Oil-oil and oil-source rock correlations in the Alpine Foreland Basin of Austria: Insights from biomarker and stable carbon isotope studies     

Reinhard Gratzer  Achim BechtelReinhard F. Sachsenhofer  Hans-Gert LinzerDoris Reischenbacher  Hans-Martin Schulz 《Marine and Petroleum Geology》2011,28(6):1171-1186

The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schöneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of different fields are only in the western part consistent with northward displacement of immature oils by subsequently generated oils. In the eastern part of the basin different migration pathways must be assumed. The trend in S/(S + R) isomerisation of ααα-C₂₉ steranes versus the αββ (20R)/ααα (20R) C₂₉ steranes ratio from oil samples can be explained by differences in thermal maturation without involving long-distance migration. The results argue for hydrocarbon migration through highly permeable carrier beds or open faults rather than relatively short migration distances from the source. The lateral distance of oil fields to the position of mature source rocks beneath the Alpine nappes in the south suggests minimum migration distances between less than 20 km and more than 50 km.Biomarker compositions of the oils suggest Oligocene shaly to marly successions (i.e. Schoeneck, Dynow, and Eggerding formations) as potential source rocks, taking into account their immature character. Best matches are obtained between the oils and units a/b (marly shale) and c (black shale) of the “normal” Schöneck Formation, as well as with the so-called “Oberhofen Facies”. Results from open system pyrolysis-gas chromatography of potential source rocks indicate slightly higher sulphur content of the resulting pyrolysate from unit b. The enhanced dibenzothiophene/phenanthrene ratios of oils from the western part of the basin would be consistent with a higher contribution of unit b to hydrocarbon expulsion in this area. Differences in the relative contribution of sedimentary units to oil generation are inherited from thickness variations of respective units in the overthrusted sediments. The observed trend towards lighter δ¹³C values of hydrocarbon fractions from oil fields in a W-E direction are consistent with lower δ¹³C values of organic matter in unit c.  相似文献   

Background simulations for the Large Area Detector onboard LOFT     

Riccardo Campana  Marco Feroci  Ettore Del Monte  Teresa Mineo  Niels Lund  George W. Fraser 《Experimental Astronomy》2013,36(3):451-477

The Large Observatory For X-ray Timing (LOFT), currently in an assessment phase in the framework the ESA M3 Cosmic Vision programme, is an innovative medium-class mission specifically designed to answer fundamental questions about the behaviour of matter, in the very strong gravitational and magnetic fields around compact objects and in supranuclear density conditions. Having an effective area of ～10 m² at 8 keV, LOFT will be able to measure with high sensitivity very fast variability in the X-ray fluxes and spectra. A good knowledge of the in-orbit background environment is essential to assess the scientific performance of the mission and optimize the design of its main instrument, the Large Area Detector (LAD). In this paper the results of an extensive Geant-4 simulation of the instrumentwillbe discussed, showing the main contributions to the background and the design solutions for its reduction and control. Our results show that the current LOFT/LAD design is expected to meet its scientific requirement of a background rate equivalent to 10 mCrab in 2?30 keV, achieving about 5 mCrab in the most important 2–10 keV energy band. Moreover, simulations show an anticipated modulation of the background rate as small as 10 % over the orbital timescale. The intrinsic photonic origin of the largest background component also allows for an efficient modelling, supported by an in-flight active monitoring, allowing to predict systematic residuals significantly better than the requirement of 1 %, and actually meeting the 0.25 % science goal.  相似文献   

An empirical regression model of soluble phosphorus retention for small pristine streams evaluating tracer experiments     

Marcus Schulz  Maik Bischoff  Jörg Klasmeier  Jürgen Berlekamp  Michael Matthies 《Aquatic Sciences - Research Across Boundaries》2008,70(2):115-122

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Sources and pathways of natural and anthropogenic hydrocarbons into the natural dump Arkona Basin (southern Baltic Sea)     

H.-M. Schulz  K.-C. Emeis 《Environmental Geology》2000,39(8):839-848

 Surface sediments, suspended particulate matter and fluffy-layer material, collected in the Arkona Basin and the Pomeranian Bay during 1995–1997, as well as air particulate matter, collected on the island of Rügen during August 1995, were analysed for total organic carbon content, saturated and polycyclic aromatic hydrocarbons (PAH). The resulting concentrations and distributions of these compounds and molecular PAH ratios are discussed in terms of matrix, origin of the organic matter and seasonal variations. The data show that the Oder river can be identified as a major source for PAH transported into the southern part of the Arkona Basin. A strong atmospheric input of PAH is noted for the central and northern part of the basin. In general, anthropogenic and bacterially degraded hydrocarbons bound to organic carbon-rich and small particles are mainly deposited in the basin center, whereas their natural counterparts accumulate mainly on the basin flanks covered by coarser grained sediments. Received: 2 March 1999 · Accepted: 8 June 1999  相似文献   

A spectrum of the veiled T Tauri star CY Tau     

J. A. Stüwe  R. Schulz 《Astronomische Nachrichten》1994,315(6):427-430

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Das erdmagnetische Feld im Jahr 1995 nach Messungen des Erdmagnetischen Observatoriums Wingst     

Günter Schulz 《Ocean Dynamics》1995,47(4):339-342

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The Greenland ice sheet through the last glacial-interglacial cycle   总被引：1，自引：0，他引：1  

