Formation of Al-rich titanite (CaTiSiO₄O–CaAlSiO₄OH) reaction rims on ilmenite in metamorphic rocks as a function of fH₂O and fO₂     

Daniel Harlov  Peter Tropper  Wolfgang Seifert  Timo Nijland  Hans-Jürgen Frster 《Lithos》2006,88(1-4):72-84

Reaction rims of titanite on ilmenite are described in samples from four terranes of amphibolite-facies metapelites and amphibolites namely the Tamil Nadu area, southern India; the Val Strona area of the Ivrea-Verbano Zone, northern Italy, the Bamble Sector, southern Norway, and the northwestern Austroalpine Ötztal Complex. The titanite rims, and hence the stability of titanite (CaTiSiO₄O) and Al–OH titanite, i.e. vuaganatite (hypothetical end-member CaAlSiO₄OH), are discussed in the light of fH₂O- and fO₂-buffered equilibria involving clinopyroxene, amphibole, biotite, ilmenite, magnetite, and quartz in the systems CaO–FeO/Fe₂O₃–TiO₂–SiO₂–H₂O–O₂ (CFTSH) and CaO–FeO/Fe₂O₃–Al₂O₃–SiO₂–H₂O–O₂ (CFASH) present in each of the examples. Textural evidence suggests that titanite reaction rims on ilmenite in rocks from Tamil Nadu, Val Strona, and the Bamble Sector originated most likely due to hydration reactions such as clinopyroxene + ilmenite + quartz + H₂O = amphibole + titanite and oxidation reactions such as amphibole + ilmenite + O₂ = titanite + magnetite + quartz + H₂O during amphibolite-facies metamorphism, or, as in the case of the Ötztal Complex, during a subsequent greenschist-facies overprint. Overstepping of these reactions requires fH₂O and fO₂ to be high for titanite formation, which is also in accordance with equilibria involving Al–OH titanite. This study shows that, in addition to P, T, bulk–rock composition and composition of the coexisting fluid, fO₂ and fH₂O also play an important role in the formation of Al-bearing titanite during amphibolite- and greenschist-facies metamorphism.  相似文献   

Geophysics of sea ice in the Baltic Sea: A review     

Timo Vihma  Jari Haapala   《Progress in Oceanography》2009,80(3-4):129-148

With improved observation methods, increased winter navigation, and increased awareness of the climate and environmental changes, research on the Baltic Sea ice conditions has become increasingly active. Sea ice has been recognized as a sensitive indicator for changes in climate. Although the inter-annual variability in the ice conditions is large, a change towards milder ice winters has been detected from the time series of the maximum annual extent of sea ice and the length of the ice season. On the basis of the ice extent, the shift towards a warmer climate took place in the latter half of the 19th century. On the other hand, data on the ice thickness, which are mostly limited to the land-fast ice zone, basically do not show clear trends during the 20th century, except that during the last 20 years the thickness of land-fast ice has decreased. Due to difficulties in measuring the pack-ice thickness, the total mass of sea ice in the Baltic Sea is, however, still poorly known. The ice extent and length of the ice season depend on the indices of the Arctic Oscillation and North Atlantic Oscillation. Sea ice dynamics, thermodynamics, structure, and properties strongly interact with each other, as well as with the atmosphere and the sea. The surface conditions over the ice-covered Baltic Sea show high spatial variability, which cannot be described by two surface types (such as ice and open water) only. The variability is strongly reflected to the radiative and turbulent surface fluxes. The Baltic Sea has served as a testbed for several developments in the theory of sea ice dynamics. Experiences with advanced models have increased our understanding on sea ice dynamics, which depends on the ice thickness distribution, and in turn redistributes the ice thickness. During the latest decade, advance has been made in studies on sea ice structure, surface albedo, penetration of solar radiation, sub-surface melting, and formation of superimposed ice and snow ice. A high vertical resolution has been found as a prerequisite to successfully model thermodynamic processes during the spring melt period. A few observations have demonstrated how the river discharge and ice melt affect the stratification of the oceanic boundary layer below the ice and the oceanic heat flux to the ice bottom. In general, process studies on ice–ocean interaction have been rare. In the future, increasingly multidisciplinary studies are needed with close links between sea ice physics, geochemistry and biology.  相似文献   

