Micro- and nano-textural evidence of Ti(–Ca–Fe) mobility during fluid–rock interactions in carbonaceous lawsonite-bearing rocks from New Zealand     

Matthieu?E.?GalvezEmail author  Olivier?Beyssac  Karim?Benzerara  Nicolas?Menguy  Sylvain?Bernard  Simon?C.?Cox 《Contributions to Mineralogy and Petrology》2012,164(5):895-914

Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions.  相似文献   

Granite magma migration and emplacement along thrusts   总被引：1，自引：0，他引：1  

Eric C. Ferré  Olivier Galland  Domenico Montanari  Thomas J. Kalakay 《International Journal of Earth Sciences》2012,101(7):1673-1688

This paper investigates the influence exerted by brittle tectonic structures in the emplacement of granite plutons in contractional settings. We address both cases where contractional tectonics and magma intrusion are (1) coeval, to study how active contractional tectonics controls the transport of magma, and (2) diachronous, to study the role of pre-existing structures on the transport of magma. In light of new experimental models, we show that magma can rise along thrusts ramps and flats. This phenomenon occurs for both low-viscosity magma (basalts to andesite) and high-viscosity magma (dry granite). The experimental results also allow the evaluation of the role played by magma viscosity in determining pluton geometries. In addition, a review of literature demonstrates a spatial and causal relationship between granites and thrusts and highlights the geometric control of magma pathways in the pluton final shape. The abundance of subhorizontal and tabular granitic intrusions indicates that the location of inflating granitic sills along thrust flats can be common. We argue that active and pre-existing flats-and-ramps thrusts provide a preferential continuous planar anisotropy susceptible to become a granitic magma migration pathway.  相似文献   

Experimental Investigation of Turbulent Momentum Transfer in a Neutral Boundary Layer over a Rough Surface     

Severine Tomas  Olivier Eiff  Valery Masson 《Boundary-Layer Meteorology》2011,138(3):385-411

The turbulent characteristics of the neutral boundary layer developing over rough surfaces are not well predicted with operational weather-forecasting models. The problem is attributed to inadequate mixing-length models, to the anisotropy of the flow and to a lack of controlled experimental data against which to validate numerical studies. Therefore, in order to address directly the modelling difficulties for the development of a neutral boundary layer over rough surfaces, and to investigate the turbulent momentum transfer of such a layer, a set of hydraulic flume experiments were carried out. In the experiments, the mean and turbulent quantities were measured by a particle image velocimetry (PIV) technique. The measured velocity variances and fluxes \({(\overline{{u_{i}^{\prime}}{u_{j}^{\prime}}})}\) in longitudinal vertical planes allowed the vertical and longitudinal gradients (?/?z and ?/?x) of the mean and turbulent quantities (fluxes, variances and third-order moments) to be evaluated and the terms of the evolution equations for ?e/?t, \({\partial \overline{u^{\prime 2}}/\partial t}\), \({\partial \overline{w^{\prime 2}}/\partial t}\) and \({\partial \overline{{u^{\prime}}{w^{\prime}}}/\partial t}\) to be quantified, where e is the turbulent kinetic energy. The results show that the pressure-correlation terms allow the turbulent energy to be transferred equitably from \({\overline{{u^{\prime}}^{2}}}\) to \({\overline{{w^{\prime}}^{2}}}\). It appears that the repartition between the constitutive terms of the budget of e, \({\overline{{u^{\prime}}^{2}}}\), \({\overline{{w^{\prime}}^{2}}}\) and \({\overline{{u^{\prime}}{w^{\prime}}}}\) is not significantly affected by the development of the rough neutral boundary layer. For the whole evolution, the transfers of energy are governed by the same terms that are also very similar to the smooth-wall case. The PIV measurements also allowed the spatial integral scales to be computed directly and to be compared with the dissipative and mixing length scales, which were also computed from the data.  相似文献   

Sumixam maximus gen. and sp. nov., a New Pennsylvanian Species of Archaeorthoptera (Neoptera; Indiana, USA)     

