Comparability of Large-Scale Studies of Agricultural Chemical Contamination of Rural Private Wells   总被引：1，自引：0，他引：1  

Chittaranjan Ray  Susan C. Schock 《Ground Water Monitoring & Remediation》1996,16(2):92-102

Detection of agricultural chemicals in ground water has prompted numerous studies. Federal, state, and regional studies were conducted in the last 10 years in order to assess the occurrence of agricultural chemicals in ground water. The results of the studies present the number or percentage of samples with agricultural chemicals above the drinking water standard or health advisory levels as well as samples with detections of one or more compounds. Data comparison from one state or region to another are frequently referred to by regulatory and agency personnel involved in water quality and agriculture issues. Unless the history of pesticide use, method of chemical analyses, detection limits, statistical design of the sampling plan, well type, well depth, geology of the formation material, and typical land use around the wellhead are known, such comparisons can be misleading. Reporting the limitations or presenting a disclaimer should be a key element for a study so that "apples and oranges" are not compared.  相似文献   

Helium isotope geochemistry of mid-ocean ridge basalts from the South Atlantic     

David W. Graham  William J. Jenkins  Jean-Guy Schilling  Geoffrey Thompson  Mark D. Kurz  Susan E. Humphris 《Earth and Planetary Science Letters》1992,110(1-4):133-147

We report new helium isotope results for 49 basalt glass samples from the Mid-Atlantic Ridge between 1°N and 47°S.³He/⁴He in South Atlantic mid-ocean ridge basalts (MORB) varies between 6.5 and 9.0 R_A (R_A is the atmospheric ratio of1.39 × 10⁻⁶), encompassing the range of previously reported values for MORB erupted away from high³He/⁴He hotspots such as Iceland. He, Sr and Pb isotopes show systematic relationships along the ridge axis. The ridge axis is segmented with respect to geochemical variations, and local spike-like anomalies in³He/⁴He, Pb and Sr isotopes, and trace element ratios such as(La/Sm)_N are prevalent at the latitudes of the islands of St. Helena, Tristan da Cunha and Gough to the east of the ridge. The isotope systematics are consistent with injection beneath the ridge of mantle “blobs” enriched in radiogenic He, Pb and Sr, derived from off-axis hotspot sources. The variability in³He/⁴He along the ridge can be used to refine the hotspot source-migrating-ridge sink model.

MORB from the 2–7°S segment are systematically the least radiogenic samples found along the mid-ocean ridge system to date. Here the depleted mantle source is characterized by⁸⁷Sr/⁸⁶Sr of 0.7022, Pb isotopes close to the geochron and with²⁰⁶Pb/²⁰⁴Pb of 17.7, and³He/⁴He of 8.6–8.9 R_A. The “background contamination” of the subridge mantle, by radiogenic helium derived from off-ridge hotspots, displays a maximum between 20 and 24°S. The HePb and HeSr isotope relations along the ridge indicate that the³He/⁴He ratios are lower for the hotspot sources of St. Helena, Tristan da Cunha and Gough than for the MORB source, consistent with direct measurements of³He/⁴He ratios in the island lavas. Details of the HeSrPb isotope systematics between 12 and 22°S are consistent with early, widespread dispersion of the St. Helena plume into the asthenosphere, probably during flattening of the plume head beneath the thick lithosphere prior to continental breakup. The geographical variation in theHe/Pbratio deduced from the isotope systematics suggests only minor degassing of the plume during this stage. Subsequently, it appears that the plume component reaching the mid-Atlantic ridge was partially outgassed of He during off-ridge hotspot volcanism and related melting activity.

Overall, the similar behavior of He and Pb isotopes along the ridge indicates that the respective mantle sources have evolved under conditions which produced related He and Pb isotope variations.  相似文献   

Textural analysis and modelling of a flood deposit: River severn,U.K.     

Susan Marriott 《地球表面变化过程与地形》1992,17(7):687-697

Samples of sediment collected from the Severn floodplain between Worcester and Gloucester following the severe flooding in January and February 1990, were analysed for their grain size distribution. The results show that most sand was deposited within 20 m of the channel bank, but that fine sand may contribute to flood sediment across the width of the floodplain. James' (1985) numerical model of overbank sedimentation attempts to predict the transfer of sediment to the floodplain during flooding. Geometrical and hydraulic data relating to the Severn flood are used as input for a computer program of James' (1985) model. The pattern of sediment concentrations predicted by the model was compared with that obtained from statistical analysis of the flood sediment. The patterns were found to be similar, so James' (1985) model was considered to predict in a relative sense the distribution of flood sediment.  相似文献   

Book reviews     

Kerry Kelts  Patrick De Deckker  Françoise Gasse  Susan K. Short 《Journal of Paleolimnology》1992,7(2):173-178

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Reducing standard errors by incorporating spatial autocorrelation into a measurement scheme for soil carbon credits     

Siân Mooney  Ken Gerow  John Antle  Susan Capalbo  Keith Paustian 《Climatic change》2007,80(1-2):55-72

