Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry   总被引：1，自引：0，他引：1  

Shifeng Dai  Xiaoqiang Hou  Deyi Ren  Yuegang Tang   《International Journal of Coal Geology》2003,55(2-4):139-150

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.  相似文献   

土体颗粒破碎研究进展   总被引：4，自引：7，他引：4  

张家铭  汪稔  张阳明  陈复兵 《岩土力学》2003,(Z2)

在打入桩的桩端以及大型土石坝、海洋平台等的地基中常常会出现高应力区。在这些高应力区中,作为地基的粒状土的颗粒会发生不同程度的破碎。对高应力水平下粒状土体的破碎特性进行深入研究有助于解决这一类型的岩土工程问题。因此近年来土体颗粒破碎逐渐引起人们的重视。本文对土体颗粒破碎研究现状进行了详尽的阐述,并指出研究中存在的问题及今后研究发展方向。  相似文献   

Deconvolving the δO seawater component from subseasonal coral δO and Sr/Ca at Rarotonga in the southwestern subtropical Pacific for the period 1726 to 1997     

Lei Ren  Braddock K. Linsley  Daniel P. Schrag 《Geochimica et cosmochimica acta》2003,67(9):1609-1621

To reconstruct oceanographic variations in the subtropical South Pacific, 271-year long subseasonal time series of Sr/Ca and δ¹⁸O were generated from a coral growing at Rarotonga (21.5°S, 159.5°W). In this case, coral Sr/Ca appears to be an excellent proxy for sea surface temperature (SST) and coral δ¹⁸O is a function of both SST and seawater δ¹⁸O composition (δ¹⁸O_sw). Here, we focus on extracting the δ¹⁸O_sw signal from these proxy records. A method is presented assuming that coral Sr/Ca is solely a function of SST and that coral δ¹⁸O is a function of both SST and δ¹⁸O_sw. This method separates the effects of δ¹⁸O_sw from SST by breaking the instantaneous changes of coral δ¹⁸O into separate contributions by instantaneous SST and δ¹⁸O_sw changes, respectively. The results show that on average δ¹⁸O_sw at Rarotonga explains ∼39% of the variance in δ¹⁸O and that variations in SST explains the remaining ∼61% of δ¹⁸O variance. Reconstructed δ¹⁸O_sw shows systematic increases in summer months (December-February) consistent with the regional pattern of variations in precipitation and evaporation. The δ¹⁸O_sw also shows a positive linear correlation with satellite-derived estimated salinity for the period 1980 to 1997 (r = 0.72). This linear correlation between reconstructed δ¹⁸O_sw and salinity makes it possible to use the reconstructed δ¹⁸O_sw to estimate the past interannual and decadal salinity changes in this region. Comparisons of coral δ¹⁸O and δ¹⁸O_sw at Rarotonga with the Pacific decadal oscillation index suggest that the decadal and interdecadal salinity and SST variability at Rarotonga appears to be related to basin-scale decadal variability in the Pacific.  相似文献   

HUBEX强化观测期雷达测雨在水文过程模拟中的应用(英)   总被引：3，自引：0，他引：3  

REN Liliang  LI Chunhong  WANG Meirong 《大气科学进展》2003,20(2):205-211

选择全球能量与水循环亚洲季风试验区的淮河黄泥庄水文站控制的史河流域(805 km2)为研究区域,基于数字高程模型,生成栅格水流流向,构建数字流域及空间拓扑关系;然后,将阜阳雷达观测数据经过订正校准后作为研究区内每一栅格单元上的雨量输入,并在每一栅格上应用新安江模型构建产流模型;再根据每一栅格至流域出口断面-黄泥庄水文站的距离,运用Muskingum方法进行汇流演算,从而获得黄泥庄站的流量过程。计算结果显示,从1998年5月31日-8月3日的强化观测期内模型确定性系数为92.41％,其间4场洪水的确定性系数分别为85.64％、86.62％、92.57％和83.91％,高于应用地面雨量计观测的数据计算的结果。这说明雷达测雨数据具有较高的时空分辨率,当它应用于水文过程模拟时优于地面雨量计资料,基于栅格的水文模型为充分利用雷达数据提供了良好平台。  相似文献   

