U–Pb zircon age of the base of the Ediacaran System at the southern margin of the Qinling Orogen     

Lecai Xing  Taiyi Luo  Zhilong Huang  Zhikuan Qian  Mingzhong Zhou  Hongtao He 《中国地球化学学报》2018,37(3):414-421

Global abrupt climate change from Marinoan snowball Earth to greenhouse Earth, recorded as cap carbonate overlain on diamictite, had shed the first light on Cambrian bio-radiation. The most documented cap carbonate sections are typical with comprehensive δ¹³C negative values and ubiquitous sedimentary structures, such as tepee-like, sheet-crack etc., which are associated with successive glacial eustatic variation caused by isostatic rebound in shallow-water facies. Here we report a deep-water basinal cap carbonate section with strong negative δ¹³C values in the southern margin of the Qinling Orogen, Heyu, Chengkou County, Chongqing in China, which consists of massive dolostone with abundant carbonaceous laminae. However, it lacks the sedimentary structure as mentioned above and is overlain by thin-bedded silicious shales and cherts. A K-bentonite bed was discovered within the base of cap carbonates, about 0.7 m above the top of the Marinoan diamictite. Magmatic zircons that were separated from the K-bentonite bed yield a SIMS concordia U–Pb age of 634.1 ± 1.9 Ma (1σ, MSWD_CE = 0.31, Probability_CE = 1.000, n = 20). The age is in good agreement with previously reported TIMS U–Pb ages for the termination of Marinoan glaciation and provides a geochronological constraint for the Ediacaran successions in the Qinling Orogen.  相似文献   

Assessment of trace metals contamination in stream sediments and soils in Abuja leather mining,southwestern Nigeria     

Abiola Oyebamiji  Adegbola Odebunmi  Hu Ruizhong  Atta Rasool 《中国地球化学学报》2018,37(4):592-613

This study is aimed at determining the level of environmental degradation as well as the concentration of trace elements in soil and stream sediments in order to evaluate the environmental impact of the mining operation. Twenty-five (25) soils and ten (10) stream sediment samples were collected from the study area. The physicochemical parameters were determined using appropriate instrumentation with the aid of a digital pH meter (Milwaukee meter) to measure the pH and electrical conductivity, total dissolved solids, moisture content and loss on ignition of the soil and stream sediment samples. The pH of the soil sample ranged from (6.10 to 7.19); Electrical conductivity ranged from (21.3 to 279.4 µS/cm), moisture content varied from (0.60% to 7.20%), and the LOI ranged from (2.03% to 18.62%). The results of the analysis showed that the concentrations of the trace elements in the soils and stream sediment samples were slightly higher than the background values. Plots of the trace elements in stream sediment samples show moderate, consistent decrease downstream except at points where there was mine water discharge into the main river. The pollution levels of heavy metals were examined in stream sediment and soil samples using different assessable indices, such as the enrichment factor, which showed significant-moderate enrichment for Cr, Th, Nb, Zn, Pb, Y and Zr and the geo-accumulation index, which showed practically moderate contamination with Cr, Ni and Sr based on regional background reference values. Geo-accumulation index and contamination index for soils and stream sediment revealed uncontaminated to moderate contamination. Likewise, elements with moderate contamination were Cr, Ni and Sr. The Pearson correlation showed that there were significant positive associations among selected metals in soil and stream sediment samples.  相似文献   

Effects of a proline solution cover on the geochemical and mineralogical characteristics of high-sulfur coal gangue     

Youfa Luo  Yonggui Wu  Tianling Fu  Hu Wang  Rongrong Xing  Zhilin Zheng 《中国地球化学学报》2018,37(5):701-714

Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration (1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. High-sulfur coal gangue was continuously immersed in a proline solution and in deionized water (as a control treatment) for 540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower pH values, higher redox potential values, higher pollutant concentrations (SO₄^2?, Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However, compared to the control treatment, the addition of the proline solution (1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations (SO₄^2?, Fe²⁺, Fe, Mn, Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants, mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover to achieve the in-situ control of pollutant releases from coal gangue dumps.  相似文献   

Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review     

Qing Hu  Huangling Gu  Xiaoyong Yang  Yisu Ren  Ergen Gao  Zhangxing Nie 《中国地球化学学报》2018,37(3):360-383

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.  相似文献   

Erratum to: The oceanic cycles of the transition metals and their isotopes     

Derek Vance  Corey Archer  Susan H. Little  Michael Köbberich  Gregory F. de Souza 《中国地球化学学报》2018,37(1):151-151

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Elemental characteristics of lacustrine oil shale and its controlling factors of palaeo-sedimentary environment on oil yield: a case from Chang 7 oil layer of Triassic Yanchang Formation in southern Ordos Basin     