Several studies have suggested that geostatistical techniques could be employed to reduce overall transactions costs associated with contracting for soil C credits by increasing the efficacy of sampling protocols used to measure C-credits. In this paper, we show how information about the range of spatial autocorrelation can be used in a measurement scheme to reduce the size of the confidence intervals that bound estimates of the mean number of C-credits generated per hectare. A tighter confidence interval around the mean number of C-credits sequestered could increase producer payments for each hectare enrolled in a contract to supply C-credits. An empirical application to dry land cropping systems in three regions of Montana shows that information about the spatial autocorrelation exhibited by soil C could be extremely valuable for reducing transactions costs associated with contracts for C-credits but the benefits are not uniform across all regions or cropping systems. Accounting for spatial autocorrelation greatly reduced the standard errors and narrowed the confidence intervals associated with sample estimates of the mean number of C-credits produced per hectare. For the payment mechanism considered in this paper, tighter confidence intervals around the mean number of C-credits created per hectare enrolled could increase producer payments by more than 100 percent under a C-contract.  相似文献   

Evaluation of vegetative criteria for near-surface groundwater detection using multispectral mapping and GIS techniques in semi-arid Botswana     

Susan Ringrose  Cornelis Vanderpost  Wilma Matheson 《Applied geography (Sevenoaks, England)》1998,18(4):331-354

The critical need to consider all options in the search for groundwater in semi-arid areas has promoted work on the possible association of near-surface groundwater and vegetation characteristics using a combination of remote-sensing data and geographic information systems (GIS) techniques. Two vegetative criteria (dense woody cover and abundance of deep-rooting species) are identified as being indicative of near-surface groundwater, and their spatial distribution is tested against the location of aquifers in southeast Botswana. Vegetative criteria classes were combined in a GIS environment with the distribution of geomorphic units and bedrock geology to determine the degree of coincidence with assumed or known aquifers. Results indicate that the distribution of dense woody vegetation as mapped from Thematic Mapper imagery has some potential in identifying especially surficial but also bedrock near-surface groundwater sources in mostly naturally vegetated semi-arid areas. Dense woody cover classes tend to select aquifers in topographically higher areas while classes comprising some deep-rooting species tend to select low-lying aquifers such as those occurring in fossil valleys. Deep-rooting species, however, are less successful as a vegetative criterion. Although various technical refinements are suggested, this work shows that vegetative criteria mapping can however be used in conjunction with conventional geological/geophysical techniques to enhance the prospects for groundwater location in relatively undisturbed semi-arid areas.  相似文献   

Thecamoebians in Lake Winnipeg: a tool for Holocene paleolimnology     

Susan M. Burbidge  Claudia J. Schröder-Adams 《Journal of Paleolimnology》1998,19(3):309-328

Holocene sediments in Lake Winnipeg are expressed in the lower Lake Agassiz sequence which is unconformably overlain by the Lake Winnipeg sequence. Nine sites, covering the North and South basins and the connecting Narrows, were selected for analysis of Holocene changes in thecamoebian faunae. Only the Lake Winnipeg sequence contains thecamoebians. This study indicates that biologic productivity and consequently the type of organic material in the sediments is the main control on thecamoebian taxa in Lake Winnipeg. Other factors controlling the distribution of thecamoebians are water chemistry and turbidity. Inorganic sediment geochemistry and water temperature do not appear to significantly influence the thecamoebian fauna of Lake Winnipeg. Variations in the abundance of key thecamoebian species along a north-south transect divide Lake Winnipeg into three distinct areas. The North Basin has remained relatively unchanged since the retreat of Lake Agassiz as indicated by the domination of Difflugia manicata throughout its history. This species appears to prefer Cyanophyta and diatoms as its food source. In the Narrows harsh conditions created by turbid waters and lack of algal food taxa result in Centropyxis aculeata replacing Difflugia manicata as the dominant species. In the South Basin three thecamoebian assemblages are recognized. Cucurbitella tricuspis, indicative of eutrophic conditions, dominates the most recent sediments of the South Basin. The underlying sediments are characterized by Difflugia globulus. In Lake Winnipeg this species is not a cold climate (arctic) indicator as suggested elsewhere but instead seems to prefer sediments containing green and yellow-green algal material. A Centropyxis-Arcella Assemblage occurs only at the base of the southernmost core where it is indicative of an early phase of hyposaline conditions as developed in shallow pools during the southward transgression of Lake Winnipeg. This study illustrates the usefulness of thecamoebians as paleolimnological indicators. Environmental changes are more significant in the restricted South Basin resulting in distinct thecamoebian assemblages. In contrast, the North Basin provided a stable environment throughout the late Holocene reflected in only subtle faunal changes.  相似文献   

A general mixing equation with applications to Icelandic basalts   总被引：4，自引：0，他引：4  

Charles H. Langmuir  Robert D. Vocke  Gilbert N. Hanson  Stanley R. Hart 《Earth and Planetary Science Letters》1978,37(3):380-392

