Oxygen isotope geochemistry of the Mesozoic volcanics of the Etendeka Formation,Namibia     

Chris Harris  H. Stuart Smith  Simon C. Milner  Anthony J. Erlank  Andrew R. Duncan  Julian S. Marsh  Nicholas P. Ikin 《Contributions to Mineralogy and Petrology》1989,102(4):454-461

The Etendeka Formation volcanics consist of a bimodal association of basalts and quartz latites. Forty three new whole rock oxygen isotope analyses are reported for all the major magma types. All the rocks except a minor suite of dolerites have higher ¹⁸O values than normal mantle. The basic rocks (average of 29=8.8) have significantly different ¹⁸O to the acid rocks (average of 10=14.4) These data are apparently consistent with previously published petrogenetic models, which propose that the basalts were affected by crustal contamination and that the quartz latites are crustally derived. However, mineral oxygen data show that there is significant oxygen isotopic disequilibrium between phenocryst and whole rock, the latter being significantly higher in most cases. One of the basic magma types (the Tafelberg basalts) shows mutual positive correlations between ¹⁸O, SiO₂ and _Sr. If these correlations are due to crustal contamination, then as much as 45% contamination is required by material having a ¹⁸O value of 15 which is the maximum observed value in the Damaran basement rocks. In the absence of pyroxene phenocryst ¹⁸O data for the high _Sr Tafelberg basalts (they are aphyric), it is not possible to confirm that contamination has taken place. An alternative explanation is that the correlation between _Sr and SiO₂ resulted from assimilation coupled with fractional crystallization (AFC) (before emplacement). Post-eruption alteration resulted in a correlation between SiO₂ ¹⁸O because the material with the most Si-O bonds was able to concentrate ¹⁸O more effectively. The limited mineral data for the quartz latites suggests that there is some source heterogeneity. A pyroxene ¹⁸O value of 10% for a southern Etendeka quartz latite is consistent with a crustal source.  相似文献   

A model of channel response in disturbed alluvial channels   总被引：2，自引：0，他引：2  

Andrew Simon 《地球表面变化过程与地形》1989,14(1):11-26

Dredging and straightening of alluvial channels between 1959 and 1978 in West Tennessee caused a series of morphologic changes along modified reaches and tributary streams. Degradation occurred for 10 to 15 years at sites upstream of the area of maximum disturbance and lowered bed-levels by as much as 6·1 m. Following degradation, reaches upstream of the area of maximum disturbance experienced a secondary aggradation phase in response to excessive incision and gradient reduction. Aggradation downstream of the area of maximum disturbance reached 0·12 m per year with the greatest rates occurring near the stream mouths. The adjustment of channel geometry and phases of channel evolution are characterized by six process-oriented stages of morphologic development—premodified, constructed, degradation, threshold, aggradation, and restabilization. Down-cutting and toe removal during the degradation stage causes bank failure by mass wasting when the critical height and angle of the bank material is exceeded (threshold stage). Channel widening continues through the aggradation stage as the ‘slough line’ develops as an initial site of lower-bank stability. The bank profile develops three dynamic elements (1) vertical face (70° to 90°), (2) upper bank (25° to 50°), and (3) slough line (20° to 25°). Alternate channel bars form during the restabilization stage and represent incipient meandering of the channel.  相似文献   

Hydraulic borehole characterization through the application of moment methods to fluid conductivity logs     

Simon Lw  Van Kelley  Stratis Vomvoris 《Journal of Applied Geophysics》1994,31(1-4)

