Effect of hydrogen on the melting temperature of FeS at high pressure: Implications for the core of Ganymede     

Yuki Shibazaki  Eiji Ohtani  Hidenori Terasaki  Ryuji Tateyama  Tatsuya Sakamaki  Taku Tsuchiya  Ken-ichi Funakoshi 《Earth and Planetary Science Letters》2011,301(1-2):153-158

We have carried out in situ X-ray diffraction experiments on the FeS–H system up to 16.5 GPa and 1723 K using a Kawai-type multianvil high-pressure apparatus employing synchrotron X-ray radiation. Hydrogen was supplied to FeS from the thermal decomposition of LiAlH₄, and FeSH_x was formed at high pressures and temperatures. The melting temperature and phase relationships of FeSH_x were determined based on in situ powder X-ray diffraction data. The melting temperature of FeSH_x was reduced by 150–250 K comparing with that of pure FeS. The hydrogen concentration in FeSH_x was determined to be x = 0.2–0.4 just before melting occurred between 3.0 and 16.5 GPa. It is considered that sulfur is the major light element in the core of Ganymede, one of the Galilean satellites of Jupiter. Although the interior of Ganymede is differentiated today, the silicate rock and the iron alloy mixed with H₂O, and the iron alloy could react with H₂O (as ice or water) or the hydrous silicate before the differentiation occurred in an early period, resulting in a formation of iron hydride. Therefore, Ganymede's core may be composed of an Fe–S–H system. According to our results, hydrogen dissolved in Ganymede's core lowers the melting temperature of the core composition, and so today, the core could have solid FeSH_x inner core and liquid FeH_x–FeSH_x outer core and the present core temperature is considered to be relatively low.  相似文献   

Degradation of algal lipids by deep-sea benthic foraminifera: An in situ tracer experiment     

Hidetaka Nomaki  Naohiko Ohkouchi  Petra Heinz  Hisami Suga  Yoshito Chikaraishi  Nanako O. Ogawa  Kouhei Matsumoto  Hiroshi Kitazato 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(9):1488-1503

We conducted an in situ feeding experiment using ¹³C-labeled unicellular algae in Sagami Bay, Japan (water depth, 1450 m), in order to understand the fate of lipid compounds in phytodetritus at the deep-sea floor. We examined the incorporation of excess ¹³C into lipid compounds extracted from bulk sediments and benthic foraminiferal cells. ¹³C-enriched fatty acids derived from ¹³C-labeled algae were exponentially degraded during 6 days of incubation in the sediment. Subsequent enrichments in ¹³C in sedimentary n-C_15, anteiso-C₁₇, and C₁₇ fatty acids indicated the microbial degradation of algal material and production of bacterial biomass in the sediment. We observed the incorporation of ¹³C-labeled algal phytol and fatty acids into foraminiferal cells. The compositions of ¹³C-labeled algal lipids in foraminiferal cells were different from those in the bulk sediments, indicating that foraminiferal feeding and digestion influenced the lipid distribution in the sediments. Furthermore, some sterols in Globobulimina affinis (e.g., 24-ethylcholesta-5,22-dien-3β-ol, 24-ethylcholest-5-en-3β-ol, and 23,24-dimethylcholesta-5,22E-dien-3β-ol) were newly produced via the modification of dietary algal sterols within 4–6 days. In addition to the effects of bacteria, feeding by benthic foraminifera can result in a significant reorganization of the composition of organic matter and influence benthic food webs and carbon cycling at the deep-sea floor.  相似文献   

Mid-latitude horizontal electric fields in the stratosphere during magnetically disturbed periods     

Toshio Ogawa  Hiroto Kawamoto 《Planetary and Space Science》1982,30(10):1013-1024

The horizontal electric field has been measured with balloons over the Pacific Ocean near the Sanriku Coast in Japan. By comparing the electric-field data obtained during magnetically disturbed periods, 16–17 October 1973, 6–7 October 1975 and 3–4 October 1977, with IMF B_z, auroral zone AU and AL, equatorial Dst and $\text{Δ(Dst)}\text{Δt}$, mid-latitude magnetic fields (H, D, Z at Kakioka), and the ionospheric electron density (?₀F2 at Kokubunji), it is found that the observed electric fields of about 9 mVm^?1 made the clockwise rotation during the growth and recovery stages of the magnetospheric substorms. Relations between high and middle latitude ionospheres and between the magnetosphere and the ionosphere are discussed in relation to the origin and propagation of these electric fields.  相似文献   