The mixing equation applied by Vollmer [1] to Pb and Sr isotope ratios is shown to be a general equation applicable to consideration of element and isotope ratios. The mixing equation is hyperbolic and has the form:Ax + Bxy + Cy + D = 0where the coefficients are dependent on the type of plot considered: i.e. ratio-ratio, ratio-element, or element-element. Careful use of this equation permits testing whether mixing is a viable process, places constraints on end member compositions, allows distinction between mixing of sources and mixing of magmas, and should allow distinction between recent mixing and long-term evolution of sources.The available chemical data for postglacial basalts from Iceland and along the Reykjanes Ridge are not consistent with either mixing of magmas or simple mixing of an enriched ocean island source with a depleted ocean ridge source. If the available analyses for basalts are representative of the source regions, the data are consistent with at least two models neither of which can be properly tested with the available data.(1) There are two separate mixing trends: one beneath Iceland with the alkali basalt source and a depleted Iceland source as end members; the second along the Reykjanes Ridge with a heterogeneous ocean ridge basalt source and a source similar to that for intermediate basalts on Iceland as end members. The depleted Iceland source and the depleted ocean ridge source are not the same.(2) The chemistry of the basalts is not determined by mixing. Instead the basalts are derived from a multiplicity of sources with a similar history which have been isolated for hundreds of millions of years.  相似文献   

Modelling of major elements in mantle-melt systems using trace element approaches   总被引：1，自引：0，他引：1  

Gilbert N. Hanson  Charles H. Langmuir 《Geochimica et cosmochimica acta》1978,42(6):725-741

Major elements can be modelled in ways similar to the quantitative petrogenetic modelling used for trace elements. In contrast to modelling with trace elements, however, modelling with major elements is constrained by the stoichiometry of the solid phases. Within these constraints, the same equations for partial melting and crystallization which have been used to such advantage for trace elements may be used for major elements.Calculated MgO and FeO abundances in a mantle-melt system are used as an example of the modelling technique. Such modelling yields limited fields of permissible melts and residues for a given parent composition, but does not give the paths of melting. It does allow the temperature and extent of melting which gave rise to a melt to be determined from the MgO and FeO abundances of the melt or residual solid. Applying the results of the modelling to igneous rocks and ultramafic nodules leads to the following conclusions, which are subject to the uncertainties in the available distribution coefficients. Least differentiated basalt glasses from the ocean floor are derived from parent melts with less than 15.5 weight % MgO and 8.2 wt. % FeO. Komatiites may be derived by less than 60% melting of a pyrolite source leaving a residue of olivine and pyroxene. Many nodules from the subcontinental mantle appear to be residues of large fractions of melting (>30%) at high temperature and pressure, whereas ultramafic nodules from oceanic basalts appear to be residues of smaller fractions of melting (<30%) at lower temperatures and pressures.  相似文献   

Plagiogranites as late-stage immiscible liquids in ophiolite and mid-ocean ridge suites: An experimental study   总被引：1，自引：0，他引：1  

Susan Dixon  M.J. Rutherford 《Earth and Planetary Science Letters》1979,45(1):45-60

Chemical studies of two ophiolite suites and of selected mid-oceanic rift (MOR) regions indicate the presence of certain magmatic compositions: basalt, Fe-enriched basalt, and sodium granite (plagiogranite). There is a notable lack of evidence for melts of intermediate composition (i.e. 50–60 wt.% SiO₂). To determine possible relationships between basic rocks (basalts and gabbros) and acidic rocks (plagiogranites) a primitive basalt was fractionated at low pressure, under anhydrous conditions, and at different oxygen fugacities near the iron-wustite buffer and slightly above the quartz-fayalite-magnetite buffer. Samples of this basalt were taken to slightly above liquidus temperatures and then cooled at rates ranging from 1 to 2°C/hr. A liquid line of descent characterized by an Fe enrichment was delineated by quenching these experiments from a final temperature in the range of 1200 to 1000°C and analyzing the residual liquid (glass). After 95% crystallization of olivine, plagioclase, calcium pyroxene, and ilmenite, the residual liquid was an Fe-enriched basalt. This Fe-enriched basalt became immiscible at a temperature of about 1010°C. The immiscible phases produced were a more Fe-enriched basaltic liquid and a granitic liquid. The granitic liquid is similar in composition to the naturally occurring plagiogranites found in small volumes in ophiolites and in certain MOR regions. It is therefore concluded that silicate liquid immiscibility could be the petrogenetic process responsible for producing plagiogranite in some MOR regions and in some ophiolites. On the other hand, plagiogranites in ophiolites and MOR rock suites having andesitic and dacitic composition rocks may have evolved under conditions more closely approximating equilibrium crystallization and/or they may have evolved at high water pressures. The available experimental data suggest that amphibole would crystallize early and yield SiO₂-enriched liquids at depths greater than 4.5 km for P_H2O's in the range 0.6–1.0 P_total.The major problem in interpreting any of the natural plagiogranites as products of silicate liquid immiscibility is the fact that neither the Fe-enriched conjugate liquid or its crystalline equivalent has been described in the ophiolite or MOR literature. The identification of this Fe-rich conjugate magma is essential in any rock suite if a completely convincing case for silicate liquid immiscibility is to be made.  相似文献