In any type of groundwater transport problem (contaminant solutes, heat, etc.), knowledge of the location and properties of pathways of increased hydraulic conductivity is essential. However, answering such questions in strongly heterogeneous media, such as fractured rock, can be very difficult and budget-intensive with standard geophysical or hydrogeological field investigations. We present a new testing concept and analysis procedure based on a time sequence of wellbore electric conductivity logs, which provides the exact location and the outflow parameters (transmissivity, formation fluid conductivity) of flowing features (fractures, faults, layers) intercepted by the borehole.Previously the quantitative analysis of this time sequence of electrical conductivity logs was based on a code, called BORE, used to simulate borehole fluid conductivity profiles given these parameters. The present report describes a new direct (not iterative) method for analyzing a short time series of electric conductivity logs which is based on moment quantities of the individual outflow peaks, and applies it to synthetic as well as to field data. The results of the method are promising and are discussed in terms of the method's advantages and limitations. In particular it is shown that the method is capable of reproducing hydraulic properties derived from packer tests well within a factor of three, which is below the range of what is recognized as the accuracy of packer tests themselves. Furthermore the new method is much quicker than the previously used iterative fitting procedure and is even capable of handling transient fracture outflow conditions.  相似文献   

Chernobyl radiocaesium in upland watershed-lake systems,Galloway, south west Scotland     

Simon M. Hutchinson 《Journal of Paleolimnology》1994,10(3):169-180

Levels of Chernobyl radiocaesium found in the upland region of Galloway, south west Scotland were relatively high e.g. catchment mean¹³⁴Cs inventories ranged from 5.72±2.64 kBq m² to 8.72±1.46 kBq m². The nuclear weapons test¹³⁷Cs content of soils and peats was significantly augmented. Accurate assessment of spatial variations and temporal changes in the levels of contamination, however, are inhibited by its marked, short-range heterogeneity. No significant change in mean catchment inventories was detected over a twelve month period. Lake sediment inventories, however, were consistently enhanced from initially lower levels of contamination than their catchments' surfaces. Pre Chernobyl catchment and lake sediment¹³⁷Cs inventories, however, show no such contrast. Both are substantially lower than rainfall based predictions. These observations of the relative levels of Chernobyl and pre-existing radiocaesium in watersheds and their waterbodies have important implications for both the assessment of the catchment and lake residence times of particle-associated contaminants and the use of lake sediment records as monitors of such pollutants.  相似文献   

Serpentinization and infiltration metasomatism in the Trinity peridotite,Klamath province,northern California: implications for subduction zones     

Simon M. Peacock 《Contributions to Mineralogy and Petrology》1987,95(1):55-70

The Trinity peridotite was emplaced over metabasalts and metasedimentary rocks of the central metamorphic belt along the Devonian Trinity thrust zone. Three metamorphic events can be recognized in the Trinity peridotite: (1) antigorite (D= –63 to –65%.) formation related to regional underthrusting of the central metamorphic belt; (2) contact metamorphism associated with Mesozoic dioritic plutons; and (3) late-stage formation of lizardite ± brucite and chrysotile (D= –127 to –175%.) due to infiltration of meteoric waters. Abundant relict phases indicate incomplete reactions and strongly suggest that the availability of H₂O was a controlling factor during serpentinization.Antigorite (event 1) formed as a result of infiltration into the Trinity peridotite of mixed H₂O-CO₂ fluids derived from the underlying central metamorphic belt. Foliation defined by magnetite veins and shear zones within antigorite serpentinites are subparallel to the Trinity thrust. The assemblage Fo + Atg + Chl + Mag ± Tr ± Carb reflects partial hydration of peridotite at 425–570° C. Talc-rich serpentinite formed along the thrust as a result of the infiltration of silica-bearing fluids. Metasomatic mass-balance calculations based on silica solubilities and the extent of antigorite serpentinization suggest that 80–175 volumes of fluid have passed through a given volume of original peridotite at the Trinity thrust.The Trinity thrust probably represents a Devonian subduction zone. Thermodynamic calculations suggest that hydration reactions account for 30–35% of the total heat released by the cooling Trinity peridotite. By analogy, similar hydration reactions are to be expected in the overlying mantle wedge of a subduction zone which act to retard cooling of the hanging wall, just as dehydration reactions delay heating of the downgoing slab. Metasomatic zones formed in peridotite at the Trinity thrust may reflect similar metasomatic processes to those proposed to occur in the mantle wedge above a subducting slab.  相似文献   

