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151.
The potential energy surface (PES) for the \(\mathrm{CP}(\mathrm{X}^{2}\varSigma^{+})\)-\(\mathrm{He}(^{1}S)\) complex has been calculated at the RCCSD(T)-F12/VTZ-F12 level of theory. The analytic fit of the PES was obtained by using global analytical method. The fitted PES was used subsequently in the close-coupling approach for the computation of the state-to-state collisional excitation cross sections of the fine-structure levels of the CP-He complex. Collision energies were taken up to 1500 cm?1 and they yield after thermal averaging, state-to-state rate coefficients up to 200 K. The propensity rules between the lowest fine-structure levels were studied. These rules show, on one hand, a strong propensity in favour of even \(\Delta N\) transitions, and the other hand, that cross sections and collisional rate coefficients for \(\Delta j =\Delta N\) transitions are larger than those for \(\Delta j\neq \Delta N\) transitions.  相似文献   
152.
The purpose of this paper is to analyse the regional impact of recent climate change on the water resources in southern France. We produced spatial reconstructions of the monthly evolutions of temperature, precipitation and water discharge in 15 watersheds of six coastal river basins and examined the major changes based on trend analysis for the last 40 years. In this part of the Mediterranean, the general warming trend was strongly enhanced by changes in the atmospheric circulation patterns, characterized by a northward extension of the subtropical high pressure domain during spring and summer. During these seasons, monthly warming rates could achieve almost twice the mean annual warming rates. Although annual precipitation did not follow clear trends, water discharge significantly decreased in one third of the watersheds and accounted for an estimated 20% reduction of the water resources in this region. This concerns both the highest and lowest watersheds. In the former, the reduction is likely the result of a temperature induced switch of snowfall to rainfall at high altitudes. In the latter, the reduction of discharge seems to come from lower groundwater levels, which may be related to the temperature increase too, but also have other origins. The recent climatic evolution is consistent with most modelling simulations for the future, indicating that the reduction of the water resources will hold on, probably still enhanced by decreases in precipitation.  相似文献   
153.
A review is given of the summer monsoon systems in Africa and India, and of their comparison at different time scales. Features of the circulation are described first, including the main respective meteorological centres of action controlling the annual cycle of the rain bands over these two regions. The main elements of the atmospheric intraseasonal variability are then presented, which controls in particular the onset of these two monsoon systems. Then the sensitivity of these two monsoon systems to oceanic and continental surface conditions in the context of interannual variability is discussed and compared. Consequences in term of predictability are commented. Finally, the Intergovernmental Panel on Climate Change (IPCC4) scenarios of the future climate over these two regions are presented.  相似文献   
154.
Lemmus and Myopus are two lemming species with distinct habitat requirements but which show very similar dental morphologies. They are thus extremely difficult to distinguish from one another in the fossil record on the basis of their dental remains, leading to poor understanding of the palaeobiogeographical evolution of Myopus as well as inaccurate palaeoenvrionmental reconstructions. Currently, the presence of Myopus in the fossil register from the Pleistocene is still debated and no firm occurrence of this lemming in western Europe has yet been confirmed for the Late Pleistocene. In this paper, we used geometric morphometrics on modern material to establish morphological differences between Lemmus and Myopus teeth (first lower and third upper molars). Morphological data were then used to build a robust linear discriminant model able to confidently classify isolated teeth of these two genera, and finally, linear discriminant models were used on fossil remains of Lemmus/Myopus from two Late Pleistocene archaeological/palaeontological sites (Grotte des Gorges and Gully Cave). This study demonstrates, for the first time, the presence of Myopus schisticolor in west European Late Pleistocene sites between the end of Marine Isotope Stage 3 and the beginning of the Holocene, during climatic events that favoured the development of taiga forest of birch and pine in these regions.  相似文献   
155.
Regional climate model (RCM) is a valuable scientific tool to address the mechanisms of regional atmospheric systems such as the West African monsoon (WAM). This study aims to improve our understanding of the impact of some physical schemes of RCM on the WAM representation. The weather research and forecasting model has been used by performing six simulations of the 2006 summer WAM season. These simulations use all combinations of three convective parameterization schemes (CPSs) and two planetary boundary layer schemes (PBLSs). By comparing the simulations to a large set of observations and analysis products, we have evaluated the ability of these RCM parameterizations to reproduce different aspects of the regional atmospheric circulation of the WAM. This study focuses in particular on the WAM onset and the rainfall variability simulated over this domain. According to the different parameterizations tested, the PBLSs seem to have the strongest effect on temperature, humidity vertical distribution and rainfall amount. On the other hand, dynamics and precipitation variability are strongly influenced by CPSs. In particular, the Mellor?CYamada?CJanjic PBLS attributes more realistic values of humidity and temperature. Combined with the Kain?CFritsch CPS, the WAM onset is well represented. The different schemes combination tested also reveal the role of different regional climate features on WAM dynamics, namely the low level circulation, the land?Catmosphere interactions and the meridional temperature gradient between the Guinean coast and the Sahel.  相似文献   
156.
