Spatial variation of metal bioaccumulation in the hydrothermal vent mussel Bathymodiolus azoricus   总被引：1，自引：0，他引：1  

Cosson RP  Thiébaut E  Company R  Castrec-Rouelle M  Colaço A  Martins I  Sarradin PM  Bebianno MJ 《Marine environmental research》2008,65(5):405-415

The variability of the bioaccumulation of metals (Ag, Cd, Cu, Fe, Mn and Zn) was extensively studied in the mussel Bathymodiolus azoricus from five hydrothermal vent sites inside three main vent fields of increasing depth along the Mid-Atlantic Ridge: Menez Gwen, Lucky Strike and Rainbow. Metal bioaccumulation varied greatly between vent fields and even between sites inside a vent field with B. azoricus showing a great capacity to accumulate metals. The bioaccumulation of these metals also varied significantly among tissues. The main target was the gills where metals were mainly associated with soluble compounds whereas in the digestive gland they were mainly associated with insoluble compounds. Storage of metals under insoluble forms in B. azoricus seems to be a major pathway for the detoxification of both essential and non-essential metals. Mussels from the studied fields can be discriminated following their metallic load but the segregation relies partially on the composition of the metal-enriched fluids.  相似文献   

Cloud condensation nuclei from biomass burning during the Amazonian dry-to-wet transition season   总被引：1，自引：0，他引：1  

Jorge Alberto Martins  Fábio Luiz T. Gonçalves  Carlos A. Morales  Gilberto F. Fisch  Francisco Geraldo M. Pinheiro  João Bosco V. Leal Júnior  Carlos J. Oliveira  Emerson M. Silva  José Carlos P. Oliveira  Alexandre A. Costa  Maria Assunção F. Silva Dias 《Meteorology and Atmospheric Physics》2009,104(1-2):83-93

Aircraft measurements of cloud condensation nuclei (CCN) during the Large-Scale Biosphere–Atmosphere Experiment in Amazonia (LBA) were conducted over the Southwestern Amazon region in September–October 2002, to emphasize the dry-to-wet transition season. The CCN concentrations were measured for values within the range 0.1–1.0% of supersaturation. The CCN concentration inside the boundary layer revealed a general decreasing trend during the transition from the end of the dry season to the onset of the wet season. Clean and polluted areas showed large differences. The differences were not so strong at high levels in the troposphere and there was evidence supporting the semi-direct aerosol effect in suppressing convection through the evaporation of clouds by aerosol absorption. The measurements also showed a diurnal cycle following biomass burning activity. Although biomass burning was the most important source of CCN, it was seen as a source of relatively efficient CCN, since the increase was significant only at high supersaturations.  相似文献   

Turbulence Intensity Parameters over a Very Complex Terrain   总被引：1，自引：1，他引：0  

Cintya A. Martins  Osvaldo L. L. Moraes  Otávio C. Acevedo  Gervásio A. Degrazia 《Boundary-Layer Meteorology》2009,133(1):35-45

Detailed knowledge of turbulence structure is important for the understanding of atmospheric phenomena in the boundary layer, especially over complex terrain. In the present study, turbulence intensity parameters are analyzed for different conditions regarding stability, wind speed and wind direction over a mountainous region. The purpose of the analysis is to verify whether the observed parameters follow Monin–Obukhov similarity theory (MOST), despite the terrain heterogeneity. The dataset was collected during an experimental campaign at the Nova Roma do Sul site, in southern Brazil, with a micrometeorological tower located near a sharp slope, approximately 400 m high. The results show that the normalized standard deviations of the vertical velocity component as well as the normalized standard deviation of temperature follow Monin–Obukhov similarity for all stability regimes, regardless of the wind direction. However the normalized standard deviation of the horizontal components of the turbulent velocity obeys the similarity relationship only for a limited range of the stability parameters.  相似文献   

A constant dark matter halo surface density in galaxies     

F. Donato  G. Gentile  P. Salucci  C. Frigerio Martins  M. I. Wilkinson  G. Gilmore  E. K. Grebel  A. Koch  R. Wyse 《Monthly notices of the Royal Astronomical Society》2009,397(3):1169-1176

