Photo-induced degradation of emamectin benzoate: effect of iron amendments and solvent system     

Saadia Rashid Tariq  Nazia Rafique  Sana Kiran  Abdul Muqeet Khan 《Environmental Earth Sciences》2014,72(4):983-988

Photodegradation is the major dissipation pathway for emamectin benzoate (EB) in water. Therefore, the photolysis of EB was studied in distilled water (DW) and methanol under different irradiation conditions such as natural sunlight, UV tube, and artificially stimulated light (mercury lamp 125 W). The results of the study showed that EB degrades rapidly in DW than in methanol as evidenced by a photodegradation efficiency of about 75 % achieved in DW, after 24 h of irradiation with UV light, while in methanol, it was only 59.3 %. The addition of iron to EB solution in DW further enhanced its photodegradation. The rate of photodegradation of EB was recorded to be increased from 5.5 × 10^?2 to 1.0 × 10^?1 k/h after amendment with iron. The order for the rate of photodegradation of EB was DW + Fe > DW > methanol, with their respective t _1/2 values of 6.5, 12.6, and 18.7 h. Fe amendment was also found to enhance the degradation efficiency of EB even in the absence of any light (dark).  相似文献   

Studies of clump structure of photodissociation regions at millimeter and sub-millimeter wavelengths     

Abdul Qaiyum  Syed Salman Ali 《Journal of Astrophysics and Astronomy》2003,24(3-4):69-83

To interpret the millimeter and sub-millimeter line emissions of atomic and molecular species from galactic and extragalactic photodissociation regions, warm gas components and molecular clouds, generally, escape probability formalism of Tielens & Hollenbach (herein referred as TH) are employed which is based on the assumption of plane parallel geometry of infinite slab allowing photons to escape only from the front. Contrary to the assumption observationally it is found that these lines are optically thin except OI(63μ m) and low rotational transitions of CO and some other molecules. This observational evidence led us to assume that emitting regions are finite parallel plane slab in which photons are allowed to escape from both the surfaces (back and front). Therefore, in the present study escape of radiations from both sides of the homogeneous and also clumpy PDR/molecular clouds are taken into consideration for calculating the line intensities at millimeter and sub-millimeter wavelengths (hereinafter referred as QA). Results are compared with that of the TH model. It is found that thermal and chemical structures of the regions are almost similar in both the formalisms. But line intensities are modified by differing factors. Particularly at low density and low kinetic temperature and also for optically thin lines line intensities calculated from TH and QA model differ substantially. But at density higher than the critical density and also for optically thick lines TH and QA models converge to almost same values. An attempt has been made to study the physical conditions of the M17 region employing the present formalism.  相似文献   

Chandra and XMM–Newton detection of large-scale diffuse X-ray emission from the Sombrero galaxy     

Zhiyuan Li  Q. Daniel Wang  Salman Hameed 《Monthly notices of the Royal Astronomical Society》2007,376(3):960-976

  相似文献   

Heavy metal contamination in surface sediments of Gökçekaya Dam Lake,Eskişehir,Turkey     

Beril Salman Akin  Oğulcan Kırmızıgül 《Environmental Earth Sciences》2017,76(11):402

The present study to find seasonal (September 2010–June 2011) heavy metal (Cd, Pb, Cr, Co, Ni, Zn, Cu, Fe, As) contamination and the origins thereof in surface sediments of Gökçekaya Dam Lake, as constructed on Sakarya River, the third-longest river in Turkey and the largest river of the Northwestern Anatolia. Upon analyses for the purpose thereof, heavy metal contamination in annual average concentrations in the lake sediment varied, respectively, as Fe > Zn > Cr > Ni > Cu > Pb > Co > As > Cd. Statistical assessments performed in order to see whether the average values of the heavy metal contamination as measured at stations placed in the lake changed by seasonal periods. There found statistically significant differences especially in Cd, Zn, and Pb between seasonal periods. In accordance with the Sediment Quality Index, Gökçekaya Dam Lake sediment was classified as “highly polluted” in terms of the amount of anthropogenic contaminants of As, Cr, Cu, Ni, Pb, and Zn. Enrichment factor and geoaccumulation index values (I _geo) were calculated in order to geochemically interpret the source of contamination due to heavy metal concentration in the lake sediment and the level of pollution. The As, Co, Cr, Cu, Ni Pb, and Zn values demonstrated that the sediment was rich for anthropogenic contaminants. The lake was found especially rich for arsenic (14.97–34.70 mg/kg) and lead (68.75–98.65 mg/kg) in accordance with annual average values. In general the lake was geochemically characterized as “moderately contaminated” in terms of As, Co, Cr, Cu, Ni, Pb, and Zn content.  相似文献   

