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201.
This work evaluated the presence and the frequency of occurrence of marine litter in the gastrointestinal tract of 31 Caretta caretta found stranded or accidentally bycaught in the North Tyrrhenian Sea. Marine debris were present in 71% of specimens and were subdivided in different categories according to Fulmar Protocol (OSPAR 2008). The main type of marine debris found was user plastic, with the main occurrence of sheetlike user plastic. The small juveniles showed a mean ± SD of marine debris items of 19.00 ± 23.84, while the adult specimens showed higher values of marine litter if compared with the juveniles (26.87 ± 35.85). The occurrence of marine debris observed in this work confirms the high impact of marine debris in the Mediterranean Sea in respect to other seas and oceans, and highlights the importance of Caretta caretta as good indicator for marine litter in the Marine Strategy Framework Directive (MSFD) of European Union.  相似文献   
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A multidisciplinary approach that combines field measurements, artificial neural networks, water balance analyses and hydrodynamic modelling was developed to investigate the water budget and renewal capacity of semi-closed coastal systems. The method was applied to the Lesina Lagoon, a micro-tidal lagoon in the southern Adriatic Sea (Italy). Surface water flux between the lagoon and the sea was determined by neural network prediction and used as input in the analysis. Strong seasonal variations in the water budget equation were predicted. Fresh water inputs estimated by the water balance analysis were used as forcing by a calibrated finite element model to describe the water circulation and transport time scale of the lagoon’s surface waters. The model highlighted the spatial heterogeneity of the renewal behaviour of the system, with a strong east–west water renewal time gradient. Knowledge of spatial distribution of water renewal times is crucial for understanding the lagoon’s renewal capacity and explaining the high spatial variability of the biogeochemistry of the Lesina Lagoon.  相似文献   
204.
The trace-element composition of rutile is commonly used to constrain PTt conditions for a wide range of metamorphic systems. However, recent studies have demonstrated the redistribution of trace elements in rutile via high-diffusivity pathways and dislocation-impurity associations related to the formation and evolution of microstructures. Here, we investigate trace-element migration in low-angle boundaries formed by dislocation creep in rutile within an omphacite vein of the Lago di Cignana unit (Western Alps, Italy). Zr-in-rutile thermometry and inclusions of quartz in rutile and of coesite in omphacite constrain the conditions of rutile deformation to around the prograde boundary from high pressure to ultra-high pressure (~2.7 GPa) at temperatures of 500–565°C. Crystal-plastic deformation of a large rutile grain results in low-angle boundaries that generate a total misorientation of ~25°. Dislocations constituting one of these low-angle boundaries are enriched in common and uncommon trace elements, including Fe and Ca, providing evidence for the diffusion and trapping of trace elements along the dislocation cores. The role of dislocation microstructures as fast-diffusion pathways must be evaluated when applying high-resolution analytical procedures as compositional disturbances might lead to erroneous interpretations for Ca and Fe. In contrast, our results indicate a trapping mechanism for Zr.  相似文献   
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