We confirm and extend the recent finding that the central surface density  μ_0D≡ r ₀ρ₀  of galaxy dark matter haloes, where r ₀ and  ρ₀  are the halo core radius and central density, is nearly constant and independent of galaxy luminosity. Based on the co-added rotation curves (RCs) of ∼1000 spiral galaxies, the mass models of individual dwarf irregular and spiral galaxies of late and early types with high-quality RCs, and the galaxy–galaxy weak-lensing signals from a sample of spiral and elliptical galaxies, we find that  log μ_0D= 2.15 ± 0.2  in units of  log(M_⊙ pc⁻²)  . We also show that the observed kinematics of Local Group dwarf spheroidal galaxies are consistent with this value. Our results are obtained for galactic systems spanning over 14 mag, belonging to different Hubble types and whose mass profiles have been determined by several independent methods. In the same objects, the approximate constancy of  μ_0D  is in sharp contrast to the systematical variations, by several orders of magnitude, of galaxy properties, including  ρ₀  and central stellar surface density.  相似文献   

Chemical and mineralogical evidence of the occurrence of mantle metasomatism by carbonate-rich melts in an oceanic environment (Santiago Island, Cape Verde)   总被引：1，自引：0，他引：1  

Sofia Martins  João Mata  José Munhá  Maria Hermínia Mendes  Claude Maerschalk  Rita Caldeira  Nadine Mattielli 《Mineralogy and Petrology》2010,99(1-2):43-65

Lavas from Santiago Island attest to a complex magmatic history, in which heterogeneous mantle source(s) and the interactions of advecting magmas with thick metasomatised oceanic lithosphere played an important role in the observed isotopic and trace element signatures. Young (<3.3 Ma) primitive lavas from Santiago Island are characterised by pronounced negative K anomalies and trace element systematics indicating that during partial melting D_K>D_Ce. These features suggest equilibration with an oceanic lithospheric mantle containing K-rich hydrous mineral assemblages, consistent with the occurrence of amphibole + phlogopite in associated metasomatised lherzolite xenoliths, where orthopyroxene is partially replaced by newly formed olivine + (CO₂ + spinel + carbonate inclusion-rich) clinopyroxene. Metasomatism induced a decrease in $ a ^{{{\text{melt}}}}_{{{\text{SiO}}_{{\text{2}}} }} $ and Ti/Eu ratios, as well as an increase in fO ₂ , Ca/Sc and Sr/Sm in the Santiago magmas, suggesting a carbonatitic composition for the metasomatic agent. Santiago primitive lavas are highly enriched in incompatible elements and show a moderate range in isotopic compositions (⁸⁷Sr/⁸⁶Sr?=?0.70318–0.70391, ¹⁴³Nd/¹⁴⁴Nd?=?0.51261–0.51287, ¹⁷⁶Hf/¹⁷⁷Hf?=?0.28284–0.28297). Elemental and isotopic signatures suggest the involvement of HIMU and EM1-type mantle end-members, in agreement with the overall isotopic characteristics of the southern Cape Verde Islands. The overall geochemical characteristics of lavas from Santiago Island allow us to consider the EM1-like end-member as resulting from the involvement of subcontinental lithospheric mantle in the genesis of magmas on Santiago.  相似文献   

Effects of the middle Holocene high sea-level stand and climate on Amazonian mangroves     

Marcelo C. L. Cohen  Paloma Maria Pinto Camargo  Luiz C. R. Pessenda  Flávio Lima Lorente  Adriana V. De Souza  José Augusto Martins Corrêa  José Bendassolli  Marianne Dietz 《第四纪科学杂志》2021,36(6):1013-1027