Dust influx reconstruction during the last 26,000 years inferred from a sedimentary leaf wax record from the Japan Sea     

Yusuke Yokoyama  Tatsuhiro Naruse  Nanako O. Ogawa  Ryuji Tada  Hiroshi Kitazato  Naohiko Ohkouchi 《Global and Planetary Change》2006,54(3-4):239-250

We obtained the high-resolution record of terrestrial biomarkers (C₂₉ and C₃₁ n-alkanes) for the last 26,000 years from Oki Ridge in the south Japan Sea that enabled us to discuss millennial scale climate changes. Our sampling resolution for the biomarker during the major deglaciation period (10–19.5 cal ka BP) is 300 years and for the elemental analyses (total organic carbon and total nitrogen) is as good as ca 200 years. The estimated mass accumulation rate of these molecules during the last glacial period is substantially higher than during the Holocene. They also exhibited two distinct peaks at 17.6 cal ka BP and 11.4 cal ka BP, which are coincident with Heinrich Event 1 and the latest stage of the Younger Dryas, respectively. The unique oceanographic setting of the Japan Sea tends to preferentially preserve organic material of aeolian origin. The nature of our biomarker record in fact suggests a strong aeolian signal, and hence their flux to the Japan Sea potentially reflects the climate conditions of the dust source regions and transport intensity. Our results are consistent with previously reported monsoon variations based on other proxies that is indicative of a strong linkage between North Atlantic climate and Asian monsoon intensity.  相似文献   

The optical reflector system for the CANGAROO-II imaging atmospheric Cherenkov telescope     

A. Kawachi  Y. Hayami  J. Jimbo  S. Kamei  T. Kifune  H. Kubo  J. Kushida  S. LeBohec  K. Miyawaki  M. Mori  K. Nishijima  J. R. Patterson  R. Suzuki  T. Tanimori  S. Yanagita  T. Yoshikoshi  A. Yuki 《Astroparticle Physics》2001,14(4):1492-269

A new imaging atmospheric Cherenkov telescope with a light-weight reflector has been constructed. Light, robust, and durable mirror facets of containing carbon fiber reinforced plastic laminates were developed for the telescope. The reflector has a parabolic shape (f/1.1) with a 30 m² surface area, which consists of 60 spherical mirror facets. The image size of each mirror facet is 0°.08 (FWHM) on average. The attitude of each facet can be adjusted by stepping motors. After the first in situ adjustment, a point image of about 0°.14 (FWHM) over 3° field of view was obtained. The effect of gravitational load on the optical system was confirmed to be negligible at the focal plane. The telescope has been in operation with an energy threshold for γ-rays of 300 GeV since May 1999.  相似文献   

Observation of cosmic soft X-rays     

S. Hayakawa  T. Kato  F. Makino  H. Ogawa  Y. Tanaka  K. Yamashita  M. Matsuoka  S. Miyamoto  M. Oda  Y. Ogawara 《Astrophysics and Space Science》1971,12(1):104-117

Cosmic soft X-rays in the energy range between 0.14 and 7 keV were observed with thin polypropylene window proportional counters on board a sounding rocket. The field of view crossed the galactic plane in the Cygnus-Cassiopeia region at a large angle and reached the galactic latitudes of –55° and +30°. Referring also to the result with Be window counters, we obtained the energy spectrum of Cyg XR-2, the flux from the Cas A region and the distribution of the intensity of diffuse X-rays over the scanned region. The turn-over of the Cyg XR-2 spectrum at about 1 keV indicates that the distance of the Cyg XR-2 source lies between 600 and 800 pc, if the turn-over is due entirely to interstellar absorption. The flux from the Cas A region is obtained as 0.23±0.05 photons cm^–2 sec^–1 in the energy range between 1.1 and 4.1 keV. The intensity of diffuse soft X-rays depends on the galactic latitude more weakly than expected from the interstellar absorption of extragalactic X-rays and shows asymmetry with respect to the galactic equator, thus suggesting a contribution of galactic X-rays. The spectrum of extragalactic X-rays is approximately represented by a power lawE ^–1.8.  相似文献   