Decadal Sahelian rainfall variability was mainly driven by sea surface temperatures (SSTs) during the twentieth century. At the same time SSTs showed a marked long-term global warming (GW) trend. Superimposed on this long-term trend decadal and multi-decadal variability patterns are observed like the Atlantic Multidecadal Oscillation (AMO) and the inter-decadal Pacific Oscillation (IPO). Using an atmospheric general circulation model we investigate the relative contribution of each component to the Sahelian precipitation variability. To take into account the uncertainty related to the use of different SST data sets, we perform the experiments using HadISST1 and ERSSTv3 reconstructed sets. The simulations show that all three SST signals have a significant impact over West Africa: the positive phases of the GW and the IPO lead to drought over the Sahel, while a positive AMO enhances Sahel rainfall. The tropical SST warming is the main cause for the GW impact on Sahel rainfall. Regarding the AMO, the pattern of anomalous precipitation is established by the SSTs in the Atlantic and Mediterranean basins. In turn, the tropical SST anomalies control the impact of the IPO component on West Africa. Our results suggest that the low-frequency evolution of Sahel rainfall can be interpreted as the competition of three factors: the effect of the GW, the AMO and the IPO. Following this interpretation, our results show that 50% of the SST-driven Sahel drought in the 1980s is explained by the change to a negative phase of the AMO, and that the GW contribution was 10%. In addition, the partial recovery of Sahel rainfall in recent years was mainly driven by the AMO.  相似文献   
157.
Metal transport in mollusk extrapallial fluid (EPF) that acts as a "bridge" between soft tissues and shell has surprisingly received little attention until now. Using ultrafiltration and radiotracer techniques we determined silver concentrations and speciation in the EPF of the blue mussel Mytilus edulis after short-term uptake and depuration laboratory experiments. Radiolabelled silver ((11?m)Ag) was used in dissolved or nanoparticulate phases (AgNPs < 40 nm), with a similar low Ag concentration (total radioactive and cold Ag ~0.7 μg/L) in a way that mussels could uptake radiotracers only from seawater. Our results indicated that silver nanoparticles were transported to the EPF of blue mussels at a level similar to the Ag ionic form. Bulk activity of radiolabelled silver in the EPF represented only up to 7% of the bulk activity measured in the whole mussels. The EPF extracted from mussels exposed to both treatments exhibited an Ag colloidal complexed form based on EPF ultrafiltration through a 3 kDa filter. This original study brings new insights to internal circulation of nanoparticles in living organisms and contributes to the international effort in studying the potential impacts of engineered nanomaterials on marine bivalves which play an essential role in coastal ecosystems, and are important contributors to human food supply from the sea.  相似文献   
158.
The Huadu flora of Guangdong Province, South China contains the lepidodendrid Lepidodendron shanyangense Wu et He, its putative rhizophore Stigmaria cf. ficoides (Brongniart) Sternberg; sphenophyte s.l. Archaeocalamites scrobiculatus (Brongniart) Stur; bowmanitid Sphenophyllum tenerrimum (Ettingshausen) Stur; pteridophyll Sphenopteris sp. of uncertain taxonomic position; undetermined ferns gen. et sp. nov.; lyginopterid pteridosperm Rhodeopteridium hsianghsiangense (Sze) Zhang, Zhao et Wu, a trigonocarpoid pteridosperm represented by fronds and isolated pinnules of Paripteris gigantea (Sternberg) Gothan, male fructifications of Potoniea sp., and seeds of Trigonocarpus sp. Ecologically, the Early Carboniferous (Visean) Huadu vegetation was divided into two neighboring communities: (1) a near-shore hydrophilous "community A" with predominating Archaeocalamites and Rhodeopteridium; and (2) a wet forest "community B" with predominating shrubby trigonocarpalean pteridosperm Paripteris gigantea (Sternberg) Gothan and tall tree-like lepidodendrid Lepidodendron shanyangense Wu et He. The Huadu vegetation was physiognomically similar to present-day low-latitude mangrove forest.  相似文献   
159.
Optimal fingerprinting has been the most widely used method for climate change detection and attribution over the last decade. The implementation of optimal fingerprinting often involves projecting onto k leading empirical orthogonal functions in order to decrease the dimension of the data and improve the estimate of internal climate variability. However, results may be sensitive to k, and the choice of k remains at least partly arbitrary. One alternative, known as regularised optimal fingerprinting (ROF), has been recently proposed for detection. This is an extension of the optimal fingerprinting detection method, which avoids the projection step. Here, we first extend ROF to the attribution problem. This is done using both ordinary and total least square approaches. Internal variability is estimated from long control simulations. The residual consistency test is also adapted to this new method. We then show, via Monte Carlo simulations, that ROF is more accurate than the standard method, in a mean squared error sense. This result holds for both ordinary and total least square statistical models, whatever the chosen truncation k. Finally, ROF is applied to global near-surface temperatures in a perfect model framework. Improvements provided by this new method are illustrated by a detailed comparison with the results from the standard method. Our results support the conclusion that ROF provides a much more objective and somewhat more accurate implementation of optimal fingerprinting in detection and attribution studies.  相似文献   
160.
Macrofossil analyses were used to reconstruct long-term vegetation successions within ombrotrophic peatlands (bogs) from the northern shorelines of the St. Lawrence Estuary (Baie-Comeau) and the Gulf of St. Lawrence (Havre-St-Pierre). Over the Holocene, the timing and the ecological context of peatland inception were similar in both regions and were mainly influenced by fluctuations in relative sea level. Peat accumulation started over deltaic sands after the withdrawal of the Goldthwait Sea from 7500 cal yr BP and above silt–clay deposits left by the Laurentian marine transgression after 4200 cal yr BP. In each region, the early vegetation communities were similar within these two edaphic contexts where poor fens with Cyperaceae and eastern larch (Larix laricina) established after land emergence. The rapid transitions to ombrotrophy in the peatlands of Baie-Comeau are associated with particularly high rates of peat accumulation during the early developmental stage. The results suggest that climate was more propitious to Sphagnum growth after land emergence in the Baie-Comeau area. Macrofossil data show that treeless Sphagnum-dominated bogs have persisted over millennia and that fires had few impacts on the vegetation dynamics. This study provides insight into peatland vegetation responses to climate in a poorly documented region of northeastern America.  相似文献   
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