the Rheinsberg Trough, but was high enough to provoke deformation of the viscous salt layer and its cover. During the Late Cretaceous–Early Cenozoic phase of inversion, horizontal strain propagation from the southern basin margin into the basin can explain the intensive thin-skinned compressive deformation of the salt cover in the basin. The thick-skinned compressive deformation along the southern basin margin may have propagated into the salt cover of the basin where the resulting folding again was balanced by viscous salt flow into the anticlines of folds. The huge vertical offset of the pre-Zechstein basement along the southern basin margin and the amount of shortening in the folded salt cover of the basin indicate that the tectonic forces responsible for this inversion event have been of a considerable magnitude.  相似文献   
96.
The thermodynamic stability constants for the hydrolysis and formation of mercury (Hg2+) chloride complexes
have been used to calculate the activity coefficients for Hg(OH) n (2–n)+ and HgCl n (2–n)+ complexes using the Pitzer specific interaction model. These values have been used to determine the Pitzer parameters for the hydroxide and chloro complexes and C ML). The values of and have been determined for the neutral complexes (Hg(OH)2 and HgCl2). The resultant parameters yield calculated values for the measured values of log to  ±0.01 from I  =  0.1 to 3 m at 25°C. Since the activity coefficients of and are in reasonable agreement with the values for Pb(II), we have estimated the effect of temperature on the chloride constants for Hg(II) from 0 to 300°C and I = 0–6 m using the Pitzer parameters for complexes. The resulting parameters can be used to examine the speciation of Hg(II) with Cl in natural waters over a wide range of conditions.  相似文献   
97.
Meteorites have been found on the small Misfits Flat dry lakebed near Stagecoach, Nevada (119.382W, +39.348N). Since the first find on Sept. 22, 2013, a total of 58 stones of weathering stage W2/3 with a combined mass of 339 g have been collected in 19 visits to the area. This small (3.3 × 3.6 km) lakebed is now a newly designated dense collection area (DCA). Most meteorites were found in a small 350 × 180 m area along the north shore and most are fragments of several broken individual stones. Three of these fragments were classified as an LL4/5 of shock stage S2, now named Misfits Flat 001, one of which (stone MF33) fell 8.1 ± 1.3 ka ago based on the 14C terrestrial age, assuming it came from a 20–80 cm diameter meteoroid. In addition, a small darkly crusted meteorite MF34, now named Misfits Flat 002, was found 820 m WSW from the main mass. This meteorite is classified as an LL5 ordinary chondrite with shock stage S4/5. The meteorite is saturated in 14C at 63 dpm kg?1, suggesting it originated from the center of a 0.5 m diameter meteoroid, or deep inside a ~1.0 m meteoroid, less than 300 yr ago. Accounts exist of a fireball seen at 13:15 UT on March 2, 1895, that are consistent with the find location of Misfits Flat 002.  相似文献   
98.
99.
Our study concerned magnetic properties of soil profiles taken from polluted regions of Eastern Ukraine around the industrial centres Krivyj Rig, Mariupol and Komsomolsk. Soils represent chernozem and podzoluvisol. The low-field magnetic susceptibility shows enhancement in the topsoil caused by contamination by coarse-grain magnetite connected with industrial pollution. Magnetic mineralogy was determined by means of thermal demagnetisation of SIRM, monitoring of susceptibility changes during warming from ?196°C to room temperature and heating to 700°C, and Mössbauer analysis. Granulometry of magnetic particles was investigated by determination of hysteresis parameters, susceptibility, M s , SIRM and ARM ratios and frequency dependence of susceptibility. The chemical parameters, namely pH, organic carbon and iron content in different pedogenic and lithogenic minerals, measured for particular horizons determined pedogenic characteristic of soil profiles. Our study showed that differences in magnetic parameters of non-polluted and polluted soil profiles are not limited to the topsoil, but reach deep layers of the parent material. Industrial pollution promotes formation of the so-called “pedogenic” SP and SD particles in these layers.  相似文献   
100.
The presence of natural gas in the pore space of reservoir rocks results in a significant decrease in P-wave velocity. Even low gas saturation can generate seismic anomalies (DHI) and false image of gas accumulation of economic importance. This article presents an attempt to evaluate gas saturation from 2D seismic section in the Miocene sandstone strata in the south-eastern part of the Carpathian Foredeep. The ESTYMACJA program and the Biot-Gassmann model were used to study the dependence between elastic parameters and saturating fluids (water and gas) recorded in wells. Series of calculations was carried out using a method of fluid substitution for various gas saturation. The applicability of seismic data for evaluating gas saturation of reservoir beds was assessed with the use of 1D modelling (synthetic seismograms) and 2D modelling (theoretical seismic section) calculated for different gas saturation. The proposed methodology can be used to identify low and high gas-saturated zones and contour the reservoir.  相似文献   
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