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21.
22.
Contamination with heavy metals in surface and groundwater is a threat to human health and ecosystems. Due to this, the need arises to remediate water polluted through ecological and profitable technologies, such as phytoremediation. The objective of the work was to evaluate the concentration of lead (Pb) and zinc (Zn) in the floating macrophytes Limnobium laevigatum and Ludwigia peploides, after being exposed to contaminated water experimentally. In this way to be able to determine if these plants have mechanisms that allow them to accumulate the metals in the roots and to perform the translocation of these to different vegetative organs, L. laevigatum and L. peploides were placed in solutions contaminated with Pb ([Pb]?=?5 mg/l) and Zn ([Zn]?=?20 mg/l). The concentrations of metals in water, root and leaf samples were evaluated as a function of time (0, 1, 2 and 4 days). The determination of the metals was performed by the atomic absorption spectrophotometry technique. After 4 days of exposure to Pb and Zn, the plants showed high metal removal efficiencies of water, more to 70% in all cases. Pb was accumulated fundamentally by roots, while Zn was accumulated more in the leaves. In addition, the bioconcentration and translocation factors for each metal were calculated.  相似文献   
23.
The Arctic is more vulnerable to climate change than are mid latitudes. Therefore, palaeolimnological studies from the High Arctic are important in providing insights into the dynamics of the climate system. Here we present a multi‐proxy study from one of the world's northernmost lakes: Bliss Lake, Peary Land, Greenland. The early Holocene (10 850–10 480 cal. a BP) is characterized by increased erosion and gradually more marine conditions. Full marine conditions developed from 10 480 cal. a BP until the lake was isolated at 7220 cal. a BP. From its marine isolation at 7220 cal. a BP Bliss Lake becomes a lacustrine environment. Evidence from geochemical proxies (δ13C and total organic carbon) suggests that warmer conditions prevailed between 7220 and 6500 cal. a BP, corresponding to the Holocene thermal maximum, and from 3300 until 910 cal. a BP. From 850 to 500 cal. a BP colder climate conditions persisted. The transition from warmer to colder climate conditions taking place around 850 cal. a BP may be associated with the transition from the Medieval Warm Period to the Little Ice Age. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
24.
Despite a clear need, little research has been carried out at the regional-level to quantify potential climate-related impacts to electricity production and delivery systems. This paper introduces a bottom-up study of climate change impacts on California's energy infrastructure, including high temperature effects on power plant capacity, transmission lines, substation capacity, and peak electricity demand. End-of-century impacts were projected using the A2 and B1 Intergovernmental Panel on Climate Change emission scenarios. The study quantifies the effect of high ambient temperatures on electricity generation, the capacity of substations and transmission lines, and the demand for peak power for a set of climate scenarios. Based on these scenarios, atmospheric warming and associated peak demand increases would necessitate up to 38% of additional peak generation capacity and up to 31% additional transmission capacity, assuming current infrastructure. These findings, although based on a limited number of scenarios, suggest that additional funding could be put to good use by supporting R&D into next generation cooling equipment technologies, diversifying the power generation mix without compromising the system's operational flexibility, and designing effective demand side management programs.  相似文献   
25.
High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na+, SO 4 2– , NO 3 , methanesulfonate (MSA), NH 4 + ,210Pb, and7Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na+, 68–151 ng m–3; NO 3 , 25–30 ng m–3; nss SO 4 2– , 81–97 ng m–3; MSA, 19–28 ng m–3; NH 4 + , 16–21 ng m–3;210Pb, 0.75–0.86 fCi m–3. Results from multiple variable regression of non-sea-salt (nss) SO 4 2– with MSA and NO 3 as the independent variables indicates that, at Mawson, the nss SO 4 2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO 4 2– during transport over Antarctica from the oceanic source region. The mean210Pb concentrations at Palmer and Marsh and the mean NO 3 concentration at Palmer are about a factor of two lower than those at Mawson. The210Pb distributions are consistent with a210Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO 3 and210Pb at Mawson support the conclusion that the primary source regions for NO 3 are continental. In contrast, the mean concentrations of MSA, nss SO 4 2– , and NH 4 + at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO 4 2– by 10%; and NH 4 + by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH 4 + /(nss SO 4 2– +MSA) equivalent ratios indicate that NH3 neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.  相似文献   
26.
Scheelite- and molybdenite-bearing scapolite skarn and plagioclase skarn occur as stratabound mineralizations in a terrain which has suffered regional metamorphism. Scapolite skarn formed as replacement skarns in plagioclase-bearing hornblendic gneiss whereas plagioclase skarn precipitated in fractures as vein skarn mineralizations. The genesis of these skarn deposits are closely connected to an episode of boudinage on the limbs of a large-scale dome-shaped fold. Fluid inclusion studies revealed that the ore-forming fluids were composed of CO2 with 2 to 17 mole% CH4, which formed due to decarbonation reactions during peak metamorphism at the end of the Caledonian orogenesis. Thermodynamic considerations indicate that scapolite and plagioclase formed above 550 °C and 2 Kbar pressure and were followed by precipitation of scheelite between 400 and 570 °C.  相似文献   
27.
