Accumulation of total CO₂ during stagnation in the Baltic Sea deep water and its relationship to nutrient and oxygen concentrations     

B. Schneider  G. Nausch  H. Kubsch  I. Petersohn 《Marine Chemistry》2002,77(4)

Accumulation of total CO₂ (C_T) was investigated in the sub-halocline deep water of the Gotland Sea (Baltic Sea) during a period of stagnation from 1995 to 1999. Depth profiles for C_T, nitrate, phosphate, and oxygen were measured during seven cruises in a grid consisting of 26 stations. The mean C_T increased by more than 60 μmol/kg from October 1995 to July 1999 corresponding to a mean accumulation rate of 1.1 mol/m² year. Taking into account vertical mixing, the vertical distribution of the C_T accumulation was used to determine mineralization rates at different depths. High rates immediately below the halocline indicated the existence of a fraction of organic matter, which is rapidly mineralized during sinking through the water column. A second fraction is more refractive and accumulates at the sediment surface in the deep center of the basin where it is slowly mineralized and partly buried. Phosphate release rates in anoxic waters and especially at the redoxcline were substantially higher than those estimated on the basis of the carbon mineralization and the Redfield C/P ratio. This is attributed to non-Redfield mineralization ratios and the dissolution of iron oxide/phosphate associates. The formation of nitrate by mineralization under oxic conditions was almost completely compensated by denitrification. Using the carbon mineralization rates and a C/N ratio of 8.4, a denitrification rate of 280 mmol/m² year was obtained, which approximately balances the input of nitrate/ammonia into the surface water. Relating the apparent oxygen utilization (AOU) to the C_T fraction that was generated by mineralization yielded a carbon mineralization/O₂ consumption ratio of 0.83.  相似文献   

Spatial dynamics of anchovy, sardine, and hake pre-recruit stages in the California Current     

Smith  P. E.; Horne  J. K.; Schneider  D. C. 《ICES Journal of Marine Science》2001,58(5):1063-1071

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Parameterization of spectral distributions for pion and kaon production in proton-proton collisions     

Schneider JP  Norbury JW  Cucinotta FA 《The Astrophysical journal. Supplement series》1995,97(2):571-574

Accurate semi-empirical parameterizations of the energy-differential cross sections for charged pion and kaon production from proton-proton collisions are presented at energies relevant to cosmic rays. The parameterizations depend on the outgoing meson momentum and also the proton energy, and are able to be reduced to very simple analytical formulas suitable for cosmic-ray transport.  相似文献   

Henry's law and the behavior of weak acids and bases in fog and cloud     

W. Winiwarter  H. Fierlinger  H. Puxbaum  M. C. Facchini  B. G. Arends  S. Fuzzi  D. Schell  U. Kaminski  S. Pahl  T. Schneider  A. Berner  I. Solly  C. Kruisz 《Journal of Atmospheric Chemistry》1994,19(1-2):173-188

Experimental data from two field experiments on ground based clouds were used to study the distribution of formic acid, acetic acid, ammonia and S(IV) species between liquid and gas phase. The ratio of the concentrations of these compounds between the phases during concurrent measurements was compared to ratios expected according to Henry's law (considering the pH influence). Large discrepancies of several orders of magnitude were seen. Three hypotheses have been investigated to explain the observed discrepancies: The existence of a microscale equilibrium which does not persist in a bulk sample, a thermodynamic shift of the equilibrium due to competing reactions, and nonequilibrium conditions due to mass transfer limitations. Approximate quantitative calculations show that none of these hypotheses is sufficient to explain all of the discrepancies, so a combination of different effects seems to be responsible for this observation. The same theoretical considerations also suggest that mass transfer limitation may be an important factor for highly soluble compounds. The data presented here indicates that it is not possible to simply extrapolate interstitial gas phase composition from measured bulk liquid phase concentrations of a fog or cloud.Notation [r _max] liquid phase molar uptake rate (mol l^–1 s^–1) - [A _g ] concentration ofA in gas phase (atm) - [A _l ] concentration ofA in liquid phase (mol l^–1) - [A _g , 0] concentration ofA in gas phase (atm) at time 0 - LWC liquid water content (g m^–3) - R universal gas constant (0.082 l atm mol^–1 K^–1 - D _g diffusivity (for all gases 0.1 cm² s^–1 was used) - K _H ^* effective Henry's law coefficient (mol l^–1 atm^–1) - t _f lifetime of fog droplet (s) - a droplet radius (cm) - accommodation coefficient - R factor of discrepancy - T temperature (K) - v mean molecular speed (cm s^–1) formic acid: 35 000 acetic acid: 31 000 ammonia: 58 000  相似文献   