Olivier BéTHOUX  Christin GROSSMANN 《《地质学报》英文版》2011,85(3):515-520

A new Mazon-Creek-type fossil specimen is described as Sumixam maximus gen. and sp. nov., assigned to the taxon Archaeorthoptera Béthoux and Nel, 2002 (composed of Orthoptera and some fossil relatives): it exhibits one of the diagnostic character states of this taxon, which is the fusion of CuA (emerging from M + CuA) with CuP, or a branch of it. A more precise taxonomic assignment is out of reach. The new taxon exhibits a fusion of the anterior branch of MA with RP, and a point of divergence of MA and MP located near the point of divergence of CuA (from M + CuA), but lack a branching of CuPa. This unique combination of character states is probably derived with respect to a number of contemporaneous species. Sumixam maximus gen. and sp. nov. is most likely the closest known relative of the panorthopterans, which include all the recent Archaeorthoptera.  相似文献   

Microstructure and hydraulic conductivity of a compacted lime-treated soil   总被引：1，自引：0，他引：1  

Olivier Cuisinier  Jean-Claude Auriol  Tangi Le Borgne  Dimitri Deneele 《Engineering Geology》2011,(3):187

Under a given compaction energy and procedure, it is known that maximum dry density of a soil is lowered due to lime addition. This modification of maximum dry density could alter the hydraulic conductivity of the soil. The main object of this study was to assess the impact of lime-stabilization on a silt soil microstructure and then on saturated hydraulic conductivity. An investigation at the microscopic level with mercury intrusion porosimetry showed that lime treatment induced the formation of a new small class, with a diameter lower than 3 × 10³ Å in the compacted soil. This class is responsible for the difference in dry density between the treated and the untreated sample after compaction. It is shown that this small pores class was not altered by the compaction water content, the compaction procedure or the dry density. As in untreated soils, only the larger pores were modified by the compaction water content and the compaction procedure in the lime treated samples. The hydraulic conductivity appeared to be only related to the largest pores volume of the tested silt, regardless of lime treatment. Therefore, this study demonstrated that even if addition of lime resulted in a dramatic change of the maximum dry density of the tested silty soil, its effect on hydraulic conductivity is limited.  相似文献   

Biradical character of D-rich carriers in the insoluble organic matter of carbonaceous chondrites: A relic of the protoplanetary disk chemistry     

Olivier Delpoux  Hervé Vezin  Sylvie Derenne 《Geochimica et cosmochimica acta》2011,75(1):326-7965

The insoluble organic matter (IOM) of the Orgueil meteorite contains deuterium-rich radicals detectable by Electron Paramagnetic Resonance (EPR) techniques (Gourier et al., 2008). However the structure of these deuterium carriers remains poorly constrained. In this work, their electronic structure is deduced from the measurement of the spin states S by transient nutation in pulsed-EPR. It is shown that these deuterium-rich radicals are dominated by biradicaloids (species with S = 0 ground state and thermally accessible S = 1 state) and biradicals (species with S = 1 ground state) representing ∼61% and ∼31% of the radicals in the IOM of Orgueil, respectively, while single radicals (S = 1/2) contribute only to ∼8%. This is definitely different from mature terrestrial IOMs, which are known to contain almost exclusively S = 1/2 radicals. A structural model is proposed, whereby the occurrence of dominant biradicaloids and biradicals is the direct consequence of the structure of the IOM, made of a network of small aromatic moieties linked by branched and short aliphatic units. This implies that the formation of stable biradicaloids and biradicals by C-H breaking and their deuterium enrichment are produced after the formation of the IOM in the primitive solar system. These results reinforce the idea that the formation of the IOM and the deuterium-rich hotspots are the product of ion chemistry in the solar disk.  相似文献   

Geological time formalization: an improved formal model for describing time successions and their correlation   总被引：1，自引：1，他引：0  

Michel Perrin  Laura S. Mastella  Olivier Morel  Alexandre Lorenzatti 《Earth Science Informatics》2011,4(2):81-96

  相似文献   

Overview of the subsurface structural pattern of the Paris Basin (France): Insights from the reprocessing and interpretation of regional seismic lines     

Laurent Beccaletto  Olivier Serrano Stéphane Marc 《Marine and Petroleum Geology》2011,28(4):861-879

