量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

K-H Instability of Dust Plasma     

Shi Zhi-dong  Li Zhong-yuanUniversity of Science  Technology of China  Hefei    PRC Advanced Centre for Earth Science  Astronomy  Third World Academy of Science 《紫金山天文台台刊》1996,(2)

Areview about K-H instability related to comet tail is presented.The effect of dust graing on KHI is theoretically analysed and relations of critical shear to excit KHI with the properties of dust grains both for sheared ion flow and for sheared dust flow re put out.Their possible application in comet tail is suggested.  相似文献   

自动高精度测距系统     

张学庄  张驰 《大地测量与地球动力学》1996,(1)

介绍了自动高精度测距系统。该系统能以５×１０－７的测距精度测定多个观测点的形变，可作为跨断层动态连续观测的新仪器。  相似文献   

Influence of soft clays on the response spectra for structures in eastern Canada     

Ren  Tinawi  Marc Sarrazin  Andr  Filiatrault 《Soil Dynamics and Earthquake Engineering》1993,12(8):469-477

The 1990 edition of the National Building Code of Canada (Associate Committee of the National Building Code, National Research Council, Ottawa, 1990) makes a clear distinction between eastern and western Canada in terms of seismic acceleration and velocity zones. While it is well established that ground motions can be amplified significantly through loose clay deposits, no results are available that take into consideration the typical high frequency content of ground motions in eastern Canada. This paper develops ground amplification curves for clays having depths between 10 and 70 m excited by typical eastern Canadian ground motions scaled to two different values of peak horizontal accelerations. Simplified free-field spectral design curves, which could be used by structural designers, are proposed. The curves show that maximum spectral accelerations occur for structural periods between 0.2 and 0.5 s. In addition, soil depth does not appear to be an important parameter controlling the response of typical clay deposits in eastern Canada.  相似文献   

抗差估计的初值选择     

王振杰  欧吉坤  曲国庆 《大地测量与地球动力学》2001,21(3):32-35

对L1 范估计的平差值和LS估计的平差值作为抗差估计的初值进行了比较 ,指出在 ρ函数是严凸函数时 ,二者无明显的区别。因为LS估计简单且易于计算 ,因此建议用LS估计的平差值作为抗差估计的初值。  相似文献   

An algorithm for detecting and estimating cycle slips in single-frequency GPS   总被引：1，自引：0，他引：1  

Jia Pei-zhang  Wu Lian-da 《Chinese Astronomy and Astrophysics》2001,25(4):1089-521

An algorithm for detecting outliers and cycle slips in single-frequency GPS using a 3rd order polynomial model of the Kalman filter and for estimating the ambiguity by using optimal wavelet is presented in this paper. It is applicable to the carrier phase measurement with sample rate of one per second. The results of calculation with the GPS data aboard satellite Topex on 1995 June 22 show that the algorithm is so efficient that it can accurately estimate the ambiguity even for signals interrupted by a few seconds.  相似文献   

Urban tourism research methodology     

Tao Wei  Zhong Wen-hui  Hong Yan 《中国地理科学(英文版)》2005,15(2):173-178

  相似文献   

Determination of physical parameters of NGC 2023 using the hyperfine NH₃ spectrum     

Xing Jun  Xu Lan-Ping 《Chinese Astronomy and Astrophysics》1985,9(4):283-290

An improved approach is given for deriving the physical parameters of a molecular cloud by its NH₃ rotation-inversion hyperfine spectra. The optical depth τ₀(1, 1) of NH₃ (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature T_ex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature T_R ( 2, 1) between the NH₃ levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH₃ (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH₃ and para-NH₃ are also discussed.

This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained.  相似文献   

Early warning research on salt-alkalization desertification in western Songnen Plain     

BIAN Jian-min  LIN Nian-feng  TANG Jie College of Environment  Resources  Jilin  University  Changchun  Jilin  China 《东北亚地学研究》2005,(Z1)

Desertification is an environmental issue in the world. The salt-alkalization desertification land area formed by both primary and secondary salt-alkalization has extended in a large scale, which has become a significant eco-environmental problem. Based on the characteristics of eco-environment and the situation of desertification in western Songnen plain, this paper reports the analyzes of its formation in background and cause. An early warning system on the salt-alkalization desertification is established and the GIS technology is used to abstract the information of desertification evaluation index. Supported by the integrated technology of the GIS and ANN, the orientation and quantitative result of desertification are gained, which is helpful to the eco-environment protection and resource development in western Songnen Plain.  相似文献   

Morphological characters of the two-ribbon flare of 1981 May 13 and their explanation     

Zu-yan Zhu  Hong-ao Wu  Tian-jun Cao 《Chinese Astronomy and Astrophysics》1985,9(2):119-123

We give a summary of the morphology of the two-ribbon flare of 1981 May 13. One striking feature is that the Ha flare began at about 0338' UT and the double-ribbon structure was formed about 0346, $\text{before}$ the impulsive phase of the radio 3 cm burst at 04 11 UT. The 3 cm radio burst flux beginning at 03 33 UT showed only slow, stepwise increases lasting half an hour until the impulsive phase and this type of increase is usually regarded to be a typical thermal process. Each step in the radio flux corresponded to a variation in the Ha flare, showing that the radio and Hα emissions during this period came from the same thermal source. In this paper, we explain this behaviour in terms of Hyder's model: we think that the magnetic trough supporting the solar prominence rose for some reason, causing the prominence matter (the dark filaments) to fall along the magnetic lines and to hit the chromosphere and trigger off the flare. We give rough estimates of the energy density, the height of prominence and the infall matter at the different radio increments. We also give a qualitative explanation for the appearances of the single-peak structure in the radio burst at 0411 and the covering of the sunspot shortly after at 04 13 and propose several possible mechanisms.  相似文献