In Situ Trace Gas and Particle Measurements in the Summer Lower Stratosphere during STREAM II: Implications for O3 Production     

A. Bregman  F. Arnold  V. Bürger  H. Fisher  J. Lelieveld  B. A. Scheeren  J. Schneider  P. C. Siegmund  J. Ström  A. Waibel  W. M. F. Wauben 《Journal of Atmospheric Chemistry》1997,26(3):275-310

In situ aircraft measurements of O₃, CO,HNO₃, and aerosol particles are presented,performed over the North Sea region in the summerlower stratosphere during the STREAM II campaign(Stratosphere Troposphere Experiments by AircraftMeasurements) in July 1994. Occasionally, high COconcentrations of 200-300 pbbv were measured in thelowermost stratosphere, together with relatively highHNO₃ concentrations up to 1.6 ppbv. The particlenumber concentration (at standard pressure andtemperature) between 0.018-1 m decreased acrossthe tropopause, from >1000 cm^-3 in the uppertroposphere to <500 cm^-3 in the lowermoststratosphere. Since the CO sources are found in thetroposphere, the elevated CO mixing ratios areattributed to mixing of polluted tropospheric air intothe lowermost extratropical stratosphere. Further wehave used a chemical model to illustrate that nitrogenoxide reservoir species (mainly HNO₃) determinethe availability of NO_x (=NO + NO₂) andtherefore largely control the total net O₃production in the lower kilometers of thestratosphere. Model simulations, applying additionalNO_x perturbations from aircraft, show that theO₃ production efficiency of NO_x is smallerthan previously assumed, under conditions withrelatively high HNO₃ mixing ratios, as observedduring STREAM II. The model simulations furthersuggest a relatively high O₃ productionefficiency from CO oxidation, as a result of therelatively high ambient HNO₃ and NO_xconcentrations, implying that upward transport of COrich air enhances O₃ production in the lowermoststratosphere. Analysis of the measurements and themodel calculations suggest that the lowermoststratosphere is a transition region in which thechemistry deviates from both the upper troposphere andlower stratosphere.  相似文献   

The DARWIN project     

A. Léger  J. M. Mariotti  B. Mennesson  M. Ollivier  J. L. Puget  D. Rouan  J. Schneider 《Astrophysics and Space Science》1996,241(1):135-146

Angel and co-workers have proposed to detect exoplanets around nearby stars in the infrared (6–17 m) and to analyze their spectra, searching for H₂O, CO₂, CH₄, NH₃, and O₃ spectral features. The presence or absence of CO₂ would indicate either a strong similarity or difference with Solar telluric planet atmospheres. Water would indicate a habitable planet, and O₃ would reveal significant photosynthesis activity, due to the presence of carbon chemistry based life. Like these authors, we suggest an infrared nulling interferometer pointing to the star and working as a coronograph. Our main contribution is to propose an observatory made of four to five 1-meter class telescopes observing from about 4 to 5 AU to avoid the Solar Zodiacal Light (ZL) background at 10m instead of four 8-meter ones observing from the Earth vicinity. This allows the mission to be feasible in thenear future. The concept, named DARWIN, is under consideration by the European Space Agency for its Horizon 2000 Plus program.  相似文献   

Halogen systematics in the Mallik 5L-38 gas hydrate production research well,Northwest Territories,Canada: Implications for the origin of gas hydrates under terrestrial permafrost conditions     