The high sea-level stand during the mid-Holocene is a benchmark in mangrove dynamics along the north-east/south-east coast of Brazil and provides a reference point for landward and seaward mangrove migrations corresponding to changes in relative sea level (RSL). However, evidence of the impacts associated with RSL fall on the northern Brazilian coast is scarce. Multi-proxy data from the highest tidal flats of the Bragança Peninsula in northern Brazil revealed modern herbaceous areas were occupied by mangroves Rhizophora and Avicennia from ~6250 to ~5850 cal a bp , and only Avicennia between ~5850 and ~5000 cal a bp . The same tidal flats were vegetation-free between ~5000 and ~4300 cal a bp . A combination of a high sea-level stand (0.6 ± 0.1 m) at ~5000 cal a bp and a dry early–middle Holocene in the Amazon probably caused an increase in porewater salinity of tidal flats, which resulted in a mangrove succession from Rhizophora to Avicennia dominance. RSL fall accentuated this process, contributing to mangrove degradation between ~5000 and ~4300 cal a bp . RSL fall, and a wetter period over the past ~4300 cal a bp caused a mangrove migration from highest to lowest flats, followed by expansion of herbaceous vegetation on the highest flats.  相似文献   

Morphological evolution of the Guadiana estuary and intertidal zone in response to projected sea‐level rise and sediment supply scenarios     

Dissanayake M.R. Sampath  Tomasz Boski  Patricia L. Silva  Flavio A. Martins 《第四纪科学杂志》2011,26(2):156-170

Analysis of Holocene sediment accumulation in the Guadiana estuary (southern Portugal) during sea‐level rise since ca. 13 cal. ka BP was used to simulate the long‐term morphological evolution of the lower Guadiana estuary and the associated intertidal zone for 21st‐century predicted sea‐level rises. Three sea‐level rise scenarios given by the IPCC ( 2007 ) were used in the simulations of morphology using a large‐scale behaviour‐oriented modelling approach. Sedimentation rate scenarios were derived both from the Holocene evolution of the estuary and from a semi‐empirical estimation of present‐day sediment aggradation. Our results show that the net lateral expansion of the intertidal zone area would be about 3–5% of the present intertidal zone area for each 10 cm rise in sea level. Under constraints imposed by the lack of fluvial sediment supply, the lateral expansion of the landward boundary of the intertidal zone will occur mainly in the Portuguese margin of the Guadiana estuary, while submergence of the salt marshes will occur in the Spanish margin. Therefore the Spanish margin is highly vulnerable to both sea‐level rise and lack of sediment supply. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Determination of Sulfamethoxazole and Trimethoprim and Their Metabolites in Hospital Effluent     

Carla G. B. Brenner  Carlos A. Mallmann  Daniel R. Arsand  Francieli M. Mayer  Ayrton F. Martins 《洁净——土壤、空气、水》2011,39(1):28-34

In this work, an analytical methodological study was carried out to determine the antimicrobials sulfamethoxazole and trimethoprim, as well as their metabolites, in hospital effluent. The determinations were conducted by liquid chromatography tandem mass spectrometry using a hybrid triple quadrupole‐linear ion trap mass spectrometer (LC‐QqLIT‐MS). The data acquisition was made in selected reaction monitoring (SRM) mode, in which two SRM transitions were monitored to ensure that the target compounds were accurately identified by the information dependent acquisition (IDA) function. The limits of detection (LOD) and quantification (LOQ) were 0.25 and 0.80 µg L^?1 for sulfamethoxazole and 0.15 and 0.50 µg L^?1 for trimethoprim. The linear range for the SMX was 0.8–100.0 µg L^?1 and TMP was 0.5–100.0 µg L^?1 on the basis of six‐point calibration curves generated by means of linear regression analysis. The coefficients of the correlation were higher than 0.999, which ensured the linearity of the method. The average concentration of sulfamethoxazole and trimethoprim found in hospital effluent was 27.8 and 6.65 µg L^?1, respectively. The analytical methodology employed allowed two metabolites to be identified, N4‐acetyl‐sulfamethoxazole and α‐hydroxy‐trimethoprim. Fragmentation pathways were proposed.  相似文献   

Fundamental constants and high‐resolution spectroscopy     

P. Bonifacio  H. Rahmani  J.B. Whitmore  M. Wendt  M. Centurion  P. Molaro  R. Srianand  M.T. Murphy  P. Petitjean  I.I. Agafonova  S. D'Odorico  T.M. Evans  S.A. Levshakov  S. Lopez  C.J.A.P. Martins  D. Reimers  G. Vladilo 《Astronomische Nachrichten》2014,335(1):83-91

