Une approche innovante pour modéliser la biodégradation des composés organochlorés volatils en aquifères poreux     

Fabien Nex  Gerhard Schäfer  Jean-Marie Côme  Timothy M. Vogel 《Comptes Rendus Geoscience》2006,338(5):297-306

The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).  相似文献   

Assessing the Vibrational Frequencies of the Cathedral of Cologne (Germany) by Means of Ambient Seismic Noise Analysis   总被引：1，自引：0，他引：1  

Andreas Fäcke  Stefano Parolai  Sandra M. Richwalski  Lothar Stempniewski 《Natural Hazards》2006,38(1-2):229-236

Ambient seismic noise measurements were conducted inside the Cathedral of Cologne (Germany) for assessing its frequencies of vibration and for checking whether these occur in the range where soil amplification is expected. If this is the case, damages may increase in case of an earthquake due to an increased structural response of the building. Analysis of the ratio between the horizontal and vertical components of the spectra recorded at stations located inside the building as well as the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference station placed in the basement of the cathedral indicated several modes of vibration. Facilitated by these results an assessment of the seismic vulnerability was attempted for a 2D ground motion scenario using the finite element method.  相似文献   

A Comparison of Sediment Varves (1950–2003 AD) in Two Adjacent Lakes in Northern Sweden     

V. Gälman  G. Petterson  I. Renberg 《Journal of Paleolimnology》2006,35(4):837-853

Koltjärnen and Nylandssjön are two closely situated lakes (<2 km apart) in northern Sweden. During the past century, distinct varved sediments have formed in these lakes. Nylandssjön has two varved, deep basins. Since lake and catchment characteristics superficially appear very similar for the two lakes and they are exposed to the same climate, one would expect the sediment varves to be similar. This investigation compares the varves in the two deep basins of Nylandssjön, and in the two lakes. The comparison of basins of Nylandssjön shows that varve thickness, water content and annual accumulation rates of organic matter and nitrogen are correlated for the period (1970–2003). The grey-scale curves are only clearly similar in about 50% of the varves. In the between-lake comparison varve thickness, water content and annual accumulation rates of organic matter and nitrogen are correlated for the period (1950–1996). However, the annual accumulation rates of dry mass, minerogenic matter and biogenic silica differ between the lakes, as well as within-varve successions in grey-scale. A general explanation to the differences is that the prerequisites for varve formation are not totally similar because of differences in catchment size, catchment- to-lake material fluxes, lake productivity and land-use influence. This study illustrates the complex relationships that exist between a lake, its catchment, in-lake productivity and formation of sediment varves. As a consequence, we must not apply a too simplistic view of the potential of varves as past climatic indicators, especially if the lakes are affected by land-use.  相似文献   

Modification of streaming potential by precipitation of calcite in a sand–water system: laboratory measurements in the pH range from 4 to 12     

Xavier Guichet  Laurence Jouniaux  Nicole Catel 《Geophysical Journal International》2006,166(1):445-460

  相似文献   

Tackling social exclusion in European neighbourhoods: experiences and lessons from the NEHOM project     

Anneli Kährik 《GeoJournal》2006,67(1):9-25

Disadvantaged urban neighbourhoods with their complex social, economic and physical situations have increasingly become the focus of governmental policies in the EU. The emphasis has shifted from improving physical qualities to building opportunities for social groups in these areas. While physical upgrade is easier to achieve, at least in the short run, initiatives often fail in outcomes on communities and local participation. This paper aims to improve understanding on how to tackle area-based social exclusion and create socially coherent communities. Building on the results of the NEHOM project, the focus is on examining how various interventions have impacted local communities and their opportunities for better inclusion. A comparison between neighbourhoods shows that mixing social groups to a certain degree is likely to be a necessary step towards opening long-term opportunities for a disadvantaged neighbourhood. The planned initiatives should at the same time directly benefit local communities, and the involvement of local groups in the planning and implementation process helps to guarantee that the overall changes are accepted by the local community. However, the proposed guidelines do not provide a universal recipe for a successful renewal suiting each neighbourhood—the contextual matters should always be a starting point when planning an initiative.  相似文献   

