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31.
Refractory Ti-bearing minerals in the calcium-, aluminum-rich inclusion (CAI) Inti, recovered from the comet 81P/Wild 2 sample, were examined using analytical (scanning) transmission electron microscopy (STEM) methods including imaging, nanodiffraction, energy-dispersive spectroscopy (EDX) and electron energy loss spectroscopy (EELS). Inti fassaite (Ca(Mg,Ti,Al)(Si,Al)2O6) was found to have a Ti3+/Ti4+ ratio of 2.0 ± 0.2, consistent with fassaite in other solar system CAIs. The oxygen fugacity (logfO2) of formation estimated from this ratio, assuming equilibration among phases at 1509 K, is −19.4 ± 1.3. This value is near the canonical solar nebula value (−18.1 ± 0.3) and in close agreement with that reported for fassaite-bearing Allende CAIs (−19.8 ± 0.9) by other researchers using the same assumptions. Nanocrystals of osbornite (Ti(V)N), 2–40 nm in diameter, are embedded as inclusions within gehlenite, spinel and diopside in Inti. Vanadium is heterogeneously distributed within some osbornite crystals. Compositions range from pure TiN to Ti0.36V0.64N. The possible presence of oxide and carbide in solid solution with the osbornite was evaluated. The osbornite may contain O, but C is not present at detectable levels. The presence of osbornite, likely a refractory early condensate, together with the other refractory minerals in Inti, indicates that the parent comet contains solids that condensed closer to the proto-sun than the distance at which the parent comet itself accreted. The estimated oxygen fugacity and the reported isotopic and chemical compositions are consistent with Inti originating in the inner solar system like other meteoritic CAIs. These results provide insight for evaluating the validity of models of radial mass transport dynamics in the early solar system. The oxidation environments inferred for the Inti mineral assemblage are inconsistent with an X-wind formation scenario. In contrast, radial mixing models that allow accretion of components from different heliocentric distances can satisfy the observations from the cometary CAI Inti.  相似文献   
32.
The 30 to 155 m thick Early Permian (Artinskian) Warchha Sandstone of the Salt Range, Pakistan is a conglomerate, sandstone and claystone succession within which seven lithofacies types (Gt, St, Sp, Sr, Sh, Fl and Fm) occur in a predictable order as repeated fining-upward cycles. Common sedimentary structures in the conglomerates and sandstones include planar and trough cross-bedding, planar lamination, soft sediment-deformed bedding, compound cosets of strata with low-angle inclined bounding surfaces and lags of imbricated pebbles. Structures in the finer-grained facies include desiccation cracks, raindrop imprints, caliche nodules and bioturbation. Groups of associated facies are arranged into nine distinct architectural elements (channels, gravel bars, sandy bedforms, downstream and laterally accreting barforms, sand sheets, crevasse splays, levees, floodplain units and shallow lakes), which is consistent with a fluvial origin for the succession. The types of architectural elements present and their relationship to each other demonstrate that the Warchha Sandstone preserves a record of a meandering river system that drained the northern margin of Gondwanaland. The dominance of fine-grained (floodplain) facies over gravel-grade (channel-base) facies and the widespread occurrence of large-scale lateral accretion elements supports the interpretation of a high-sinuosity, meandering fluvial system in which channel bodies accumulated via the lateral accretion of point bars but in which the active channels covered only a small part of a broad floodplain at any time instant. Although the regional and temporal distribution of these deposits is complex, in broad terms the lower part is dominated by stacked, multistorey channel bodies, whereas single-storey channel elements isolated in abundant fine-grained floodplain deposits dominate the middle and upper parts of the formation.  相似文献   
33.
The 2015 Paris Agreement commits countries to pursue efforts to limit the increase in global mean temperature to 1.5 °C above pre-industrial levels. We assess the consequences of achieving this target in 2100 for the impacts that are avoided, using several indicators of impact (exposure to drought, river flooding, heat waves and demands for heating and cooling energy). The proportion of impacts that are avoided is not simply equal to the proportional reduction in temperature. At the global scale, the median proportion of projected impacts avoided by the 1.5 °C target relative to a rise of 4 °C ranges between 62 and 95% across sectors: the greatest reduction is for heat wave impacts. The 1.5 °C target results in impacts that would be between 27 and 62% lower than with the 2 °C target. For each indicator, there are differences in the proportions of impacts avoided between regions depending on exposure and the regional changes in climate (particularly precipitation). Uncertainty in the proportion of impacts that are avoided for a specific sector depends on the range in the shape of the relationship between global temperature change and impact, and this varies between sectors.  相似文献   
34.
35.
Australian meteorological observers started using the World Meteorological Organization (WMO) weather coding system in the 1950s. This system is still in use around the world today. However, observing and recording the weather in an organized and systematic manner had been ongoing for over 100 years prior to the adoption of this coding system, and much like Australia, most countries will have historical meteorological records. In this paper we compare the wind erosion of two of the greatest droughts in Australian recorded history; the World War II (WWII) Drought (1937–1945) and the Millennium Drought (2001–2009). To do this we analysed previously unavailable meteorological observer records from the Australian Bureau of Meteorology (ABM). Wind erosion records, mostly in long‐hand written form, were translated to the modern WMO coding system for the WWII Drought and compared with the wind erosion of Australia's recently‐ended Millennium Drought, one of the longest and harshest on record. We quantify wind erosion using Dust Event Days (DED) and a modified version of a published Dust Storm Index (DSI) to show that wind erosion during the WWII Drought was up to 4.6 times higher than during the Millennium Drought. This study has international significance because it demonstrates a methodology for tracking changes in wind erosion over the past 75 years based on observer records available in every country with a history of organized weather observation. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
36.
