A computer simulation study of natural silicate melts. Part II: High pressure properties     

Bertrand Guillot  Nicolas Sator 《Geochimica et cosmochimica acta》2007,71(18):4538-4556

The thermodynamic, structural and transport properties of natural silicate melts under pressure are investigated by molecular dynamics simulation with the help of a force field recently introduced by us [Guillot B. and Sator N. (2007) A computer simulation study of natural silicate melts. Part I: low pressure properties. Geochim. Cosmochim. Acta71, 1249-1265]. It is shown that the simulation reproduces accurately the bulk moduli of a large variety of silicate liquids as evaluated from ultrasonic studies. The equations of state (EOS) of the simulated melts are in good agreement with the density data on mid-ocean ridge basalt, komatiite, peridotite and fayalite as obtained either by sink/float experiments or by shock-wave compression. From the structural point of view it is shown that the population of ^[5]Al and ^[6]Al species increases rapidly upon initial compression (0-50 kbar) whereas for Si these highly coordinated species are found in a significant abundance (>5%) only above ∼50 kbar for ^[5]Si and ∼100-150 kbar for ^[6]Si. This increase of the coordination of network formers is not the only response of the melt structure to the densification: there is also a large redistribution of the T-O-T (T = Si, Al) bond angles with the pressure and noticeably upon initial compression in rhyolitic and basaltic liquids. Furthermore, a detailed analysis of the population of bridging oxygens (BO) and nonbridging oxygens (NBO) points out that the polymerization of the melt generally increases when the pressure increases, the magnitude of this polymerization enhancement being all the more important that the melt is depolymerized at low pressure. The role of triclusters (threefold coordinated oxygens to network former cations) is particularly emphasized in acidic and basaltic liquids. The pressure-induced redistribution of the oxygen atoms through the melt structure is also stressed. Finally, the simulation predicts a nonmonotonic behavior of the diffusivity of network former ions when the pressure increases, a feature with depends on the melt composition. This could have a counterpart in the electrical conductivity at sufficiently high temperature when the viscosity of the liquid is low.  相似文献   

From land to sea: provenance,composition, and preservation of organic matter in a marine sediment record from the North-East Greenland shelf spanning the Younger Dryas–Holocene     

Nanna Andreasen  Rebecca Jackson  Arka Rudra  Henrik Nøhr-Hansen  Hamed Sanei  Jørgen Bojesen-Koefoed  Marit-Solveig Seidenkrantz  Christof Pearce  Nicolas Thibault  Sofia Ribeiro 《Boreas: An International Journal of Quaternary Research》2023,52(4):459-475

The organic matter content of marine sediments is often used to infer past changes in ocean conditions. However, the organic carbon pool preserved in coastal sediments is a complex mixture derived from different sources and may not reflect in situ processes. In this study, we combine taxonomic identification of reworked palynomorphs with pyrolysis organic geochemistry and reflected-light organic petrographic microscopy to investigate the provenance, composition and preservation of organic matter in a marine sediment core retrieved from the NE Greenland shelf. Our study reveals continuous yet variable input of land-derived organic carbon to the marine environment throughout the late Younger Dryas–Holocene, with the highest input of inert carbon in the late Younger Dryas. Although the sediments contain some recent marine palynomorphs, there is no other evidence of fresh marine organic carbon. In contrast, our results indicate that these shelf sediments represent a significant sink of recycled organic carbon. The results of pyrolysis geochemistry revealed that ~90% of the total organic carbon in the sediments is inert. The organic petrography analyses revealed that >70–84% of the organic carbon in the sediment core is terrigenous. Reworked dinoflagellate cysts showed a continuous provenance of Cretaceous land-derived material, most likely from the nearby Clavering Island. Our study points to the importance of constraining the organic matter origin, composition and preservation in marine sediments to achieve more accurate palaeoenvironmental reconstructions based on organic proxies.  相似文献   

Environmental change in subtropical South America for the last two millennia as shown by lacustrine pigments     

Lisa Coianiz  Daniel Ariztegui  Eduardo L. Piovano  Andrea Lami  Piero Guilizzoni  Stefano Gerli  Nicolas Waldmann 《Journal of Paleolimnology》2015,53(2):233-250

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Comet McNaught (260P/2012 K2): spin axis orientation and rotation period     

Federico Manzini  Virginio Oldani  Roberto Crippa  José Borrero  Erik Bryssink  Martin Mobberley  Joel Nicolas 《Astrophysics and Space Science》2014,351(2):435-450

