This paper presents the experimental results of composition changes of heavy fuel oil by simulating weathering in static seawater under natural environmental conditions. The results indicate: n-C10 to n-C15 were lost gradually in 24 weeks and the relative abundance of alkanes with long chains (n-C19) increased markedly. The aromatic compounds with less than two rings (except C4N) were completely lost in 24 weeks and CnP and CnD became the main aromatics in the heavy fuel oil after 24 weeks. The ratios of n-C17/Pristane (Pr) and n-C18/Phytane (Ph) were suitable for identifying lightly weathered (3 weeks) heavy fuel oil. The ratios of n-C17/n-C18 and Pr/Ph were suitable for identifying moderately weathered heavy fuel oil (12 weeks); the ratios of C2D/C2P and C3D/C3P did not change significantly in 24 weeks and were more suitable for identifying moderately weathered heavy fuel oil (24 weeks). 相似文献
Infiltration losses may be significant and warrant proper incorporation into mathematical models for river floods in arid and semi-arid areas, rainfall-induced surface runoffs in watersheds and swashes on beaches. Here, a depth-averaged two-dimensional hydrodynamic model is presented for such processes based on the cell-centred finite volume method on unstructured meshes, with the full Green-Ampt equation evaluating the infiltration rate. A local time stepping strategy is employed along with thread parallelization with Open Multi-processing and high-performance computing to reduce model run time and therefore facilitate applications for large-scale processes. The numerical solutions generally agree with the experimental and field-measured data for typical cases with significant infiltration losses. The case study shows that neglecting infiltration leads to an overestimated discharge hydrograph, which cannot be compensated by means of varied bed resistance as estimated by Manning roughness, and the infiltration parameters play disparate roles in modifying shallow flows compared with Manning roughness. In addition, infiltration affects bed shear stress, which in turn modifies the critical bed sediment size that could be initiated for incipient motion by the flow and therefore needs to be properly accounted for when sediment transport and morphological evolution are to be resolved. 相似文献
Improving the engineering properties of low-strength soft clay in an environmentally friendly way becomes a challenge in coastal areas. Conventional ground treatment techniques for marine clay using cement can cause significant environmental pollution. In this study, the potential use of industrial waste residue-based binder (IWRB), a silicate-based chemical modified by a powdery polymer, as a substitute for Portland cement (PC) is investigated. Collected marine clay was treated with various IWRB-to-PC ratios (0:8, 4:4, 2:6 and 8:0 wt. %) to measure the mechanical properties, through unconfined compression (UC) test and one-dimensional consolidation (ODC) test, and the microstructural and mineralogical characters, through scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetry analysis (TGA) and Fourier transform infrared spectroscopy (FT-IR). The strength and the deformation of specimens treated with mixed IWRB and PC in a ratio of 1:1 were similar to those improved with PC alone, but the toughness was significantly improved. The microstructural results demonstrated that the cementitious compounds (C–S–H and C–A–S–H) increased significantly in the early curing stage of marine clay treated with IWRB, contributing to the improvement of mechanical properties. It is suggested that IWRB can be an effective substitute for PC to reduce the cost and environmental pollution.
贵州涟江惠水段级次清晰的四级阶地是流域地貌阶段性演化的直观记录。笔者等利用差分GPS测量法精确厘定了涟江阶地的级序和高程,结合剖面观测发现从上游到下游,涟江惠水段阶地标高和级差逐渐降低,地貌面整体呈“收拢”趋势;阶地沉积物呈现砾石层厚度变小,砾石含量降低、砾径减小,砂质沉积占比增大趋势;阶地类型从基座阶地为主向堆积阶地为主演变。光释光(OSL)测年显示,T1阶地埋藏年龄31.2±2.0 ka BP到14.7±1.3 ka BP,T2阶地122.4±8.5 ka BP到66.9±3.8 ka BP,阶地年龄与贵州高原其他流域十分相近,具有同步演化特征。结合阶地时代和发育特征,认为贵州高原河流阶地是构造运动的产物。涟江四级阶地记录了在更新世以来四次构造抬升背景下,流域经过多期自北向南“削高补低”的地貌改造,逐步由构造洼地演变为山间盆地的地貌过程。 相似文献