Boron contamination in groundwater at a sewage waste disposal facility near Jeddah,Saudi Arabia     

Faisal Rehman  Tariq Cheema 《Environmental Earth Sciences》2017,76(5):218

  相似文献   

Image data fusion for the remote sensing of freshwater environments   总被引：2，自引：0，他引：2  

Salman Ashraf  Lars BrabynBrendan J. Hicks 《Applied geography (Sevenoaks, England)》2012,32(2):619-628

Remote sensing based mapping of diverse and heterogeneous freshwater environments requires high-resolution images. Data fusion is a useful technique for producing a high-resolution multispectral image from the merging of a high-resolution panchromatic image with a low-resolution multispectral image. Given the increasing availability of images from different satellite sensors that have different spectral and spatial resolutions, data fusion techniques that combine the strengths of different images will be increasingly important to Geography for land-cover mapping. Different data fusion methods however, add spectral and spatial distortions to the resultant data depending on the geographical context; therefore a careful selection of the fusion method is required. This paper compares a technique called subtractive resolution merge, which has not previously been formally tested, with conventional techniques such as Brovey transformation, principal component substitution, local mean and variance matching, and optimised high pass filter addition. Data fusion techniques are grouped into spectral and spatial centric methods. Subtractive resolution merge belongs to a new class of data fusion techniques that uses a mix of both spatial and spectral centric approaches. The different data fusion techniques were applied to a QuickBird image of a semi-aquatic freshwater environment in New Zealand. The results were compared both qualitatively and quantitatively using spectral and spatial error metrics. This research concludes that subtractive resolution merge performed better than all the other techniques and will be a valuable technique for enhancing images for freshwater land-cover mapping.  相似文献   

Seasonal and Interannual Sea Surface Temperature Variability in the Coastal Cities of Arabian Sea and Bay of Bengal     

Tariq Masood Ali Khan  Dewan Abdul Quadir  Tad S. Murty  Majajul Alam Sarker 《Natural Hazards》2004,31(2):549-560

The sea surface temperature (SST) variations play a veryimportant role in the genesis and maintenance of meteorological and oceanographic processessuch as monsoon depressions and subsequent floods, large-scale sea level fluctuationsand genesis of tropical cyclones. Many low lying coastal regions of South Asia are adjacentto river deltas and have large population. The dense population, poor economy and severalother socio-economic factors make these areas most vulnerable to the impact of climate change.Variability of sea surface temperature (SST) is importantas the duration and intensity of SST provide the basis for studies related to climatic changescenario. In this study an attempt has been made to estimate the recent SST trends in the coastalwaters of some cities, which lie on the Arabian Sea and Bay of Bengal. The annual andinterannual variability has also been studied. The SST variations have then been linkedwith the El Nino and La Nina events.The NOAA-NASA Pathfinder Advanced Very High Resolution Radiometer (AVHRR) SST fields from 1985-1998, created in the Jet Propulsion Laboratory(JPL), USA are used in this study. Here the quality of data is an important factor toobtain reliable estimates of Sea Surface Temperature (SST) trends and other related parameters.However, this is not possible with the conventional type data, due to low quality as wellas sparse data in the region. Though the satellite based SST climatologies have shorterobservation lengths, they can provide reliable estimates of recent SST variability overa large oceanic areas with sparse or no data.Increasing trend of SST is observed throughout all theseasons in the northern Arabian Sea extending from Oman to Karachi and Mumbai and furthersouth to Salalah and Colombo. However, in coastal islands stations further south ofIndia such as at Colombo the increment is not significant. Though the increasing trend in SSTduring winter is not significant, nevertheless it shows the increasing influence of coldspells on this Island. An interesting situation has been observed in the Bay of Bengal. On anaverage, increasing trends in the annual SST were observed in Visakhaputnam. But at thestations located in the northeastern part of Bay of Bengal, namely Hiron Point and Cox'sBazar reverse conditions are observed. In the Southern Bay of Bengal variations in SST isnot significant which reflects in the SST analysis of Chennai and Port Blair stations. Locationof these stations at lower latitudes (near by equator) probably is the reason for this insignificantchange. It has been found that the interannual mode of SST variations dominate the linear SSTtrends which is characterized by the El Nino Southern Oscillations (ENSO) scale cycle.  相似文献   