Possibility of measuring the large scale electric field at ground level     

Toshio Ogawa 《Planetary and Space Science》1976,24(8):801-802

A method is proposed for making measurements near the ground of a large scale electric field mapped from ionospheric and magnetospheric sources.  相似文献   

Remobilization of Highly Crystalline Felsic Magma by Injection of Mafic Magma: Constraints from the Middle Sixth Century Eruption at Haruna Volcano, Honshu, Japan   总被引：1，自引：0，他引：1  

Suzuki  Yuki; Nakada  Setsuya 《Journal of Petrology》2007,48(8):1543-1567

The latest eruption of Haruna volcano at Futatsudake took placein the middle of the sixth century, starting with a Plinianfall, followed by pyroclastic flows, and ending with lava domeformation. Gray pumices found in the first Plinian phase (lowerfall) and the dome lavas are the products of mixing betweenfelsic (andesitic) magma having 50 vol. % phenocrysts and maficmagma. The mafic magma was aphyric in the initial phase, whereasit was relatively phyric during the final phase. The aphyricmagma is chemically equivalent to the melt part of the phyricmafic magma and probably resulted from the separation of phenocrystsat their storage depth of 15 km. The major part of the felsicmagma erupted as white pumice, without mixing and heating priorto the eruption, after the mixed magma (gray pumice) and heatedfelsic magma (white pumice) of the lower fall deposit. Althoughthe mafic magma was injected into the felsic magma reservoir(at 7 km depth), part of the product (lower fall ejecta) precedederuption of the felsic reservoir magma, as a consequence ofupward dragging by the convecting reservoir of felsic magma.The mafic magma injection made the nearly rigid felsic magmaerupt, letting low-viscosity mixed and heated magmas open theconduit and vent. Indeed the lower fall white pumices preservea record of syneruptive slow ascent of magma to 2 km depth,probably associated with conduit formation. KEY WORDS: high-crystallinity felsic magma; magma plumbing system; multistage magma mixing; upward dragging of injected magma; vent opening by low-viscosity magma  相似文献   

Sea‐cliff retreat and shore platform widening: steady‐state equilibrium?     

Mark E. Dickson  Hiroki Ogawa  Paul S. Kench  Andrew Hutchinson 《地球表面变化过程与地形》2013,38(9):1046-1048

We challenge the notion of steady‐state equilibrium in the context of progressive cliff retreat on micro‐tidal coasts. Ocean waves break at or close to the abrupt seaward edge of near‐horizontal shore platforms and then rapidly lose height due to turbulence and friction. Conceptual models assume that wave height decays exponentially with distance from the platform edge, and that the platform edge does not erode under stable sea‐level. These assumptions combine to a steady‐state view of Holocene cliff retreat. We argue that this model is not generally applicable. Recent data show that: (1) exponential decay in wave height is not the most appropriate conceptual model of wave decay; (2) by solely considering wave energy at gravity wave frequencies the steady‐state model neglects a possible formative role for infragravity waves. Here we draw attention to possible mechanisms through which infragravity waves may drive cliff retreat over much greater distances (and longer timescales) than imaginable under the established conceptual model. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater   总被引：2，自引：0，他引：2  

Jonathan H. Sharp  Kathrine R. Rinker  Karen B. Savidge  Jeffrey Abell  Jean Yves Benaim  Deborah Bronk  David J. Burdige  Gustave Cauwet  Wenhao Chen  Marylo D. Doval  Dennis Hansell  Charles Hopkinson  Gerhard Kattner  Nancy Kaumeyer  Karen J. McGlathery  Jeffrey Merriam  Nick Morley  Klaus Nagel  Hiroshi Ogawa  Carol Pollard  Mireille Pujo-Pay  Patrick Raimbault  Raymond Sambrotto  Sybil Seitzinger  Georgina Spyres  Frank Tirendi  Ted W. Walsh  C. S. Wong 《Marine Chemistry》2002,78(4)

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.  相似文献