Photometric modeling of Saturn's rings: I. Monte Carlo method and the effect of nonzero volume filling factor     

Heikki Salo  Raine Karjalainen 《Icarus》2003,164(2):428-460

The scattering properties of particulate rings with volume filling factors in the interval D=0.001-0.3 are studied, with photometric Monte Carlo ray tracing simulations combining the advantages of direct (photons followed from the source) and indirect methods (brightness as seen from the observing direction). Besides vertically homogeneous models, ranging from monolayers to classical many-particle thick rings, particle distributions obtained from dynamical simulations are studied, possessing a nonuniform vertical profile and a power law distribution of particle sizes. Self-gravity is not included to assure homogeneity in planar directions. Our main goal is to check whether the moderately flattened ring models predicted by dynamical simulations (with central plane D>0.1) are consistent with the basic photometric properties of Saturn's rings seen in ground-based observations, including the brightening near zero phase angle (opposition effect), and the brightening of the B-ring with increasing elevation angle (tilt effect). Our photometric simulations indicate that dense rings are typically brighter in reflected light than those with D→0, due to enhanced single scattering. For a vertically illuminated layer of identical particles this enhancement amounts at intermediate viewing elevations to roughly 1+2D. Increased single scattering is also obtained for low elevation illumination, further augmented at low phase angles α by the opposition brightening when D increases: the simulated opposition effect agrees very well with the Lumme and Bowell (1981, Astron. J. 86, 1694-1704) theoretical formula. For large α the total intensity may also decrease, due to reduced amount of multiple scattering. For the low (α=13°) and high (α=155°) phase angle geometries analyzed in Dones et al. (1993, Icarus 105, 184-215) the brightness change for D=0.1 amounts to 20% and −17%, respectively. In the case of an extended size distribution, dynamical simulations indicate that the smallest particles typically occupy a layer several times thicker than the largest particles. Even if the large particles form a dynamically dense system, a narrow opposition peak can arise due to mutual shadowing among the small particles: for example, a size distribution extending about two decades can account for the observed about 1° wide opposition peak, solely in terms of mutual shadowing. The reduced width of the opposition peak for extended size distribution is in accordance with Hapke's (1986, Icarus 67, 264-280) treatment for semi-infinite layers. Due to vertical profile and particle size distribution, the photometric behavior is sensitive to the viewing elevation: this can account for the tilt-effect of the B-ring, as dense and thus bright central parts of the ring become better visible for larger elevation, whereas in the case of smaller elevation, mainly low volume density upper layers are visible. Since multiple scattering is not involved, the explanation works also for albedo well below unity. Inclusion of nonzero volume density helps also to model some of the Voyager observations. For example, the discrepancy between predicted and observed brightness at large phase angles for much of the A-ring (Dones et al., 1993, Icarus 105, 184-215) is removed when the enhanced low α single scattering and reduced large α multiple scattering is allowed for. Also, a model with vertical thickness increasing with saturnocentric distance offers at least a qualitative explanation for the observed contrast reversal between the inner and outer A-ring in low and high phase Voyager images. Differences in local size distribution and thus on the effective D may also account for the contrast reversal in resonance sites.  相似文献   

Environmental Geology     

Reijo Salminen Anne Kousa Rolf Tore Ottesen Olle Selinus Eiliv Steinnes Timo Tarvainen Bjoern OEhlander 《《幕》》2008,31(1):155-162