Extensive observations of comet 260P/McNaught were carried out between August 2012 and January 2013. The images obtained were used to analyze the comet’s inner coma morphology at resolutions ranging from 250 to about 1000 km/pixel. A deep investigation of the dust features in the inner coma allowed us to identify only a single main active source on the comet’s nucleus, at an estimated latitude of ?50^°±15^°. A thorough analysis of the appearance and of the motion of the morphological structures, supported by graphic simulations of the geometrical conditions of the observations, allowed us to determine a pole orientation located within a circular spot of a 15^°-radius centered at RA=60^°, Dec=0^°. The rotation of the nucleus seems to occur on a single axis and is not chaotic, furthermore no precession effects could be estimated from our measurements. The comet’s spin axis never reached the plane of the sky from October 2012 to January 2013; during this period it did not change its direction significantly (less than 30^°), thus giving us the opportunity to observe mainly structures such as bow-shaped jets departing from the single active source located on the comet’s nucleus. Only during the months of August 2012 and January 2013 the polar axis was directed towards the Earth at an angle of about 45^° from the plane of the sky; this made it possible to observe the development of faint structures like fragments of shells or spirals. A possible rotation period of 0.340±0.01 days was estimated by means of differential photometric analysis.  相似文献   

SPIRE point source photometry: within the Herschel interactive processing environment (HIPE)     

Chris Pearson  Tanya Lim  Chris North  George Bendo  Luca Conversi  Darren Dowell  Matt Griffin  Terry Jin  Nicolas Laporte  Andreas Papageorgiou  Bernhard Schulz  Dave Shupe  Anthony J. Smith  Kevin Xu 《Experimental Astronomy》2014,37(2):175-194

The different algorithms appropriate for point source photometry on data from the SPIRE instrument on-board the Herschel Space Observatory, within the Herschel Interactive Processing Environment (HIPE) are compared. Point source photometry of a large ensemble of standard calibration stars and dark sky observations is carried out using the 4 major methods within HIPE: SUSSEXtractor, DAOphot, the SPIRE Timeline Fitter and simple Aperture Photometry. Colour corrections and effective beam areas as a function of the assumed source spectral index are also included to produce a large number of photometric measurements per individual target, in each of the 3 SPIRE bands (250, 350, 500μm), to examine both the accuracy and repeatability of each of the 4 algorithms. It is concluded that for flux densities down to the level of 30mJy that the SPIRE Timeline Fitter is the method of choice. However, at least in the 250 and 350μm bands, all 4 methods provide photometric repeatability better than a few percent down to at approximately 100mJy. The DAOphot method appears in many cases to have a systematic offset of ～8 % in all SPIRE bands which may be indicative of a sub-optimal aperture correction. In general, aperture photometry is the least reliable method, i.e. largest scatter between observations, especially in the longest wavelength band. At the faintest fluxes, <30mJy, SUSSEXtractor or DAOphot provide a better alternative to the Timeline Fitter.  相似文献   

The Herschel-PACS photometer calibration     

Zoltan Balog  Thomas Müller  Markus Nielbock  Bruno Altieri  Ulrich Klaas  Joris Blommaert  Hendrik Linz  Dieter Lutz  Attila Moór  Nicolas Billot  Marc Sauvage  Koryo Okumura 《Experimental Astronomy》2014,37(2):129-160

This paper provides an overview of the PACS photometer flux calibration concept, in particular for the principal observation mode, the scan map. The absolute flux calibration is tied to the photospheric models of five fiducial stellar standards (α Boo, α Cet, α Tau, β And, γ Dra). The data processing steps to arrive at a consistent and homogeneous calibration are outlined. In the current state the relative photometric accuracy is ～2 % in all bands. Starting from the present calibration status, the characterization and correction for instrumental effects affecting the relative calibration accuracy is described and an outlook for the final achievable calibration numbers is given. After including all the correction for the instrumental effects, the relative photometric calibration accuracy (repeatability) will be as good as 0.5 % in the blue and green band and 2 % in the red band. This excellent calibration starts to reveal possible inconsistencies between the models of the K-type and the M-type stellar calibrators. The absolute calibration accuracy is therefore mainly limited by the 5 % uncertainty of the celestial standard models in all three bands. The PACS bolometer response was extremely stable over the entire Herschel mission and a single, time-independent response calibration file is sufficient for the processing and calibration of the science observations. The dedicated measurements of the internal calibration sources were needed only to characterize secondary effects. No aging effects of the bolometer or the filters have been found. Also, we found no signs of filter leaks. The PACS photometric system is very well characterized with a constant energy spectrum νF _ν = λF _λ = const as a reference. Colour corrections for a wide range of sources SEDs are determined and tabulated.  相似文献   

Seismic‐stratigraphic record of a deglaciation sequence: from the marine Laflamme Gulf to Lake Saint‐Jean (late Quaternary,Québec,Canada)     

Alexis Nutz  Jean‐François Ghienne  Mathieu Schuster  Raphaël Certain  Nicolas Robin  Claude Roquin  Olivier Raynal  Frédéric Bouchette  Philippe Duringer  Pierre A. Cousineau 《Boreas: An International Journal of Quaternary Research》2014,43(2):309-329