The study presents the methodology used by the French Geological Survey (BRGM) for the building, reprocessing and interpretation of selected regional seismic lines in the Paris intracratonic basin (France): the 14 constructed E-W and N-S regional transects represent a total of 2,516 km length, and are based on the merge of 240 seismic single profiles recorded by petroleum operators between 1971 and 1995. The regional lines have been selected to cross the main oil fields of the Paris Basin, as well as high potential areas for oil exploration. A first difficulty was to recover the raw data necessary to build-up the regional transects. The signal reprocessing, harmonization and merge of the single seismic lines, constituent of the regional transects, are then described; these operations represent the cornerstone of the study. We put the emphasis on the primary static corrections, as the targeted structures are commonly spatially associated with large seismic velocity variations in the upper Cretaceous chalk and Tertiary sedimentary cover.The interpreted regional transects definitely give complementary information to the existing studies, which generally lack seismic (and therefore structural) data: we give an overview of the main structural and geometrical features of the Paris Basin: inversion structures, major unconformities, as well as Permo-Carboniferous basins. We also describe the structural pattern, and show the close relationships between the faults geometry, the faults density, and the geological evolution of the Paris Basin: we distinguish (1) few large-scale polyphase faults, with a Variscan origin, representing the first order structural frame of the Paris Basin; (2) monophase normal faults, with strike-slip features, representing the subsurface prolongation of Cenozoic grabens cropping out in the neighbourhood; (3) deep normal faults, sealed by the base Calcareous Dogger sequence, related to the Permo-Liassic extensional tectonic regime. This large-scale view of the Paris Basin has highlighted several potential exploration targets.  相似文献   

Formation of U-depleted rhyolite from a basanite at El Hierro, Canary Islands   总被引：2，自引：0，他引：2  

Olgeir Sigmarsson  Didier Laporte  Marion Carpentier  Bertrand Devouard  Jean-Luc Devidal  Joan Marti 《Contributions to Mineralogy and Petrology》2013,165(3):601-622

Phonolite and trachyte are the felsic magmas of the alkaline magma suites, which characterize the Canary Islands. The October 2011 submarine eruption off El Hierro, the westernmost island, nevertheless, produced a small volume of rhyolitic magma. The rhyolite occurred as highly vesicular, white coloured pumices enveloped in and mingled with darker coloured basanitic pumice. The basanitic pumice is relatively crystal poor with a few euhedral olivines (mostly Fo_77–79), clinopyroxenes and Fe-rich spinels, whereas very rare olivine of same composition is found together with equally rare Fe-sulphide and FeTi-rich oxides in the rhyolite. The Fe–Mg exchange equilibrium in the oxides permits to calculate an equilibrium temperature of 970–890 °C for the rhyolite, in agreement with quartz-melt equilibrium at ca. 930 °C. A striking mineralogical feature of the rhyolite is the presence of rounded to contorted grains of milky quartz, which are xenocrysts incorporated and partly dissolved into the magma. Analyses of residual volatile concentrations in the glasses show that the rhyolite melt was highly degassed, whereas the basanitic glass still has important halogen concentrations. Trace element patterns of the mafic glasses and their elevated incompatible element concentrations are typical of the western Canary Island basanites. In contrast, the trace element composition of the rhyolite shows surprisingly low concentrations for all elements except the most incompatible ones (e.g. Rb, Ba, K and Th). All other measured LILE, HFSE and REE have significantly lower concentration than the basanitic counterpart that can be explained by fractionation of accessory phases (1 % apatite, 1 % sphene and 0.1 % zircon). Surprisingly, low U concentration is presumably related to elevated oxygen fugacity in the rhyolite, causing U to be in a hexavalent state, and fluxing of F-rich gas leading to volatilization of UF₆, known to emanate at low temperature. The results suggest that a gas-rich basanitic melt remobilized a small volume of stagnant rhyolitic melt formed by incorporation of approximately 10 % quartz-rich sediment into a late differentiate of trachytic composition. Sediments at the interface of an old oceanic crust adjacent to a continental shield and younger volcanic island are likely to act as magma traps were sediment assimilation may alter the mantle-derived magma composition. Quartz assimilation thus explains the production of rhyolite magma in a volcanic island characterized by an alkaline magma series from primitive basanites to trachytes.  相似文献