Man-induced gradient adjustment of the South Fork Forked Deer River,west Tennessee     

Andrew Simon  Clarence H. Robbins 《Environmental Geology》1987,9(2):109-118

Channel modifications from 1968 to 1969 on the South Fork Forked Deer River in western Tennessee have caused upstream degradation, downstream aggradation, and bank failures along the altered channels, adjacent reaches, and tributaries. The result of these adjustments is a general decrease in gradient as the channel attempts to absorb the imposed increase in energy conditions created by channelization. Headward degradation at a rate of approximately 2.57 km/yr on the South Fork Forked Deer River caused from 1.52 m to about 3.14 m of incision over a 13.5 km reach from 1969 to 1981. As a consequence of substantially increased sediment supply, approximately 2.13 m of aggradation was induced downstream of this reach during the same period. This accumulation represents a 60% recovery of bed level at the downstream site since the completion of channel work in 1969. Gradient adjustment with time is described by exponential decay functions. The length of time required for adjustment to some new quasi-equilibrium condition is computed by these decay functions and is about 20 years from the completion of channel work. Adjusted slopes are less than predisturbed values, probably because straightened channels dissipate less energy by friction, allowing more energy for sediment transport. An equivalent sediment load, therefore, can be transported at a considerably gentler slope. The predisturbed slope exceeds the adjusted slope by an order of magnitude on the downstream reach of the South Fork Forked Deer River.  相似文献   

Pb isotopic composition,colour, and microstructure of monazites from a polymetamorphic rock in Antarctica   总被引：1，自引：0，他引：1  

Lance P. Black  John D. Fitzgerald  Simon L. Harley 《Contributions to Mineralogy and Petrology》1984,85(2):141-148

A moderate- to high-grade regionally metamorphosed paragneiss from Antarctica contains monazites of several different colours — brown, yellow and grey. Each colour type has a distinctive U-Pb isotopic composition which appears to result from different proportions of radiogenic Pb loss. Isotopic differences are neither related to La, Nd, Ce, P, Ca, Ti (and/or Ba), nor to U or Th content. All colour types have similar structures at the submicron scale, as determined by both conventional and high-resolution transmission electron microscopy (TEM). These show that the grains are essenttially non-metamict but are composed of 100 Å crystalline domains misoriented from each other by no more than 2× 10^–3 radians, and separated by narrow confused boundary regions where misorientation is probably accommodated by imperfect atomic arrangements. These regions of mismatch form potential zones of high permeability/diffusivity which are believed to be fundamental to the isotopic and colour differences between grains. Colour type is apparently related to the capacity of different minerals to shield included monazite grains from fluids circulating in the rock system.The well aligned monazite U — Pb analyses produce concordia intercepts of 2429 _–16 ⁺¹⁷ Ma and 1087±29 Ma. Both ages are comparable to those of major geological events in this part of Antarctica. They are interpreted in terms of isotopic resetting through Pb loss, and original monazite crystallisation is thought to have occurred somewhat earlier, possibly at the time this terrain first underwent granulite-facies metamorphism, about 3070 Ma ago.  相似文献   

Coordination of Fe,Ga and Ge in high pressure glasses by Mössbauer,Raman and X-ray absorption spectroscopy,and geological implications     

M.E Fleet  C.T Herzberg  G.S Henderson  E.D Crozier  M.D Osborne  C.M Scarfe 《Geochimica et cosmochimica acta》1984,48(7):1455-1466

