A Case Study on the Occurrence and Mobility of the Shale Oil from the Muli Coalfield, Qilian Mountain     

CHEN Xiaohui  ZHANG Min 《《地质学报》英文版》2016,90(6):2267-2268

正Objective Shale oil occurs in free state(including condensate state),adsorption state(adsorbed on kerogen and mineral particles)and dissolved state(dissolved in natural gas,residual water,etc.)in shales and adjacent layers.The characterization of the occurrence of different hydrocarbons in shale oil,especially the quantitative  相似文献   

新疆“帕米尔式”铁矿床成因与成矿背景分析     

张德贤  曹汇  曾敏  许明珠  李广旭  星显宏 《岩石学报》2016,32(12):3847-3864

帕米尔式"铁矿床是新疆西昆仑地区重要的磁铁矿床类型之一,其矿床地质特征、形成时代明显有别于典型的BIFs类型磁铁矿床。本文以塔什库尔干地区翁吉勒磁铁矿床和孜勒依磁铁矿床作为研究对象,通过研究其赋矿围岩和岩体的岩石地球化学特征、矿石矿相学特征、磁铁矿微量元素地球化学特征和原位Pb-Pb同位素特征,探讨了"帕米尔式"磁铁矿床的矿床成因和成矿背景。岩石地球化学研究表明翁吉勒黑云母二长花岗岩具有高SiO_2、Al_2O_3、K_2O和Na_2O。低MgO、CaO和TiO_2,而Na_2O/K_2O值变化范围很小。铝饱和指数为(1.44~1.51),显示其具有为弱过铝质岩石的特征,稀土总量富集,具有强的负Eu异常。在微量元素蛛网图上显示其富集大离子亲石元素(LILE),如K、Rb、Sr、Ba及轻稀土元素(LREE),亏损Nb、Ta,P、Ti等高场强元素。而黑云母石英片岩稀土含量亦较富集,具有中等强度的负Eu异常。低的Rb/Sr比,明显的Th、Zr、Hf、Nb、Ta,P、Ti负异常,明显的Ba正异常,显示岩石具有古大陆边缘环境的富铝沉积岩特征。翁吉勒黑云母二长花岗岩和布伦阔勒岩群黑云母石英片岩地球化学性质非常相似,表明翁吉勒黑云母二长花岗岩的形成与布伦阔勒岩群黑云母石英片岩的重熔有关。锆石LA ICP-MS定年结果表明翁吉勒黑云母二长花岗岩形成于15.0±0.3Ma和15.4±0.2Ma。磁铁矿LA ICP-MS微量元素地球化学特征表明翁吉勒铁矿床中的磁矿床中主要Si、Mn、Zn、Sn、Hf和Pb相对较高,其中Mn和Ga变化范围较大,而孜勒依铁矿床中的磁铁矿具有相对较高的亲石元素,如Mg、Al、Ti、V、Co、Ni、Ga和Sc等,其Mn和Zn含量较低且变化范围较大,其它元素变化范围均相对较窄。二者相比,翁吉勒铁矿床中的磁铁矿中微量元素变化范围相对较大,而孜勒依铁矿床中的磁铁矿变化范围较小。两个矿床的磁铁矿的原位Pb-Pb同位素存在明显的不同,两类岩石全岩Pb同位素与两个矿床中磁铁矿Pb-Pb同位素研究表明翁吉勒铁矿床中磁铁矿可能与黑云母二长花岗岩有关,为热液成因。综上所述,在塔什库尔干地区不仅存在与沉积作用有关的铁矿床,还可能存在一部分与年轻岩浆岩有关的热液型磁铁矿床。  相似文献   

