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61.
This work is immediate continuation of Part I, using an identical method and evaluation for kinetic studies. The systems chalcocite-ethylene diamine tetra-acetic acid and chalcocite-ethylene diamine were studied. It was necessary to refine the geometrical model method for chalcocite in order to establish dissolution kinetics of polydispersions. This work confirms that chalcocite leaching proceeds through covellite even in the medium of complex-forming agents and kinetic equations for both leaching stages were evaluated with an attempt at physical interpretation.  相似文献   
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We introduce a new computational model designed to simulate and investigate reach-scale alluvial dynamics within a landscape evolution model. The model is based on the cellular automaton concept, whereby the continued iteration of a series of local process ‘rules’ governs the behaviour of the entire system. The model is a modified version of the CAESAR landscape evolution model, which applies a suite of physically based rules to simulate the entrainment, transport and deposition of sediments. The CAESAR model has been altered to improve the representation of hydraulic and geomorphic processes in an alluvial environment. In-channel and overbank flow, sediment entrainment and deposition, suspended load and bed load transport, lateral erosion and bank failure have all been represented as local cellular automaton rules. Although these rules are relatively simple and straightforward, their combined and repeatedly iterated effect is such that complex, non-linear geomorphological response can be simulated within the model. Examples of such larger-scale, emergent responses include channel incision and aggradation, terrace formation, channel migration and river meandering, formation of meander cutoffs, and transitions between braided and single-thread channel patterns. In the current study, the model is illustrated on a reach of the River Teifi, near Lampeter, Wales, UK.  相似文献   
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The problem is not uncertainty—proposed here as an inevitable condition—but the chimera of certainty asserted by most contemporary researchers. Problems of data definition, collection, and their use are reviewed in terms of spatial epidemiology and health data with examples drawn from several areas of contemporary health research. The argument is that preconceptions limit data modeled in a manner assuming its completeness. The result, as the West Nile Virus example seeks to demonstrate, may obscure other patterns and limit avenues of research.  相似文献   
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A New Lichenometric Dating Curve For Southeast Iceland.   总被引:2,自引:0,他引:2  
This paper presents a new lichenometric dating curve for southeast Iceland. The temporal framework for the curve is based on reliably dated surfaces covering the last 270 years, making it the best constrained study of this nature conducted in Iceland. The growth of lichen species within Rhizocarpon Section Rhizocarpon is non-linear over time, with larger (older) thalli apparently growing more slowly. The linear 'growth' curves derived previously by former authors working in Iceland represent only part of a curve which has an overall exponential form. Reasons for the non-linearity of the new dating curve are probably physiological, although climatic change over the last three centuries cannot be ruled out. Use of linear 'growth' curves in Iceland is problematic over time-spans of more than c . 80 years. Pre-20th century moraines dated using a constant, linear relationship between lichen size and age are probably older than previously believed. Those moraines lichenometrically 'dated' to the second half of the 19th century in Iceland may actually pre-date this time by several decades (30–100 years), thus throwing doubt on the exact timing of maximum glaciation during the 'Little Ice Age'.  相似文献   
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Recent mixed-layer formulations for computing large-scale surface energy fluxes under daytime convective conditions do not require the estimation of surface-layer parameters, such as the roughness lengths for momentum and heat. This greatly simplifies approaches using operational satellite measurements of surface temperature for computing the surface energy balance at regional scales because the surface roughness parameters are not well known for many landscapes. The utility of such mixed-layer formulations is tested using data from several recent multidisciplinary field experiments (HAPEX-MOBILHY, FIFE and Monsoon 90). The results indicate that specific mixed-layer formulations adequately simulate surface sensible heat fluxes in the grassland and shrubland sites. However, use of the original values of proposed empirical coefficients for the forested site yield poor results. This is probably due to the fact that the forested site has significantly different surface geometry and associated distribution of temperature among the surface components (especially the relative importance of soil background temperatures) compared to the other sites. Therefore, the relationship between aerodynamic and radiometric surface temperature may have greatly differed between the forested site and the other locations. However, differences in aerodynamic roughness between the experimental sites were not correlated with changes required in the values of the coefficients. Instead, a two-source model which makes the distinction between aerodynamic and radiative temperature is proposed, as a means to determine which surface properties significantly affect the magnitude of the mixed-layer coefficients.  相似文献   
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