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Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   
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Underwater photogrammetry provides an efficient nondestructive means for measurement in environments with limited accessibility. With the growing use of consumer cameras, its application is becoming easier, thus benefiting a wide variety of disciplines. However, utilizing cameras for underwater photogrammetry poses some nontrivial modeling problems due to refraction effect and the extension of the imaging system into a unit of both the camera and the protecting housing device. This paper studies the effect that the underwater environment has on the photogrammetric process, and proposes a model for describing the geometric distortions and for estimating the additional parameters involved. The proposed model accounts not only for the multimedia effect, but also for inaccuracies related to the setting of the camera and housing device. The paper shows that only a small number of additional parameters is needed to model both elements and to preserve the collinearity relation. The results show that no unique setup is needed for estimating the additional parameters and that the estimation is insensitive to noise or first approximations. Experiments show that high levels of accuracy can be achieved.  相似文献   
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A rockfall is a mass instability event frequently observed in road cuts, open pit mines and quarries, steep slopes and cliffs. After its detachment, the rock mass may disaggregate and break due to the impact with the ground surface, thus producing new rock fragments. The consideration of the fragmentation of the rockfall mass is critical for the calculation of the trajectories of the blocks and the impact energies and for the assessment of the potential damage and the design of protective structures. In this paper, we present RockGIS, a GIS-based tool that simulates stochastically the fragmentation of the rockfall, based on a lumped mass approach. In RockGIS, the fragmentation is triggered by the disaggregation of the detached rock mass through the pre-existing discontinuities just before the impact with the ground. An energy threshold is defined in order to determine whether the impacting blocks break or not. The distribution of the initial mass between a set of newly generated rock fragments is carried out stochastically following a power law. The trajectories of the new rock fragments are distributed within a cone. The fragmentation model has been calibrated and tested with a 10,000 m3 rockfall that took place in 2011 near Vilanova de Banat, Eastern Pyrenees, Spain.  相似文献   
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Doñana National Park is an area of approximately 500 km2 located on the SW coast of Spain that shows one of the greatest geoid gradients on the entire Iberian Peninsula, due to its peculiar tectonic characteristics. So, it is necessary to elaborate an accurate geoid model that can be used with GPS for precise surveying, since the existing ones are insufficient, due to their poor resolution and their limited adaptation to a small area with such a strong gradient. The least squares prediction method was tested in order to obtain the undulation from GPS/orthometric points. The results obtained were unsatisfactory because of the strong geoid gradient. In order to improve accuracy the remove-restore technique was used. Global geopotential model EIGEN-CG01C and a Digital Elevation Model (DEM) with a 25 × 25 m resolution and an accuracy better than 3 m were used. Thus, the final geometrical geoid obtained reaches the precision required by other disciplines (3 cm in any point within the Park). Particularly, the geoid model has allowed for the acquisition of a precision DEM that is essential to formulate a hydrodynamic model for the Doñana marsh functions.  相似文献   
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In this paper we present a study concerning the climatic behaviour of two principal observables, temperature and precipitation as obtained from the measurements carried out at 50 Italian meteorological stations, since 1961. Analyses of WMO Climate Normals (CliNo) from 1961 to 1990 have been performed dividing the 50 Italian stations in three different classes: mountain (11 stations), continental (17) and coastal areas (21).The comparison of the CliNo 1961–1990 with the trend of temperature and precipitation for the period 1991–2000 showed a sharp significant increase of summer temperatures over Italy starting from 1980. This phenomenon was particularly evident for mountain stations, where a significant temperature increase has been recorded also during the autumn. Moreover, the analysis of precipitation data permitted to point out that, starting from 1980, mountain stations have been affected by a significant increase of precipitation events during autumn and winter, while for the rest of the Italian territory a reduction of precipitations has been recorded during early spring.  相似文献   
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Stability conditions in an area located NW of Barcelona (Spain) are discussed. Here, several mass movements were observed, mainly affecting weathered Paleozoic slates. Many of these failures involved slopes cut along recent infrastructures: debris flows, wedge and plane failures, generally surficial, occurred more frequently. After a detailed geological and geomorphologic survey, geomechanic characterization was carried out, according to RMR and SMR classifications. This rating gave a prediction of slope behaviour, in fairly good agreement with the real observed one.

Stability numerical analysis was carried out for the main cut slopes, based upon the Limit Equilibrium Method. First of all, the deterministic factor of safety was computed using the mean values of parameters. After that, a simulation technique based upon the Monte Carlo Method was applied in order to obtain factor of safety distributions. The probability of failure was estimated as P(F<1).

Finally, results from deterministic and probabilistic approaches were compared. The effectiveness of different possible remedial measures was highlighted by means of a sensitivity analysis, which showed that the more important parameters in the study area are the geometrical ones (height, slope and failure plane angles). The final technical solutions adopted are briefly outlined.  相似文献   

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