Mössbauer spectra of glasses of NaFeSi₃O₈ and 3NaAlSi₂O₆ · NaFeSiO₄ starting compositions consist of a dominant Fe³⁺ and subordinate Fe²⁺ quadrupole-split doublet, in agreement with previous work. Fe³⁺ is assigned to tetrahedral coordination. Pressure-induced coordination changes are not observed in the pressure range 1 bar to 30 kbar. A gradual increase in isomer shift of the Fe³⁺ doublet with increase in pressure is attributed to steric effects. Raman spectra of GeO₂, NaGaSi₃O₈ and NaGaSiO₄ glasses are dominated by network structure vibrations. There is no detectable change in the nearest-neighbor coordination of Ge⁴⁺ in GeO₂ from 1 bar to 14 kbar, of Ga³⁺ in NaGaSi₃O₈ from 1 bar to 28 kbar and of Ga³⁺ in NaGaSiO₄ from 1 bar to 25 kbar. However, some structural reorganization outside of the first coordination sphere occurs in the high pressure glasses.XANES and EXAFS spectra on powdered samples of 1 bar and 25 kbar NaGaSiO₄ glasses and crystalline NaGaSiO₄ were obtained from K edge absorption spectra at the Stanford Synchrotron Radiation Laboratory using a double crystal monochromator equipped with Si(220) crystals. The XANES spectra indicate that Ga³⁺ has a similar extended coordination geometry in both glasses. The EXAFS spectra reveal that Ga³⁺ is four-coordinated with oxygen in all three samples with a Ga³⁺-O distance of about 1.83 Å. The radial distribution functions of the two glasses are virtually identical. However, both XANES and EXAFS spectra indicate significant structural differences between crystalline NaGaSiO₄ (nepheline-type structure) and vitreous NaGaSiO₄ beyond the first coordination shell of Ga³⁺. Thus, X-ray absorption spectroscopy independently confirms the Raman results on the unchanged coordination of Ga³⁺ in NaGaSiO₄ glasses with pressures up to 25 kbar.Glass compositions were selected in anticipation that larger and/or lower charged cations would exhibit pressure-induced coordination changes at lower pressures than Al³⁺ and Si⁴⁺. The present null result suggests that the stabilizing features of open network structures in the liquid state (large entropy and minimized cation-cation repulsion) more than compensate for large molar volume in the pressure range accessible to experimentation. It appears that network structures in natural magmas should remain stable throughout the upper mantle. Consequently, the densities of magmas at high pressures which are calculated from compressibility data and the appropriate equation of state will be only slightly underestimated, due to the effect of minor structural changes beyond the first coordination sphere.  相似文献   

Mössbauer investigation of niningerite solid solutions (Mg,Fe)S     

Margery D. Osborne  Michael E. Fleet 《Physics and Chemistry of Minerals》1984,10(6):245-249

⁵⁷Fe Mössbauer spectra of (Mg,Fe)S solid solutions (niningerite) quenched from 1,000° C exhibit a singlet only within the composition range 8.4 to 50.0 mol. percent FeS. The isomer shift decreases progressively with increasing FeS content (from 0.99 to 0.95 mm/s) and extrapolates to a value of about 0.9 mm/s for FeS (halite structure), in close agreement with the isomer shift for FeS (troilite). Line width increases progressively with increasing FeS content (from 0.32 to 0.47 mm/s) and with decreasing temperature. The broadened singlet spectrum is interpreted as an unresolved composite quadrupole split doublet, which is attributed to local site distortion by next-nearest neighbor cation substitution. The ground state splitting is estimated to be 40 cm^?1 in (Mg_0.5Fe_0.5)S. The next-nearest neighbor effect in niningerite is anomalously small compared to that observed in spinel and (Mg,Fe)O compositions.  相似文献   

Ultraviolet absorption spectrum of trifluoro-bromo-methane,difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase     

D. Gillotay  P. C. Simon 《Journal of Atmospheric Chemistry》1989,8(1):41-62

Ultraviolet absorption cross-sections of trifluoro-bromo-methane (CF₃Br-Halon 1301), difluoro-dibromo-methane (CF₂Br₂-Halon 1202) and of difluoro-bromo-chloro-methane (CF₂BrCl-Halon 1211) are measured in the wavelength interval 172–304 nm for temperatures ranging from 210 to 295 K with uncertainties of between 2 and 4%. They are compared with previous measurements available at room temperature. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-sections for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.  相似文献