CO₂加富对塔玛亚历山大藻叶绿素荧光参数及产毒的影响   总被引：2，自引：2，他引：0  

徐金涛  庞敏  马新  毛雪薇  吴振兴  陈洪举  王燕  张学雷 《海洋与湖沼》2016,47(3):557-563

由大气中CO_2浓度升高引起的海洋酸化,是全球性的重大环境问题之一。本研究采用实验生态学的方法,以塔玛亚历山大藻(Alexandrium tamarense)为研究对象,分析其在CO_2加富条件下叶绿素荧光动力学参数及产毒特征的变化。调制叶绿素荧光结果显示,CO_2加富对塔玛亚历山大藻的PSⅡ最大光化学量子产量(Fv/Fm)、最大相对电子传递效率(r ETRmax)有显著影响(P0.05),且随着培养时间的增长Fv/Fm、r ETRmax均降低,对半饱和光强(Ik)、快速光曲线初始斜率(α)却无显著影响(P0.05)。结果说明CO_2加富能促进塔玛亚历山大藻的PSⅡ最大光化学量子产量,提高其最大光能转换效率和相对最大电子传递效率。高效液相色谱法分析结果显示,该株塔玛亚历山大藻主要产漆沟藻毒素1(GTX1)、漆沟藻毒素4(GTX4)、N-磺酰氨甲酰基毒素(C1)及N-磺酰氨甲酰基毒素(C2)四种PSTs毒素,CO_2加富不改变主要麻痹性贝毒(PSTs)的种类组成,但能显著提高氨基甲酸酯类毒素(GTX1、GTX4)产量(P0.05),而降低N-磺酰氨甲酰基类毒素(C1、C2)产量(P0.05),说明加富能使塔玛亚历山大藻所产毒素发生转化,进而影响藻细胞的整体毒性。  相似文献   

中国近海以及邻近海域海洋再分析产品(CORA)中季节内变化的评估   总被引：5，自引：2，他引：3  

张敏  周磊  付红丽  姜良红  章向明 《海洋学报(英文版)》2016,35(3):90-101

A regional reanalysis product—China Ocean Reanalysis(CORA)—has been developed for the China's seas and the adjacent areas. In this study, the intraseasonal variabilities(ISVs) in CORA are assessed by comparing with observations and two other reanalysis products(ECCO2 and SODA). CORA shows a better performance in capturing the intraseasonal sea surface temperatures(SSTs) and the intraseasonal sea surface heights(SSHs) than ECCO2 and SODA do, probably due to its high resolution, stronger response to the intraseasonal forcing in the atmosphere(especially the Madden-Julian Oscillation), and more available regional data for assimilation. But at the subsurface, the ISVs in CORA are likely to be weaker than reality, which is probably attributed to rare observational data for assimilation and weak diapycnal eddy diffusivity in the CORA model. According to the comparison results, CORA is a good choice for the study related to variabilities at the surface, but cares have to be taken for the study focusing on the subsurface processes.  相似文献   

低分子质量褐藻寡糖的高效酶法制备及其抗氧化活性评价     

张明杰  李恒  蒋敏  郝瑶  许正宏  史劲松 《海洋科学》2016,40(12):62-70

褐藻寡糖具有多种生理活性,本研究通过酶解与分级条件的优化,获得了低分子质量褐藻寡糖的酶法制备工艺,并在体外模型上评价了不同分子质量组分的抗氧化活性。结果表明,优化后的褐藻寡糖制备条件为:底物浓度1.20%,酶底比4.35 U/mg,酶解时间4 h。进一步采用乙醇沉淀和超滤分离后,获得了重均分子质量分别为0.84、1.40、2.25和34.56 k Da的4种组分,其得率分别为50.82%、5.15%、11.48%和12.00%。各组分均具有一定的还原能力,可有效清除DPPH和羟自由基,其中低分子质量组分A的抗氧化活性最为显著,其清除羟自由基的能力与维生素C相近。  相似文献   

Iron Reduction Along an Inundation Gradient in a Tidal Sedge (<Emphasis Type="Italic">Cyperus malaccensis</Emphasis>) Marsh: the Rates,Pathways, and Contributions to Anaerobic Organic Matter Mineralization     

Min?Luo  Cong-Sheng?ZengEmail author  Chuan?Tong  Jia-Fang?Huang  Kai?Chen  Feng-Qin?Liu 《Estuaries and Coasts》2016,39(6):1679-1693