Formation of iron-containing colloids by the weathering of phyllite     

Harald Zänker  Gudrun Hüttig  Thuro Arnold  Heino Nitsche 《Aquatic Geochemistry》2006,12(4):299-325

The formation of colloids during the weathering of phyllite was investigated by exposing ground phyllite to Milli-Q water. Secondary mineral colloids of 10¹–10² nm were detected in significant concentrations. At pH of about 8.5, the solution concentration of these colloids reached up to 10 mg/L (however, acidification to pH 4.0 prevented the formation of the colloids). The mineralogical composition of the secondary mineral colloids is assumed to be a mixture of ferrihydrite, manganese oxyhydroxides, aluminosilicates, amorphous Al(OH)₃ and gibbsite with possible additions of iron silicates and␣iron-alumino silicates. The colloids were stable over longer periods of time (at least several weeks), even in the presence of suspended ground rock. Direct formation of iron-containing secondary mineral colloids at the rock–water interface by the weathering of rock material is an alternative to the well-known mechanism of iron colloid formation in the bulk of water bodies by mixing of different waters or by aeration of anoxic waters. This direct mechanism is of relevance for colloid production during the weathering of freshly crushed rock in the unsaturated zone as for instance crushed rock in mine waste rock piles. Colloids produced by this mechanism, too, can influence the transport of contaminants such as actinides because these colloids have a large specific surface area and a high sorption affinity.  相似文献   

Dissolved Trace Metal–Organic Complexes in the Lot–Garonne River System Determined Using the C18 Sep-Pak System     

E. Lemaire  G. Blanc  J. Schäfer  A. Coynel  H. Etcheber 《Aquatic Geochemistry》2006,12(1):21-38

An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd, Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g⁻¹) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture, sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport.  相似文献   

Facies partitioning and sequence stratigraphy of cool-water, mixed carbonate-siliciclastic sediments (Upper Miocene Guadalquivir Domain, southern Spain)     

I. Gläser  C. Betzler 《International Journal of Earth Sciences》2002,91(6):1041-1053

During the late Miocene, the Guadalquivir Basin and its satellite basin, the Ronda Basin, were under Atlantic cool-water influence. The aim of our study is to develop a sequence stratigraphic subdivision of the Ronda Basin fill and to provide models for the cool-water carbonates. The Upper Miocene of the Ronda Basin can be divided into three depositional sequences. Sequence 1 is early Tortonian, Sequence 2 late Tortonian to earliest Messinian, and Sequence 3 Messinian in age. The sediments were deposited in a ramp depositional system. Sequence 1 is dominated by conglomerates and marls. In Sequence 2 and Sequence 3, carbonate deposits dominate in the inner ramp whereas siliciclastics preferentially occur in the middle and outer ramp. Bryomol carbonate sediments occur in all sequences whereas rhodalgal carbonates are restricted to Sequence 3. In bays protected from siliciclastic influx, rhodalgal deposits formed under transgressive conditions. A bryomol factory occurs in zones of continuous siliciclastic supply. This distribution results from facies partitioning during the flooding of the Ronda Basin, which has a rugged and irregular relief. Embayments were protected from siliciclastic influx and provided regions with less hydraulic energy.  相似文献   

Occurrence of naphthalenesulfonates and their condensates with formaldehyde in a landfill leachate and their transport behavior in groundwater of the Upper Rhine Valley, Germany     

C. Menzel  F. Lange  W. Käss  H. Hötzl 《Environmental Geology》2002,41(6):731-741

. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l^–1, which decreased to 9.5 µg l^–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.  相似文献   

The Svecofennian gabbro-hosted Koivusaarenneva magmatic ilmenite deposit,Kälviä, Finland     

Niilo K. Kärkkäinen  Theodore J. Bornhorst 《Mineralium Deposita》2003,38(2):169-184

  相似文献