Delu Li  Rongxi Li  Zengwu Zhu  Feng Xu 《中国地球化学学报》2018,37(2):228-243

As an important unconventional resource, oil shale has received widespread attention. The oil shale of the Chang 7 oil layer from Triassic Yanchang Formation in Ordos Basin represents the typical lacustrine oil shale in China. Based on analyzing trace elements and oil yield from boreholes samples, characteristics and paleo-sedimentary environments of oil shale and relationship between paleo-sedimentary environment and oil yield were studied. With favorable quality, oil yield of oil shale varies from 1.4% to 9.1%. Geochemical data indicate that the paleo-redox condition of oil shale’s reducing condition from analyses of V/Cr, V/(V + Ni), U/Th, δU, and authigenic uranium. Equivalent Boron, Sp, and Sr/Ba illustrate that paleosalinity of oil shale is dominated by fresh water. The paleoclimate of oil shale is warm and humid by calculating the chemical index of alteration and Sr/Cu. Fe/Ti and (Fe + Mn)/Ti all explain that there were hot water activities during the sedimentary period of oil shale. In terms of Zr/Rb, paleohydrodynamics of oil shale is weak. By means of Co abundance and U/Th, paleo-water-depth of oil shale is from 17.30 to 157.26 m, reflecting sedimentary environment which is mainly in semi deep–deep lake facies. Correlation analyses between oil yield and six paleoenvironmental factors show that the oil yield of oil shale is mainly controlled by paleo-redox conditions, paleoclimate, hot water activities, and depth of water. Paleosalinity and paleohydrodynamics have an inconspicuous influence on oil yield.  相似文献   

Timing of mineralization at the Shihu gold deposit in the middle segment of the Taihang Mountain,China     

Chao Chen  Shuyin Niu  Fang Wang  Fuxiang Zhang  Qinglian Zhang  Baojun Ma  Aiqun Sun  Jianzhen Zhang  Yaqi Cao  Xiaoqing Zhang 《中国地球化学学报》2018,37(1):80-89

The Shihu gold deposit, located in the middle-south section of the core of the Fuping mantle branch structure, is hosted in the Archean Fuping Group and adjacent to the quartz diorite porphyrite. The gold deposit is the only large gold deposit with reserves of more than 30 tons gold discovered in western Hebei Province so far. In order to constrain the timing of mineralization of this ore deposit, this paper focuses on the isotopic dating of zircon and pyrite. Zircons in gold-bearing quartz veins are magmatic in origin and no hydrothermal zircon has been found in such quartz veins, indicating that zircons were derived from the wall rocks. U–Pb ages of zircons fall mainly in the two domains: 2492 ± 82 and 136 ± 4 Ma, respectively, indicative of the contribution of the Fuping-Group TTG gneiss and Yanshanian igneous rocks, respectively. The Re–Os isotopic compositions of pyrites in the gold-bearing quartz veins yield an isochron age of 127 ± 31 Ma. Combined with other dating results, we suggest that the main metallogenic age of the Shihu gold deposit is 120–127 Ma.  相似文献   

Identification and determination of the boundary between the Cathaysian and Yangtze blocks: a preliminary understanding of gravity and magnetic fields     

Jiayong Yan  Kun Zhang  Guangming Fu  Fan Luo  Hao Wang  Guang Qi 《《地质学报》英文版》2018,92(Z1):222-225

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Elastic properties of orthoenstatite and its high-pressure phase and implications for the origin of low VP/VS zones and the X discontinuity     

Wangsheng Qian  Wengzhong Wang  Fan Zou  Zhongqing Wu 《《地质学报》英文版》2018,92(Z1):133-133

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内蒙古科尔沁右翼中旗协和尔斯德中生代火山沉积地层时代研究          下载免费PDF全文

付俊彧  那福超  郑少林  钟辉  汪岩  宋维民  孙巍  杨帆 《中国地质》2018,45(1):129-140

内蒙古科尔沁右翼中旗协和尔斯德一带出露一套中生代地层,岩石组合主要为酸性火山碎屑岩、火山碎屑沉积岩夹碎屑沉积岩及酸性火山熔岩。1∶50000区调依据在该套地层上部层位发现的木化石组合确定其时代为中—晚侏罗世,结合岩石组合,将该套地层划分为上侏罗统满克头鄂博组。为了准确厘定该套地层时代,为木化石延限研究及区域生物地层划分对比提供依据,本次研究在低于产木化石层位的酸性火山碎屑岩中采取了锆石测年样品(LA-ICP-MS),获得锆石U-Pb年龄(165±1)Ma,时代为中侏罗世。同时采取了侵入该套地层的斑状细晶闪长岩测年样品,获得锆石年龄(131±1)Ma,限定了地层形成的上限年龄。根据岩性组合的区域对比、测年结果、木化石组合时限、地层产状特征,认为该套地层应划为中侏罗统新民组,是突泉火山-沉积盆地充填物的一部分。  相似文献