The mining environment, medical geology and urban geochemistry form a group of related scientific disciplines that have developed strongly during recent years in the Nordic countries. Modern legislation controls the environmental issues. Close co-operation of researchers and legislators has improved the quality and safety of life in the societies of the Nordic countries. In mining environmental studies, methods that are suitable in Arctic conditions have been developed; in medical geology, the input from the Nordic countries has made it an appreciated scientific discipline throughout the world, and in the case of the urban environment, methods developed by our geochemists have especially improved the health conditions, particularly of children.  相似文献   

On the Factors Controlling the Snow Surface and 2-m Air Temperatures Over the Arctic Sea Ice in Winter     

Timo?VihmaEmail author  Roberta?Pirazzini 《Boundary-Layer Meteorology》2005,117(1):73-90

Factors controlling the magnitudes of, and short-term variations in, the potential temperatures of the snow surface and the air at the height of 2 m θ_S and θ_{2 m} over Arctic sea ice in winter are analysed. The study addresses the winters of 1986–1987 and 1987–1988, and is based on the temperature, wind, and cloud observations made by Russian drifting ice stations. It also relies on the ERA40 re-analyses of the European Centre for Medium-Range Weather Forecasts, which were utilised to calculate the lateral heat advection at the sites of the ice stations. The cloud cover and wind speed were more important than the heat advection in controlling the magnitudes of θ_{2 m} and θ_S, while on a time scale of 24 h, during steady forcing conditions, the heat advection was the most important factor affecting the changes in θ_S and θ_{2 m}. During changing conditions, and considering individual factors separately, the monthly mean 24-h temperature changes were less than ± 5 °C: the effect of the cloud cover was the largest, and that of the heat advection was the smallest. When simultaneous changes in the three factors were analysed, the seasonal mean temperature changes were even of the order of ±15 °C, with the strongest warming events exceeding 35 K in a single day. The difference θ_S − θ_{2 m} reached its lowest seasonal mean values during conditions of clear skies (−1.3 °C), light winds (−1.3 °C) and warm-air advection (−0.8 °C). θ_S and θ_{2 m} followed each other closely, even during major synoptic-scale temperature variations.  相似文献   

A Modelling Approach For Optimizing Flight Patterns In Airborne Meteorological Measurements     

Timo Vihma  Christoph Kottmeier 《Boundary-Layer Meteorology》2000,95(2):211-230

A method is presented for selecting the optimal flight patterns for airbornemeteorological measurements in various flow situations. The method is basedon systematic utilisation of mesoscale model fields. Flow overan Arctic sea-ice boundary zone is modelled, and it is assumed that the mesoscale model fields represent the true state of the atmosphere, and that each possible flight pattern yields a different sample of the true fields. A plan for the basic structure of the flight pattern is assumed, and then the unexplained variance, i.e., the difference between the true variance and the sample variance, of a quantity of interest is calculated for a variety of possible flight patterns. Different target quantities are considered, such as wind speed, air temperature, and the turbulent fluxesof momentum and sensible heat. The optimal flight pattern is defined byminimisation of the unexplained variance, and often depends on the quantitywe are interested in. For sawtooth patterns, the optimal flight pattern was sensitive to the maximum ascent angle of the aircraft. In flight patterns designed for turbulence measurements, the optimal pattern was different for the unexplained variance of the turbulent fluxes and for the unexplained total heat content of the convective layer.  相似文献   

Damage‐viscoplastic consistency model for rock fracture in heterogeneous rocks under dynamic loading     

Timo Saksala 《国际地质力学数值与分析法杂志》2010,34(10):1041-1062

This paper presents a damage‐viscoplastic consistency model for numerical simulation of brittle fracture in heterogeneous rocks. The model is based on a combination of the recent viscoplastic consistency model by Wang and the isotropic damage concept with separate damage variables in tension and compression. This approach does not suffer from ill‐posedness, caused by strain softening, of the underlying boundary/initial value problem since viscoplasticity provides the regularization by introducing a length scale effect under dynamic loading conditions. The model uses the Mohr–Coulomb yield criterion with the Rankine criterion as a tensile cut‐off. The damage law in compression is calibrated via the degradation index concept of Fang and Harrison. Thereby, the model is able to capture the brittle‐to‐ductile transition occurring in confined compression at a certain level of confinement. The heterogeneity of rock is accounted for by the statistical approach based on the Weibull distribution. Numerical simulations of confined compression test in plane strain conditions demonstrate a good agreement with the experiments at both the material point and structural levels as the fracture modes are realistically predicted. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Footprint Evaluation for Flux and Concentration Measurements for an Urban-Like Canopy with Coupled Lagrangian Stochastic and Large-Eddy Simulation Models   总被引：1，自引：1，他引：0  

