Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements. 相似文献
Karst aquifers are characterized by a high degree of hydrologic variability and spatial heterogeneity of transport parameters. Tracer tests allow the quantification of these parameters, but conventional point-to-point experiments fail to capture spatiotemporal variations of flow and transport. The goal of this study was to elucidate the spatial distribution of transport parameters in a karst conduit system at different flow conditions. Therefore, six tracer tests were conducted in an active and accessible cave system in Vietnam during dry and wet seasons. Injections and monitoring were done at five sites along the flow system: a swallow hole, two sites inside the cave, and two springs draining the system. Breakthrough curves (BTCs) were modeled with CXTFIT software using the one-dimensional advection-dispersion model and the two-region nonequilibrium model. In order to obtain transport parameters in the individual sections of the system, a multi-pulse injection approach was used, which was realized by using the BTCs from one section as input functions for the next section. Major findings include: (1) In the entire system, mean flow velocities increase from 183 to 1,043 m/h with increasing discharge, while (2) the proportion of immobile fluid regions decrease; (3) the lowest dispersivity was found at intermediate discharge; (4) in the individual cave sections, flow velocities decrease along the flow direction, related to decreasing gradients, while (5) dispersivity is highest in the middle section of the cave. The obtained results provide a valuable basis for the development of an adapted water management strategy for a projected water-supply system. 相似文献
Water suppliers face major challenges such as climate change and population growth. To prepare for the future, detailed knowledge of water resources is needed. In southern Germany, the state water supplier Zweckverband Landeswasserversorgung provides 3 million people with drinking water obtained from a complex karst and alluvial aquifer system and the river Danube. In this study, a combination of different tracing techniques was used with the goal of a multi-scale characterization of the aquifer system and to gain additional knowledge about groundwater flow toward the extraction wells in the Danube Valley. For the small-scale characterization, selected groundwater monitoring wells were examined using single-borehole dilution tests. With these tests, a wide range of flow behavior could be documented, including fast outflow within just a few hours in wells with good connection to the aquifer, but also durations of many weeks in low-permeability formations. Vertical flow, caused by multiple flow horizons or uprising groundwater, was detected in 40% of the tested wells. A regional multi-tracer test with three injections was used to investigate the aquifer on a large scale. For the highly karstified connection between a swallow hole and a spring group, high flow velocities of around 80 m/h could be documented. Exceptionally delayed arrivals, 250 and 307 days after the injection, respectively showing maximum velocities of 0.44 and 0.39 m/h, were observed in an area where low-permeability sediments overlay the karst conduits. With the chosen methods, a distinct heterogeneity caused by the geological setting could be documented on both scales.
We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary. 相似文献
IFKIS-Hydro is an information and warning system for hydrological hazards in small- and medium-scale catchments. The system
collects data such as weather forecasts, precipitation measurements, water level gauges, discharge simulations and local observations
of event-specific phenomena. In addition, IFKIS-Hydro incorporates a web-based information platform, which serves as a central
hub for the submission and overview of data. Special emphasis is given to local information. This is accomplished particularly
by human observers. In medium-scale catchments, discharge forecast models have an increasing importance in providing valuable
information. IFKIS-Hydro was developed in several test regions in Switzerland and the first results of its application are
available now. The system is constantly extended to additional regions and may become the standard for warning systems in
smaller catchments in Switzerland. 相似文献
The larval fish assemblage was investigated in the shallow, nearshore region of a proposed marine protected area in eastern Algoa Bay, temperate South Africa, prior to proclamation. Sampling was conducted at six sites along two different depth contours at ∼5 m and ∼15 m to assess shore association. Larvae were collected by means of stepped oblique bongo net tows deployed off a ski-boat, twice per season for 2 years between 2005 and 2007. In total, 6045 larval fishes were collected representing 32 families and 78 species. The Gobiidae, Cynoglossidae, Clupeidae, Engraulidae and Sparidae were the dominant fish families. Catches varied significantly among seasons peaking in spring with a mean of ∼200 larvae/100 m3. Mean overall larval density was higher along the deeper contour, at ∼15 m (40 larvae/100 m3). The preflexion stage of development dominated catches at the ∼5 m (80%) and ∼15 m (73%) depth contours. Body lengths of Argyrosomus thorpei, Caffrogobius gilchristi, Diplodus capensis, Heteromycteris capensis and Solea turbynei, all estuary associated species, were larger at the shallow sites nearer to shore. Larvae of coastal species that produce benthic eggs dominated catches (75%) in the shallow sites (∼5 m) but were less abundant (32%) farther from shore at the deeper (∼15 m) sites. All developmental stages of D. capensis, Engraulis capensis, H. capensis, Sardinops sagax and two Pomadasys species were found in the study area. It appears that some species use the shallow nearshore as a nursery area. 相似文献
Mapping and monitoring carbon stocks in forested regions of the world, particularly the tropics, has attracted a great deal
of attention in recent years as deforestation and forest degradation account for up to 30% of anthropogenic carbon emissions,
and are now included in climate change negotiations. We review the potential for satellites to measure carbon stocks, specifically
aboveground biomass (AGB), and provide an overview of a range of approaches that have been developed and used to map AGB across
a diverse set of conditions and geographic areas. We provide a summary of types of remote sensing measurements relevant to
mapping AGB, and assess the relative merits and limitations of each. We then provide an overview of traditional techniques
of mapping AGB based on ascribing field measurements to vegetation or land cover type classes, and describe the merits and
limitations of those relative to recent data mining algorithms used in the context of an approach based on direct utilization
of remote sensing measurements, whether optical or lidar reflectance, or radar backscatter. We conclude that while satellite
remote sensing has often been discounted as inadequate for the task, attempts to map AGB without satellite imagery are insufficient.
Moreover, the direct remote sensing approach provided more coherent maps of AGB relative to traditional approaches. We demonstrate
this with a case study focused on continental Africa and discuss the work in the context of reducing uncertainty for carbon
monitoring and markets. 相似文献