Anne Letrguilly  Niels Reeh  Philippe Huybrechts 《Global and Planetary Change》1991,4(4)

The evolution of the Greenland ice sheet during the last 150,000 years, in response to a climate history derived from a Greenland ice-margin oxygen-18 record, is simulated by means of a three-dimensional, time-dependent ice-sheet model. The calculations indicate that the ice sheet displayed considerable thinning and ice-margin retreat during the last interglacial (the Eemian) and during a warm interstadial c. 100,000 yr B.P., resulting in a splitting up of the ice sheet into a central-northern and a southern part. However, the ice sheet in Central Greenland survived the warm stages with almost unchanged surface elevations as compared with the present.  相似文献   

Wide field monitoring of the X-ray sky using Rotation Modulation Collimators     

Niels Lund  Søren Brandt 《Experimental Astronomy》1995,6(4):19-24

Wide field monitoring is of particular interest in X-ray astronomy due to the strong time-variability of most X-ray sources. Not only does the time-profiles of the persistent sources contain characteristic signatures of the underlying physical systems, but, additionally, some of the most intriguing sources have long periods of quiesense in which they are almost undetectable as X-ray sources, interspersed with relatively brief periods of intense outbursts, where we have unique opportunities of studying dynamical effects, in, for instance, the evolution of accretion discs. Another question for which wide field monitors may provide key information, is the origin and nature of the cosmic gamma ray bursts.Rotation Modulation Collimators (RMC's) were originally introduced in X-ray astronomy to provide accurate source localizations over extended fields. This role has since been taken over by the grazing incidence telescope systems. The potential of the RMC's as wide field monitors have recently been demonstrated by the WATCH instruments on GRANAT and EURECA. It now appears likely, that for use on large, 3-axis stabilized spacecraft, a pinhole camera system may provide better sensitivity than an RMC-system of corresponding physical dimensions. But due to its simplicity, low data rate, and ability to work on spin stabilized (micro)satellites, the RMC wide field monitor may still have a role to play in the X-ray astronomy of the future.  相似文献   

Heat flow and lithospheric thermal regime in the Northeast German Basin   总被引：3，自引：0，他引：3  

Ben Norden  Andrea Frster  Niels Balling 《Tectonophysics》2008,460(1-4):215-229

New values of surface heat flow are reported for 13 deep borehole locations in the Northeast German Basin (NEGB) ranging from 68 to 91 mW m^− 2 with a mean of 77 ± 3 mW m^− 2. The values are derived from continuous temperature logs, measured thermal conductivity, and log-derived radiogenic heat production. The heat-flow values are supposed free of effects from surface palaeoclimatic temperature variations, from regional as well as local fluid flow and from thermal refraction in the vicinity of salt structures and thus represent unperturbed crustal heat flow. Two-D numerical lithospheric thermal models are developed for a 500 km section along the DEKORP-BASIN 9601 deep seismic line across the basin with a north-eastward extension across the Tornquist Zone. A detailed conceptual model of crustal structure and composition, thermal conductivity, and heat production distribution is developed. Different boundary conditions for the thickness of thermal lithosphere were used to fit surface heat flow. The best fit is achieved with a thickness of thermal lithosphere of about 75 km beneath the NEGB. This estimate is corroborated by seismological studies and somewhat less than typical for stabilized Phanerozoic lithosphere. Modelled Moho temperatures in the basin are about 800 °C; heat flow from the mantle is about 35 to 40 mW m^− 2. In the southernmost part of the section, beneath the Harz Mountains, higher Moho temperatures up to 900 to 1000 °C are shown. While the relatively high level of surface heat flow in the NEGB obviously is of longer wave length and related to lithosphere thickness, changes in crustal structure and composition are responsible for short-wave-length anomalies.  相似文献   

Variability in inorganic and organic nitrogen uptake associated with riverine nutrient input in the Gulf of Riga, Baltic Sea     

Gry Mine Berg  Patricia M. Glibert  Niels O. G. Jørgensen  Maija Balode  Ingrida Purina 《Estuaries and Coasts》2001,24(2):204-214

Concentrations and rates of uptake of dissolved organic nitrogen (DON, free amino acids, and urea) and inorganic nitrogen (DIN, nitrate, and ammonium) were measured along two transects in the Gulf of Riga, a sub-basin of the Baltic Sea, during May and July 1996. Concentrations of total dissolved nitrogen (TDN) were 23±3 μg-at N 1⁻¹ in the northern region (mouth) and 41±5 μg-at N 1⁻¹ in the southern region (head) of the Gulf. Rates of nitrogen uptake, determined with¹⁵N-labeled substrates, reflected differences in TDN concentration between the regions. In May, uptake of DIN+DON measured 0.17 and 0.43 μg-at N 1⁻¹ h⁻¹ in the northern and southern parts of the Gulf, respectively. In July, DIN+DON uptake measured 0.38 and 0.68 μg-at N 1⁻¹ h⁻¹ in the north and south, respectively. Most of the variability in total nitrogen flux between the northern and southern regions was due to heterogeneity of DON utilization. Uptake of urea and dissolved free amino acid were up to 6 and 3 times greater in the south compared to the north. As evidenced by size-fractionation, plankton size structure appeared to play a role in the uptake of DON. The community in the southern part was largely composed of cells <5 μm, while up to 67% of the community in the northern part was composed of cells >5 μm. Our results indicate that DON was a major source of nitrogen to phytoplankton, particularly in the southern part of the Gulf.  相似文献