长白山天池火山区长白-敦化剖面结晶基底的探测和研究     

潘素珍  张先康  杨卓欣  张成科  赵金仁  潘纪顺  任青芳  张建狮 《地震研究》2003,26(3):271-274

时间项分析法中，应用广义最小二乘法进行反演，对长白山天池火山区岩浆系统的长白—敦化(L1)剖面的Pg波到时进行了计算处理，得到了Pg波时间项及基底速度值；取上部地壳的介质平均速度为4．5km/s，经反演求得了各点的深度值，给出了长白山天池火山区结晶基底的厚度分布。结晶基底厚度一般在2．0km左右，而在长白山天池下方结晶基底最厚处接近4．0km；在万宝和敦化附近各有一不太明显的凹陷，其原因可能与在这两个位置处有几条断裂穿过有关。  相似文献   

A training model for GIS application in land resource allocation     

Fuhu Ren 《ISPRS Journal of Photogrammetry and Remote Sensing》1997,52(6):261-265

  相似文献   

中强地震前山东地下流体地震前兆模糊分维特征研究   总被引：6，自引：0，他引：6  

耿杰  魏焕 《地震研究》1997,20(3):311-315

采用模糊集理论与分形理论相结合的模糊分维方法，计算山东地下流体在１９８３年菏泽５．９级地震和１９９５年苍山５．２级地震前的变化。分析结果认为，模糊分维值反映了地震前兆时序观测资料的结构变化特征，具有一定的物理意义，为从复杂的地下流体前兆观测值中提取地震异常信息提供了新的方法，但对某些台、测项而言、必须具体分析其模糊分维变化特征及其震前异常变化特征。  相似文献   

河南省短期区域性暴雨动力诊断及综合预报方案          下载免费PDF全文

李平  孙景兰  张金彬  孔海江  李保生  闫少伟 《气象》1997,23(8):25-28

介介绍了（１）用Ｔ６３数值预报产品对河南省省６－８月区域性暴雨进行物理量诊断分析。（２）用人工智能研制的河南省６－８月分片大－暴雨短短期自动化预报系统与用Ｔ６３数值预报产品资料采用逐步回归分析法和预测误差平方和最不上准则两种选取回归自变量的方法，建立处分片预报方程的综合判别预报。（３）在１９９５，１９９６年７－８月业务预报中试验结果。  相似文献   

NUMERICAL SIMULATION OF OZONE DISTRIBUTIONS AND ITS VARIATION MECHANISM_*     

Ren Chuansen  Zhou Xiuji  Li Weiliang  Qin Yu 《Acta Meteorologica Sinica》1997,11(2):129-142

A 2-D global chemistry-transport model is set up in this paper.The model simulates the atmospheric ozone distributions well with specified dynamical conditions.The analysis of ozone variation mechanism shows that ozone is chemically in quasi-equilibrium except for the polar night region where the variation of ozone concentration is under the control of dynamical processes,that the oxygen atoms which produce ozone are mainly provided by the photolysis of O₂ in the upper stratosphere and by the photolysis of NO₂ in the lower stratosphere and the troposphere.and that the ozone is destroyed mainly by NO_x:the reactions between NO_x and O₃ and the odd oxygen cycle contribute 80% to more than 90% of the ozone destruction.  相似文献   

楚雄盆地下侏罗统磨拉石楔沉积与含油性研究   总被引：1，自引：1，他引：1  

朱同兴  尹福光  蒲心纯  苟汉成  周明辉  张贵权 《沉积与特提斯地质》1997,17(2):11-23

楚雄盆地为一中生代周缘型走滑前陆盆地，通过对下侏罗统冯家河组沉积特征的详细研究与对比，作者认为早侏罗世是楚雄前陆盆地强烈坳陷与沉降的主要发展时期从早期到晚期经历了一个变深又变浅的典型前陆盆地充填过程。在前陆冲断块体的不断逆冲和加载条件下，楚雄盆地西部早侏罗世沉积物的来源主要为哀牢山造山带隆起，其沉积环境以滨，浅湖或湖泊三角洲为主。  相似文献