Establishing a baseline to evaluate future impacts to groundwater resources in North Kuwait     

Amitabha Mukhopadhyay  Adnan Akber  Tariq Rashed  Vincent Kotwicki  Saif Uddin  Abdullah Bushehri 《Environmental Earth Sciences》2016,75(4):324

  相似文献   

Emission quantification of refrigerant CFCs,HCFCs and HFCs in megacity Lahore (Pakistan) and contributed ODPs and GWPs     

Zia Ul-Haq  Muhammad Ali  Syeda Adila Batool  Salman Tariq  Zarmina Qayyum 《Journal of Earth System Science》2016,125(6):1273-1284

An integrated assessment of emissions of some important refrigerant ozone depleting substances (ODSs) (CFC-11, CFC-12, HCFC-141b and HFC-134a) and their contributed ozone depletion potentials (ODPs) and global warming potentials (GWPs) have been made in the megacity Lahore (Pakistan) for the period from 2005 to 2013. During the production of 6.488 million refrigerator units, the cumulative estimated emissions of CFC-11, CFC-12, HCFC-141b and HFC-134a were 129.7, 6.8, 1257 and 104 mega grams (1 Mg = 10⁶ grams). The estimated GWP (CO₂-eq) and ODP (CFC 11-eq) associated with production phase emissions of these four gases were 616.07, 73.52, 910.96, and 87.36 kilotonnes, and 129.7, 6.8, 139.4, and 0 tonnes, respectively. ODP of HFC-134a is considered to be zero. In addition, the repair and maintenance of 81.2 thousand units resulted in 10.8 Mg emissions of CFC-12 with 10.8 tonnes ODP(CFC 11-eq) and 117,802 tonnes GWP (CO₂-eq) that were higher than the HFC-134a emissions recorded at 4.3 Mg causing 4563 tonnes GWP(CO₂-eq). A decrease in ODP (CFC 11-eq) and GWP (CO₂-eq) at the rate of ?8.3% and ?8.2% per year is observed to be contributed by all the selected ODSs during the study period.  相似文献   

Satellite and ground-based remote sensing of aerosols during intense haze event of October 2013 over lahore,Pakistan     

Salman Tariq  ul-Haq Zia  Muhammad Ali 《Asia-Pacific Journal of Atmospheric Sciences》2016,52(1):25-33

Due to increase in population and economic development, the mega-cities are facing increased haze events which are causing important effects on the regional environment and climate. In order to understand these effects, we require an in-depth knowledge of optical and physical properties of aerosols in intense haze conditions. In this paper an effort has been made to analyze the microphysical and optical properties of aerosols during intense haze event over mega-city of Lahore by using remote sensing data obtained from satellites (Terra/Aqua Moderate-resolution Imaging Spectroradiometer (MODIS) and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO)) and ground based instrument (AErosol RObotic NETwork (AERONET)) during 6-14 October 2013. The instantaneous highest value of Aerosol Optical Depth (AOD) is observed to be 3.70 on 9 October 2013 followed by 3.12 on 8 October 2013. The primary cause of such high values is large scale crop residue burning and urban-industrial emissions in the study region. AERONET observations show daily mean AOD of 2.36 which is eight times higher than the observed values on normal day. The observed fine mode volume concentration is more than 1.5 times greater than the coarse mode volume concentration on the high aerosol burden day. We also find high values (~0.95) of Single Scattering Albedo (SSA) on 9 October 2013. Scatter-plot between AOD (500 nm) and Angstrom exponent (440-870 nm) reveals that biomass burning/urban-industrial aerosols are the dominant aerosol type on the heavy aerosol loading day over Lahore. MODIS fire activity image suggests that the areas in the southeast of Lahore across the border with India are dominated by biomass burning activities. A Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model backward trajectory showed that the winds at 1000 m above the ground are responsible for transport from southeast region of biomass burning to Lahore. CALIPSO derived sub-types of aerosols with vertical profile taken on 10 October 2013 segregates the wide spread aerosol burden as smoke, polluted continental and dust aerosols.  相似文献