Antti Hellsten  Sofia-M. Luukkonen  Gerald Steinfeld  Farah Kanani-Sühring  Tiina Markkanen  Leena Järvi  Juha Lento  Timo Vesala  Siegfried Raasch 《Boundary-Layer Meteorology》2015,157(2):191-217

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Use of ALS, Airborne CIR and ALOS AVNIR-2 data for estimating tropical forest attributes in Lao PDR     

Zhengyang Hou  Qing Xu  Timo Tokola 《ISPRS Journal of Photogrammetry and Remote Sensing》2011,66(6):776-786

In this study, the potential of remote sensing in tropical forests is examined in relation to the diversification of sensors. We report here on the comparison of alternative methods that use multisource data from Airborne Laser Scanning (ALS), Airborne CIR and ALOS AVNIR-2 to estimate stem volume and basal area, in Laos. Multivariate linear regression analyses with stepwise selection of predictors were implemented for modelling. The predictors of ALS metrics were calculated by means of the canopy height distribution approach, while predictors from both spectral and textual features were respectively generated for Airborne CIR and ALOS AVNIR-2 data. With respect to the estimation capacity from individual data sources after leave-one-out cross-validation, the ALS data proved superior, with the lowest RMSE of 36.92% for stem volume and 47.35% for basal area, whereas Airborne CIR and ALOS AVNIR-2 remained at similar accuracy levels, but fell well behind the ALS data. By integrating ALS metrics with other predictors from Airborne CIR or ALOS AVNIR-2, hybrid modelling was further tested respectively. The results showed that only the hybrid model for stem volume involving ALS and Airborne CIR improved the accuracy of 1.9% in terms of relative RMSE than that of using ALS alone.  相似文献   

Intra-City Variation in Urban Morphology and Turbulence Structure in Helsinki, Finland   总被引：3，自引：3，他引：0  

Annika Nordbo  Leena Järvi  Sami Haapanala  Joonas Moilanen  Timo Vesala 《Boundary-Layer Meteorology》2013,146(3):469-496

Most atmospheric boundary-layer theories are developed over vegetative surfaces and their applicability at urban sites is questionable. Here, we study the intra-city variation of turbulence characteristics and the applicability of boundary-layer theory using building-morphology data across Helsinki, and eddy-covariance data from three sites: two in central Helsinki (400 m apart) and one 4 km away from the city centre. The multi-site measurements enable the analysis of the horizontal scales at which quantities that characterize turbulent transport vary: (i) Roughness characteristics vary at a 10-m scale, and morphometric estimation of surface-roughness characteristics is shown to perform better than the often used rule-of-thumb estimates (average departures from the logarithmic wind profile are 14 and 44 %, respectively). (ii) The drag coefficient varies at a 100-m scale, and we provide an updated parametrization of the drag coefficient as a function of z/z _H (the ratio of the measurement height to the mean building height). (iii) The transport efficiency of heat, water vapour and CO₂ is shown to be weaker the more heterogeneous the site is, in terms of sources and sinks, and strong scalar dissimilarity is observed at all sites. (iv) Atmospheric stability varies markedly even within 4 km across the city: the median difference in nocturnal sensible heat fluxes between the three sites was over 50W m^?2. Furthermore, (v) normalized power spectra and cospectra do not vary between sites, and they follow roughly the canonical theory as developed over vegetated terrain.  相似文献