Both the rate and the vertical distribution of soil disturbance modify soil properties such as porosity, particle size, chemical composition and age structure; all of which play an important role in a soil's biogeochemical functioning. Whereas rates of mixing have been previously quantified, the nature of bioturbation's depth dependence remains poorly constrained. Here we constrain, for the first time, the relationship between mixing rate and depth in a bioturbated soil in northeast Queensland, Australia using a novel method combining OSL (optically‐stimulated luminescence) ages and meteoric beryllium‐10 (10Be) inventories. We find that the best fit mixing rate decreases non‐linearly with increasing soil depth in this soil and the characteristic length scale of 0.28 m over which the mixing coefficient decays is comparable to reported rooting depth coefficients. In addition we show that estimates of surface mixing rates from OSL data are highly dependent on erosion rate and that erosion rate must be constrained if accurate mixing rates are to be quantified. We calculate surface diffusion‐like mixing coefficients of 1.8 × 10?4 and 2.1 × 10?4 m2 yr?1 for the studied soil for two different estimates of soil erosion. © 2014 The Authors. Earth Surface Processes and Landforms Published by John Wiley & Sons Ltd.  相似文献   
37.
A validation experiment, carried out in a scaled field setting, was attempted for the long electrode electrical resistivity tomography method in order to demonstrate the performance of the technique in imaging a simple buried target. The experiment was an approximately 1/17 scale mock‐up of a region encompassing a buried nuclear waste tank on the Hanford site. The target of focus was constructed by manually forming a simulated plume within the vadose zone using a tank waste simulant. The long electrode results were compared to results from conventional point electrodes on the surface and buried within the survey domain. Using a pole‐pole array, both point and long electrode imaging techniques identified the lateral extents of the pre‐formed plume with reasonable fidelity but the long electrode method was handicapped in reconstructing vertical boundaries. The pole‐dipole and dipole‐dipole arrays were also tested with the long electrode method and were shown to have the least favourable target properties, including the position of the reconstructed plume relative to the known plume and the intensity of false positive targets. The poor performance of the pole‐dipole and dipole‐dipole arrays was attributed to an inexhaustive and non‐optimal coverage of data at key electrodes, as well as an increased noise for electrode combinations with high geometric factors. However, when comparing the model resolution matrix among the different acquisition strategies, the pole‐dipole and dipole‐dipole arrays using long electrodes were shown to have significantly higher average and maximum values within the matrix than any pole‐pole array. The model resolution describes how well the inversion model resolves the subsurface. Given the model resolution performance of the pole‐dipole and dipole‐dipole arrays, it may be worth investing in tools to understand the optimum subset of randomly distributed electrode pairs to produce maximum performance from the inversion model.  相似文献   
38.
Gas hydrates are a potential energy resource, a possible factor in climate change and an exploration geohazard. The University of Toronto has deployed a permanent seafloor time‐domain controlled source electromagnetic (CSEM) system offshore Vancouver Island, within the framework of the NEPTUNE Canada underwater cabled observatory. Hydrates are known to be present in the area and due to their electrically resistive nature can be monitored by 5 permanent electric field receivers. However, two cased boreholes may be drilled near the CSEM site in the near future. To understand any potential distortions of the electric fields due to the metal, we model the marine electromagnetic response of a conductive steel borehole casing. First, we consider the commonly used canonical model consisting of a 100 Ωm, 100 m thick resistive hydrocarbon layer embedded at a depth of 1000 m in a 1 Ωm conductive host medium, with the addition of a typical steel production casing extending from the seafloor to the resistive zone. Results show that in both the frequency and time domains the distortion produced by the casing occurs at smaller transmitter‐receiver offsets than the offsets required to detect the resistive layer. Second, we consider the experimentally determined model of the offshore Vancouver Island hydrate zone, consisting of a 5.5 Ωm, 36 m thick hydrate layer overlying a 0.7 Ωm sedimentary half‐space, with the addition of two borehole casings extending 300 m into the seafloor. In this case, results show that the distortion produced by casings located within a 100 m safety zone of the CSEM system will be measured at 4 of the 5 receivers. We conclude that the boreholes must be positioned at least 200 m away from the CSEM array so as to minimize the effects of the casings.  相似文献   
39.
We examine macrofaunal and physico-chemical responses to organic enrichment beneath salmon farms in contrasting flow environments, and reveal pronounced flow-related differences in the magnitude and spatial extent of effects. Total macrofaunal abundances at high flow sites were nearly an order of magnitude greater than at comparable low flow sites, representing a significant benthic biomass. These very high abundances occurred in conjunction with moderate-to-high species richness, and were evident in the absence of appreciable organic matter accumulation. Biological responses to increasing sulfide were variable; however a significant biological threshold was evident at 1500 μM. Macrofaunal responses at high flow sites differed substantially from the Pearson–Rosenberg model. The atypical ecological conditions were attributed to (i) limited accumulation of fine sediments, (ii) maintenance of aerobic conditions in near-surface sediments, and (iii) an abundant food supply. Thus, enhanced resilience to organic waste at well-flushed sites appears related to both biological and physical processes.  相似文献   
40.
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