Hitoshi Tomaru  Udo Fehn  Zunli Lu  Ryo Matsumoto 《Applied Geochemistry》2007

The authors report here halogen concentrations in pore waters and sediments collected from the Mallik 5L-38 gas hydrate production research well, a permafrost location in the Mackenzie Delta, Northwest Territories, Canada. Iodine and Br are commonly enriched in waters associated with CH₄, reflecting the close association between these halogens and source organic materials. Pore waters collected from the Mallik well show I enrichment, by one order of magnitude above that of seawater, particularly in sandy layers below the gas hydrate stability zone (GHSZ). Although Cl and Br concentrations increase with depth similar to the I profile, they remain below seawater values. The increase in I concentrations observed below the GHSZ suggests that I-rich fluids responsible for the accumulation of CH₄ in gas hydrates are preferentially transported through the sandy permeable layers below the GHSZ. The Br and I concentrations and I/Br ratios in Mallik are considerably lower than those in marine gas hydrate locations, demonstrating a terrestrial nature for the organic materials responsible for the CH₄ at the Mallik site. Halogen systematics in Mallik suggest that they are the result of mixing between seawater, freshwater and an I-rich source fluid. The comparison between I/Br ratios in pore waters and sediments speaks against the origin of the source fluids within the host formations of gas hydrates, a finding compatible with the results from a limited set of ¹²⁹I/I ratios determined in pore waters, which gives a minimum age of 29 Ma for the source material, i.e. at the lower end of the age range of the host formations. The likely scenario for the gas hydrate formation in Mallik is the derivation of CH₄ together with I from the terrestrial source materials in formations other than the host layers through sandy permeable layers into the present gas hydrate zones.  相似文献   

Editorial to announce online submission for Climate Dynamics     

Jean-Claude Duplessy  Elisa Manzini  Edwin K. Schneider 《Climate Dynamics》2007,28(1):1

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Microphysical and chemical characteristics of cloud droplet residuals and interstitial particles in continental stratocumulus clouds     

Admir C. Targino  Kevin J. Noone  Frank Drewnick  Johannes Schneider  Radovan Krejci  Gustavo Olivares  Silke Hings  Stephan Borrmann   《Atmospheric Research》2007,86(3-4):225-240

During June and July 2003 the Sources and Origins of Atmospheric Cloud Droplets experiment (SOACED) was carried out on a mountain-top site in central Sweden. The main objective of the experiment was to characterise the microphysical and chemical properties of cloud droplet residuals and interstitial aerosol particles in continental clouds and to understand the processes controlling cloud properties at this location.Interstitial and residual aerosol size distributions, cloud liquid water content and species- and size-resolved aerosol mass concentrations are the main variables employed to address questions pertaining to the cloud droplet number concentration and scavenging efficiency during a stratocumulus cloud event observed on July 28, 2003. In this cloud event, about 56% of the aerosol mass was associated with organic species, whilst SO₄ accounted for 23% and NH₄ for 14%. NO₃ and Cl made up about 7% of the total mass.The partitioning of the aerosol particles between cloud droplets and interstitial air has been studied in terms of their microphysical properties. The scavenging efficiency, defined as the fraction of particles activated into cloud elements compared to the total amount of particles, was investigated as a function of size. The scavenging efficiency curves displayed different shapes during the cloud event, from an S-shaped curve, with low scavenging efficiency in the Aitken mode and larger scavenging efficiency in the accumulation mode, to more unusual shapes where Aitken-mode particles were either solely activated or activated in addition to accumulation-mode particles.This study suggests that alterations of the aerosol chemical composition occurred during the measurement period, changing the hygroscopic nature of the CCN and decreasing their activation diameter. It is also hypothesized that entrainment of drier air aloft may have introduced inhomogeneities in the supersaturation field and modified the S-shaped scavenging curves.  相似文献   

Physico‐chemical Assessment of the Reference Status in German Surface Waters: A Contribution to the Establishment of the EC Water Framework Directive 2000/60/EG in Germany     

Petra Schneider  Peter L. Neitzel  Martin Schaffrath  Helmut Schlumprecht 《洁净——土壤、空气、水》2003,31(1):49-63

For the establishment of the EC Water Framework Directive in Germany the physico‐chemical reference conditions of surface waters in Germany had to be determined. The results of the statistical analysis of 3500 data sets of 31 surface water catchment types show that water body types can be aggregated to bogs and bog riverside meadows, saliniferous type, carbonatic‐dolomitic type, sandy‐clayey type, silicatic type, and metallogenic type. The data base allows an assessment of the plausibility of the surface water quality classification and quality targets of the LAWA (Länderarbeitsgemeinschaft Wasser). The investigated reference status of the natural surface waters for the considered elements in the suspended particulate matter, except in metallogenic landscapes, corresponds to the water quality class I of the LAWA. The reference conditions of cadmium and mercury in the total water phase are significantly higher than the quality targets of the LAWA. The evaluated reference data of the other physico‐chemical parameters in the total water phase show, that assessable physico‐chemical parameters refer to a quality class of I, mainly and quality class II, locally. Mainly, the data reached the quality targets of the LAWA. In spite of the hard evaluation criteria to separate reference sites a special enrichment of nitrate and cadmium was found in many German surface water reference catchment types.  相似文献