Abstract Slab detachment is a geophysical instability whose manifestation can be revealed by seismic tomography. Evidence of this phenomenon is in the Dinarides/Hellenic and the New Hebrides subduction zones. Subducted slabs in these regions are torn horizontally at depths ranging from 100 to 300 km. We constructed a viscoelastic three-dimensional finite element model and investigated the state of stress. We found that an area with high stress concentration of the order of several hundred MPa is formed near the tip of the tear inside the slab, which can cause lateral migration of the tear. Favorable conditions for slab detachment are characterized by large interplate frictional force at a subduction zone and small slab resistance force deeper down. Stress concentration increases with the down-dip tension inside the slab. The phenomenon of slab weakening has also been studied from a thermal-mechanical standpoint, using a two-dimensional convection model with non-Newtonian, temperature-dependent rheology. The stress-dependent rheology plays an important role in causing local weakening of the descending slab. In strongly time-dependent situations the fast descending slab is not strong everywhere but has a weak region in the middle, making it vulnerable to slab detachment. The presence of viscous heating will enhance slab detachment tendency by further weakening the interior by the frictional heating. Besides these effects, there are other mechanisms which can also weaken the slab interior and help to make slabs more pliable and susceptible to detachment.  相似文献   
28.
Alkaline rocks were intruded into the Precambrian basement in southern West Greenland during at least five separate episodes. The Tupertalik carbonatite intrusion was emplaced around or before 2650 m.y.; it is now metamorphosed in granulite facies but is recognisable by its trace element content. Lamprophyre dykes were intruded at ca. 1800 m.y. and again at ca. 1200 m.y. At ca. 600 m.y. the Sarfartôq carbonatite intrusion and extensive kimberlite dykes were emplaced in the Holsteiborg-Strømfjord region. At 225-115 m.y. the Qaqarssuk carbonatite complex was emplaced in the Sukkertoppen region, and numerous lamprophyre and kimberlite dykes were emplaced between Fishenasset and Ivigtut. All these episodes are correlatable with contemporaneous alkaline activity in Canada and Scandinavia and substantiate the periodicity of carbonatite emplacement. The Mesozoic suite of intrusions is related to rifting prior to continental break-up and the formation of the North Atlantic Ocean. The Eocambrian suite of 600 m.y. is thought to have formed under similar conditions during continental break-up and the formation of the Iapetus ocean.  相似文献   
29.
This paper presents an investigation of the decay of bricks in the chancel vault of Brarup Church located close to the Baltic Sea at the island of Falster in Denmark. The aim of the work was to study a peculiar phenomenon in order to prescribe appropriate treatment. Although protected by a lime plaster, some bricks were pulverized up to 50 mm deep from the topside. The decay occurred in a random pattern over the structure, with undamaged bricks positioned next to deteriorated bricks. The brick structure was investigated by Mercury Intrusion Porosiometry. All bricks had a majority of pores in the range 1–10 μm, but the decayed bricks also had a fraction of pores with a diameter less than 100 nm. The difference may be due to a lower firing temperature, or it may be a consequence of the salt decay. Salt analysis proved that the deteriorated bricks were contaminated with sodium chloride, which could have degraded the brick structure. However, the powdering of the bricks may be caused by the precipitation of gypsum, which was found in the brick powder but not in the deteriorated brick itself. According to calculations with the computer program RUNSALT, the precipitation of gypsum is much influenced by the presence of sodium chloride. The gypsum precipitates due to changes in temperature between 0 and 30°C and variations in relative humidity between 75 and 95%. Seasonal climatic changes in the attic were measured to cover this interval. Perhaps sodium chloride acted as a catalyst that facilitated the accumulation and precipitation of gypsum at the topside of the bricks. A sacrificial plaster, which is the traditional treatment for salt contaminated structures, would not prevent such decay.  相似文献   
30.
By combining AVHRR data from the NOAA satellites with information from a database of in situ measurements, large-scale maps can be generated of the microphysical parameters most immediately significant for the modelling of global circulation and climate. From the satellite data, the clouds can be classified into cumuliform, stratiform and cirrus classes and then into further sub-classes by cloud top temperature. At the same time a database of in situ measurements made by research aircraft is classified into the same sub-classes and a statistical analysis is used to derive relationships between the sub-classes and the cloud microphysical properties. These two analyses are then linked to give estimates of the microphysical properties of the satellite observed clouds. Examples are given of the application of this technique to derive maps of the probability of occurrence of precipitating clouds and of precipitating water content derived from a case study within the International Cirrus Experiment (ICE) held in 1989 over the North Sea.  相似文献   
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