Incubation experiments were adopted to characterize the rates and pathways of iron reduction and the contributions to anaerobic organic matter mineralization in the upper 0–5 cm of sediments along a landscape-scale inundation gradient in tidal marsh sediments in the Min River Estuary, Southeast China. Similar sediment characteristics, single-species vegetation, varied biomass and bioturbation, distinct porewater pH, redox potential, and electrical conductivity values have resulted in a unique ecogeochemical zonation along the inundation gradient. Decreases in solid-phase Fe(III) and increases in nonsulfidic Fe(II) and iron sulfide were observed in a seaward direction. Porewater Fe²⁺ was only detected in the upland area. High rates of iron reduction were observed in incubation jars, with significant accumulations of nonsulfidic Fe(II), moderate accumulations of iron sulfides, and negligible accumulations of porewater Fe²⁺. Most of the iron reduction was microbially mediated rather than coupled to reduced sulfides. Microbial iron reduction accounted for 20–89 % of the anaerobic organic matter mineralization along the inundation gradient. The rate and dominance of microbial iron reduction generally decreased in a seaward direction. The contributions of microbial iron reduction to anaerobic organic matter mineralization depended on the concentrations of bioavailable Fe(III), the spatial distribution of which was significantly related to tidal inundation. Our results clearly showed that microbial iron reduction in the upper sediments along the gradient is highly dependent on spatial scales controlled primarily by tidal inundation.  相似文献   

Identification of light-harvesting chlorophyll a/b-binding protein genes of Zostera marina L. and their expression under different environmental conditions     

Fanna Kong  Yang Zhou  Peipei Sun  Min Cao  Hong Li  Yunxiang Mao 《中国海洋大学学报(英文版)》2016,15(1):152-162

  相似文献   

Antialgal and antilarval activities of bioactive compounds extracted from the marine dinoflagellate <Emphasis Type="Italic">Amphidinium carterae</Emphasis>     

Xianyu Kong  Xiurong Han  Min Gao  Rongguo Su  Ke Wang  Xuzhao Li  Wei Lu 《中国海洋大学学报(英文版)》2016,15(6):1014-1020

With the global ban on the application of organotin-based marine coatings by the International Maritime Organization, the development of environmentally friendly, low-toxic and nontoxic antifouling compounds for marine industries has become an urgent need. Marine microorganisms have been considered as a potential source of natural antifoulants. In this study, the antifouling potential of marine dinoflagellate Amphidinium carterae, the toxic and red-tide microalgae, was investigated. We performed a series of operations to extract the bioactive substances from Amphidinium carterae and tested their antialgal and antilarval activities. The crude extract of Amphidinium carterae showed significant antialgal activity and the EC₅₀ value against Skeletonema costatum was 55.4 μg mL^?1. After purification, the isolated bioactive substances (the organic extract C) exhibited much higher antialgal and antilarval activities with EC₅₀ of 12.9 μg mL^?1 against Skeletonema costatum and LC₅₀ of 15.1 μg mL^?1 against Amphibalanus amphitrite larvae. Subsequently, IR, Q-TOFMS, and GC-MS were utilized for the structural elucidation of the bioactive compounds, and a series of unsaturated and saturated 16- to 22-carbon fatty acids were detected. The data suggested the bioactive compounds isolated from Amphidinium carterae exhibited a significant inhibiting effect against the diatom Skeletonema costatum and Amphibalanus amphitrite larvae, and could be substitutes for persistent, toxic antifouling compounds.  相似文献   

玲珑金矿西山幔源脉岩地球化学特征          下载免费PDF全文

孙雨沁  马晓东  程伟  张岩  李敏 《山东国土资源》2016,32(2)

玲珑西山幔源脉岩主微量元素的变化暗示了源岩很可能经历过类似俯冲带流体的交代作用,矿化流体中含有较高含量的金属矿物,具有Eu的正异常,指示了源区是深源的。脉岩中的CO2来源可能是花岗岩岩浆热液的混入,石英来源于陆壳碎屑物质部分熔融形成的S型花岗岩,硫的来源与幔源脉岩岩浆同源,或来自地幔,或来自地壳深部。  相似文献   

基于多元对应分析的国家地质公园综合价值及分类   总被引：1，自引：0，他引：1  

刘佳  姚华军  高伟  冯春涛  李闵 《地质通报》2016,35(5):842-849

目前地质公园的分类难以针对具有多重价值属性的各类地质公园提出行之有效的分类管理模式。提出基于综合价值的国家地质公园分类模式,建立了国家地质公园综合价值评价指标,通过问卷调查与小组讨论获取了35个国家地质公园的量化综合价值评价指标数据,应用多元对应分析对量化数据进行统计处理,最后将35个国家地质公园分为禀赋型地质公园、生态型地质公园、成熟型地质公园、均衡型地质公园和发展型地质公园五大类,为国家地质公园分类管理提供依据。  相似文献