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81.
ABSTRACT

This paper analyses the composition of surface water and shallow groundwater in the Grande River basin, North-Central Chile, using this information to characterize water interactions. Chemical and isotopic data for surface water and groundwater (7 and 6 sampling locations, respectively) were obtained from three sampling campaigns performed in March–April (autumn), August–September (late winter) and December (early summer) 2012. Precipitation samples were also collected. Data was processed using spatial distribution charts, Piper and Stiff diagrams, and multivariate analysis. In general, the results for each method converge on a high degree of connectivity between surface water and shallow groundwater in the study area. Furthermore, approximately a 10% of groundwater contribution to the surface flow discharge was estimated for a particular reach. This multi-method approach was useful for the characterization of surface water–groundwater interactions in the Grande River basin, and may become a suitable and replicable scheme for studies in arid and semi-arid basins facing similar water management challenges.
Editor D. Koutsoyiannis; Associate editor B. Dewals  相似文献   
82.
In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.  相似文献   
83.
84.
Several different inventories of global and regional anthropogenic and biomass burning emissions are assessed for the 1980?C2010 period. The species considered in this study are carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon. The inventories considered include the ACCMIP historical emissions developed in support of the simulations for the IPCC AR5 assessment. Emissions for 2005 and 2010 from the Representative Concentration Pathways (RCPs) are also included. Large discrepancies between the global and regional emissions are identified, which shows that there is still no consensus on the best estimates for surface emissions of atmospheric compounds. At the global scale, anthropogenic emissions of CO, NOx and SO2 show the best agreement for most years, although agreement does not necessarily mean that uncertainty is low. The agreement is low for BC emissions, particularly in the period prior to 2000. The best consensus is for NOx emissions for all periods and all regions, except for China, where emissions in 1980 and 1990 need to be better defined. Emissions of CO need better quantification in the USA and India for all periods; in Central Europe, the evolution of emissions during the past two decades needs to be better determined. The agreement between the different SO2 emissions datasets is rather good for the USA, but better quantification is needed elsewhere, particularly for Central Europe, India and China. The comparisons performed in this study show that the use of RCP8.5 for the extension of the ACCMIP inventory beyond 2000 is reasonable, until more global or regional estimates become available. Concerning biomass burning emissions, most inventories agree within 50?C80%, depending on the year and season. The large differences between biomass burning inventories are due to differences in the estimates of burned areas from the different available products, as well as in the amount of biomass burned.  相似文献   
85.
The applicability of the horizontal-to-vertical (H/V) ambient-noise spectral ratio for characterizing earthquake site effects caused by near-surface topography and velocity structures was evaluated at sites underlain by thick (i.e. >100 m) sediment deposits near the southern-end of the New Madrid seismic zone in the central United States. Three-component ambient-noise and velocity models derived from seismic (shear-wave) refraction/reflection surveys showed that a relatively horizontal, sharp shear-wave velocity interface in the soil column resulted in an H/V spectral ratio with a single well-defined peak. Observations at sites with more than one sharp shear-wave velocity contrast and horizontally arranged soil layers resulted in at least two well-defined H/V spectral ratio peaks. Furthermore, at sites where there were sharp shear-wave velocity contrasts in nonhorizontal, near-surface soil layers, the H/V spectra exhibited a broad-bandwidth, relatively low-amplitude signal instead of a single well-defined peak.  相似文献   
86.
Polycyclic aromatic hydrocarbons (PAHs) are widespread persistent pollutants that readily undergo biotic and abiotic conversion to numerous transformation products in rivers, lakes and estuarine sediments. Here we characterize the developmental toxicity of four PAH transformation products each structural isomers of hydroxynaphthoic acid: 1H2NA, 2H1NA, 2H3NA, and 6H2NA. Medaka fish (Oryzias latipes) embryos and eleutheroembryos were used to determine toxicity. A 96-well micro-plate format was used to establish a robust, statistically significant platform for assessment of early life stages. Individual naphthoic acid isomers demonstrated a rank order of toxicity with 1H2NA > 2H1NA > 2H3NA > 6H2NA being more toxic. Abnormalities of circulatory system were most pronounced including pericardial edema and tube heart. To determine if HNA isomers were AhR ligands, spatial-temporal expression and activity of CYP1A was measured via in vivo EROD assessments. qPCR measurement of CYP1A induction proved different between isomers dosed at respective concentrations affecting 50% of exposed individuals (EC50s). In vitro, all ANH isomers transactivated mouse AhR using a medaka CYP1A promoter specific reporter assay. Circulatory abnormalities followed P450 induction and response was consistent with PAH toxicity. A 96-well micro-plates proved suitable as exposure chambers and provided statistically sound evaluations as well as efficient toxicity screens. Our results demonstrate the use of medaka embryos for toxicity analysis thereby achieving REACH objectives for the reduction of adult animal testing in toxicity evaluations.  相似文献   
87.
88.
The purpose of the current study is to compare the influence of different aerobic conditions(biostimulation(BS),bioaugmentation(BA),and a combination of biostimulation and bioaugmentation(BB))on polycyclic aromatic hydrocarbons(PAH)degradation and compare the degraded amount with single step XAD-4 extraction as a new tool for bioavailability assessment for chronically contaminated sediment samples obtained from territory of Autonomous Province Vojvodina of Serbia(S1,S2,and S3).A great number of papers dealing with biodegradation of PAHs in spiked sediment or soil have been published,but to the authors’knowledge,a limited number of papers studied aged,historically polluted sediment and a sum of chosen U.S.Environmental Protection Agency(USEPA)PAHs.A significant reduction(up to67%)in PAH concentration was observed,while the percentage of reduction varied depending on the sediment sample and treatment used.BS treatment successfully stimulated growth of indigenous bacteria.Further,PAH-degrading strain Sphingomonas paucimobilis F8 inoculated in BA and BB treatment survived for up to 7 weeks after it was suppressed by unfavorable conditions or native microbes.Degraded amounts generally showed good correlation with results obtained from XAD-4 extraction.Results obtained in the current study represent a good start for standardizing a XAD-4 extraction technique as a simplified,easier,and lower cost method for bioavailability assessment.  相似文献   
89.
The spectral response of atmospheric electric potential gradient gives important information about phenomena affecting this gradient at characteristic time scales ranging from years (e.g., solar modulation) to fractions of a second (e.g., turbulence). While long-term time scales have been exhaustively explored, short-term scales have received less attention. At such frequencies, space-charge transport inside the planetary boundary layer becomes a sizeable contribution to the potential gradient variability. For the first time, co-located (Évora, Portugal) measurements of boundary-layer backscatter profiles and the 100-Hz potential gradient are reported. Five campaign days are analyzed, providing evidence for a relation between high-frequency response of the potential gradient and strong dry convection.  相似文献   
90.
A reply to a recent paper by Setten.  相似文献   
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