The stratigraphy of the last deglaciation sequence is investigated in Lake Saint‐Jean (Québec Province, Canada) based on 300 km of echo‐sounder two dimensional seismic profiles. The sedimentary archive of this basin is documented from the Late Pleistocene Laurentidian ice‐front recession to the present‐day situation. Ten seismic units have been identified that reflect spatio‐temporal variations in depositional processes characterizing different periods of the Saint‐Jean basin evolution. During the postglacial marine flooding, a high deposition rate of mud settling, from proglacial glacimarine and then prodeltaic plumes in the Laflamme Gulf, produced an extensive, up to 50 m thick mud sheet draping the isostatically depressed marine basin floor. Subsequently, a closing of the water body due to glacio‐isostatic rebound occurred at 8.5 cal. ka BP, drastically modifying the hydrodynamics. Hyperpycnal flows appeared because fresh lake water replaced dense marine water. River sediments were transferred towards the deeper part of the lake into river‐related sediment drifts and confined lobes. The closing of the water body is also marked by the onset of a wind‐driven internal circulation associating coastal hydrodynamics and bottom currents with sedimentary features including shoreface deposits, sediment drifts and a prograding shelf‐type body. The fingerprints of a forced regression are well expressed by mouth‐bar systems and by the shoreface–shelf system, the latter unexpected in such a lacustrine setting. In both cases, a regressive surface of lacustrine erosion (RSLE) has been identified, separating sandy mouth‐bar from glaciomarine to prodeltaic muds, and sandy shoreface wedges from the heterolithic shelf‐type body, respectively. The Lake Saint‐Jean record is an example of a regressive succession driven by a glacio‐isostatic rebound and showing the transition from late‐glacial to post‐glacial depositional systems.  相似文献   

Rotation of a rigid satellite with a fluid component: a new light onto Titan’s obliquity     

Gwenaël Boué  Nicolas Rambaux  Andy Richard 《Celestial Mechanics and Dynamical Astronomy》2017,129(4):449-485

We revisit the rotation dynamics of a rigid satellite with either a liquid core or a global subsurface ocean. In both problems, the flow of the fluid component is assumed inviscid. The study of a hollow satellite with a liquid core is based on the Poincaré–Hough model which provides exact equations of motion. We introduce an approximation when the ellipticity of the cavity is low. This simplification allows to model both types of satellite in the same manner. The analysis of their rotation is done in a non-canonical Hamiltonian formalism closely related to Poincaré’s “forme nouvelle des équations de la mécanique”. In the case of a satellite with a global ocean, we obtain a seven-degree-of-freedom system. Six of them account for the motion of the two rigid components, and the last one is associated with the fluid layer. We apply our model to Titan for which the origin of the obliquity is still a debated question. We show that the observed value is compatible with Titan slightly departing from the hydrostatic equilibrium and being in a Cassini equilibrium state.  相似文献   

Solar Prominence Modelling and Plasma Diagnostics at ALMA Wavelengths     

Andrew Rodger  Nicolas Labrosse 《Solar physics》2017,292(9):130

Our aim is to test potential solar prominence plasma diagnostics as obtained with the new solar capability of the Atacama Large Millimeter/submillimeter Array (ALMA). We investigate the thermal and plasma diagnostic potential of ALMA for solar prominences through the computation of brightness temperatures at ALMA wavelengths. The brightness temperature, for a chosen line of sight, is calculated using the densities of electrons, hydrogen, and helium obtained from a radiative transfer code under non-local thermodynamic equilibrium (non-LTE) conditions, as well as the input internal parameters of the prominence model in consideration. Two distinct sets of prominence models were used: isothermal-isobaric fine-structure threads, and large-scale structures with radially increasing temperature distributions representing the prominence-to-corona transition region. We compute brightness temperatures over the range of wavelengths in which ALMA is capable of observing (0.32?–?9.6 mm), however, we particularly focus on the bands available to solar observers in ALMA cycles 4 and 5, namely 2.6?–?3.6 mm (Band 3) and 1.1?–?1.4 mm (Band 6). We show how the computed brightness temperatures and optical thicknesses in our models vary with the plasma parameters (temperature and pressure) and the wavelength of observation. We then study how ALMA observables such as the ratio of brightness temperatures at two frequencies can be used to estimate the optical thickness and the emission measure for isothermal and non-isothermal prominences. From this study we conclude that for both sets of models, ALMA presents a strong thermal diagnostic capability, provided that the interpretation of observations is supported by the use of non-LTE simulation results.  相似文献   

Evaluation of the Global Mean Sea Level Budget between 1993 and 2014     

Don P. Chambers  Anny Cazenave  Nicolas Champollion  Habib Dieng  William Llovel  Rene Forsberg  Karina von Schuckmann  Yoshihide Wada 《Surveys in Geophysics》2017,38(1):309-327

Evaluating global mean sea level (GMSL) in terms of its components—mass and steric—is useful for both quantifying the accuracy of the measurements and understanding the processes that contribute to GMSL rise. In this paper, we review the GMSL budget over two periods—1993 to 2014 and 2005 to 2014—using multiple data sets of both total GMSL and the components (mass and steric). In addition to comparing linear trends, we also compare the level of agreement of the time series. For the longer period (1993–2014), we find closure in terms of the long-term trend but not for year-to-year variations, consistent with other studies. This is due to the lack of sufficient estimates of the amount of natural water mass cycling between the oceans and hydrosphere. For the more recent period (2005–2014), we find closure in both the long-term trend and for month-to-month variations. This is also consistent with previous studies.  相似文献