Absorption‐line systems detected in high resolution quasar spectra can be used to compare the value of dimensionless fundamental constants such as the fine‐structure constant, α, and the proton‐to‐electron mass ratio, μ = m_p/m_e, as measured in remote regions of the Universe to their value today on Earth. In recent years, some evidence has emerged of small temporal and also spatial variations in α on cosmological scales which may reach a fractional level of ≈ 10 ppm (parts per million). We are conducting a Large Programme of observations with the Very Large Telescope's Ultraviolet and Visual Echelle Spectrograph (UVES), and are obtaining high‐resolution (R ≈ 60000) and high signal‐to‐noise ratio (S/N ≈ 100) spectra calibrated specifically to study the variations of the fundamental constants. We here provide a general overview of the Large Programme and report on the first results for these two constants, discussed in detail in Molaro et al. (2013) and Rahmani et al. (2013). A stringent bound for Δα /α is obtained for the absorber at z_abs = 1.6919 towards HE 2217‐2818. The absorption profile is complex with several very narrow features, and is modeled with 32 velocity components. The relative variation in α in this system is +1.3 ± 2.4_stat ± 1.0_sys ppm if Al II λ 1670 Å and three FeII transitions are used, and +1.1 ± 2.6_stat ppm in a slightly different analysis with only FeII transitions used. This is one of the tightest bounds on α ‐variation from an individual absorber and reveals no evidence for variation in α at the 3‐ppm precision level (1σ confidence). The expectation at this sky position of the recently‐reported dipolar variation of α is (3.2–5.4) ± 1.7 ppm depending on dipole model used and this constraint of Δα /α at face value is not supporting this expectation but not inconsistent with it at the 3σ level. For the proton‐to‐electron mass ratio the analysis of the H₂ absorption lines of the z_abs ≈ 2.4018 damped Lyα system towards HE 0027–1836 provides Δμ /μ = (–7.6 ± 8.1_stat ± 6.3_sys) ppm which is also consistent with a null variation. The cross‐correlation analysis between individual exposures taken over three years and comparison with almost simultaneous asteroid observations revealed the presence of a possible wavelength dependent velocity drift as well as of inter‐order distortions which probably dominate the systematic error and are a significant obstacle to achieve more accurate measurements. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Assessment of aquifer recharge and groundwater availability in a semiarid region of Brazil in the context of an interbasin water transfer scheme     

Costa  Alexandre C.  Dupont  Fanny  Bier  George  van Oel  Pieter  Walker  David W.  Martins  Eduardo S. P. R. 《Hydrogeology Journal》2023,31(3):751-769

Particularly in arid and semiarid areas, more and more populations rely almost entirely on imported water. However, the extent to which intentional discharge into transiting river systems and unintentional leakage may be augmenting water resources for communities along and down gradient of the water transfer scheme has not previously been subject to research. The objective of this study was to assess both the potential of a large-scale water transfer (WT) scheme to increase groundwater availability by channel transmission losses in a large dryland aquifer system (2,166 km²) in Brazil, and the capability of the receiving streams to transport water downstream under a prolonged drought. An integrated surface-water/groundwater model was developed to improve the estimation of the groundwater resources, considering the spatio-temporal variability of infiltrated rainfall for aquifer recharge. Aquifer recharge from the WT scheme was simulated under prolonged drought conditions, applying an uncertainty analysis of the most influential fluxes and parameters. The annual recharge (66 mm/year) was approximately twice the amount of water abstracted (1990–2016); however, the annual recharge dropped to 13.9 mm/year from 2012 to 2016, a drought period. Under similar drought conditions, the additional recharge (6.89 × 106 m³/year) from the WT scheme did not compensate for the decrease in groundwater head in areas that do not surround the receiving streams. Actually, the additional recharge is counteracted by a decrease of 25% of natural groundwater recharge or an increase of 50% in pumping rate; therefore, WT transmission losses alone would not solve the issue of the unsustainable management of groundwater resources.

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