Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

南黄海及相邻陆区松散沉积层磁性地层的研究     

周墨清  葛宗诗 《海洋地质与第四纪地质》1990,(4)

本文通过研究区5个钻孔松散沉积岩心磁性地层的划分对比,获知布容与松山极性带的界线,南黄海和陆区北部位于80.0—99.5m。陆区的南部此界线于270.4m深处。松山和高斯极性带的界线,海区未揭露到,其沉积起始时间都小于1.7Ma。而陆区的南、北部分别位于117m和328.2m。高斯和吉尔伯特极性带的界线,陆区北部为140m,而南部区为460.15m。沉积起始时间为3.4Ma。吉尔伯特底界仅北部陆区所揭示,为190.5m。松散沉积层与下伏白垩纪(?)石灰岩接触面位于400.35m,沉积起始时间约17.0Ma。  相似文献   

黄海、渤海底层温度数值预报方法的研究     

王宗山  徐伯昌  龚滨  邹娥梅  李繁华 《海洋科学进展》1996,(3)

根据文献［ｌ］建立的底层温度（ＴＨ）与其水柱垂向平均温度（）的经验关系，结合流体动力学方程和（垂向平均）热传导方程，发展了以水气温差和风速为已知量的底层温度二维数值预报模式。该模式避开了海面热量和动量输入在垂直水柱中分配的复杂物理过程而直接报出底层水温场，具有较好的实用性；此外，从试报结果看，效果令人满意。  相似文献   

常压法合成Methomyl的研究     

钱佐国  孙明昆  杨福顺  孙林枫  周曾昊 《中国海洋大学学报(自然科学版)》1990,(3)

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。  相似文献   

东海XH凹陷烃资源预测──勘探层分析及石油资源专家系统分析     

肖国林  周才凡  李桂群 《中国海洋大学学报(自然科学版)》1995,(3)

应用勘探层分析及石油资源专家系统对ＸＨ凹陷下第三系勘探目的层的三个勘探层烃资源量作出了综合预测，结果表明，凹陷内各勘探层，尤其是渐新统勘探层，烃资源量相当可观。提出在渐新统内的地层圈闭中可进一步作详细的勘探工作。  相似文献   

六溴苯的合成研究     

钱佐国  孙明昆  苗世昌  刘新河  周曾昊 《中国海洋大学学报(自然科学版)》1991,(2)

对直接溴化法合成六溴苯作了系统的研究,并对文献方法进行了一系列的改进。包括选择适当的摧化剂及其用量,使反应基本上在室温下进行;利用水汽蒸馏法驱除残余溴,可直接得到无色或近乎无色的纯净产物,而勿需进行还原脱溴,且得率较高。提出一种以溴化物形式回收副产物的方法。  相似文献   

Effect of shallow and narrow water on added mass of cylinders with various cross-sectional shapes     

Z.X. Zhou  Edmond Y.M. Lo  S.K. Tan 《Ocean Engineering》2005,32(10):1199-1215

The sway, heave and roll added masses of three uniform cylinders with semi-circular, rectangular and triangular cross-sectional shapes in shallow and narrow water are numerically analysed. The method is based on simulation of the potential flow induced by the cylinder's mode of motion. The effects of shallow and narrow water on added mass are analysed and presented. It is concluded that the shallow and narrow water effects on added mass depend on the different cross-section shapes of the cylinders. In particular, the water depth effect on sway added mass is stronger than that on heave added mass while the narrow water effect on sway is weaker than that on heave. The shallow water effect on added mass tends to weaken the narrow water effect. Lastly the effect of shallow and narrow water on added mass on a rectangular cylinder is the strongest while that on a triangular cylinder is the weakest.  相似文献   

Wave interaction with a perforated wall breakwater with a submerged horizontal porous plate   总被引：1，自引：0，他引：1  

Yong Liu  Yu-cheng Li  Bin Teng 《Ocean Engineering》2007,34(17-18):2364-2373

This study examines the hydrodynamic performance of a new perforated-wall breakwater. The breakwater consists of a perforated front wall, a solid back wall and a submerged horizontal porous plate installed between them. The horizontal porous plate enhances the stability and wave-absorbing capacity of the structure. An analytical solution based on linear potential theory is developed for the interaction of water waves with the new proposed breakwater. According to the division of the structure, the whole fluid domain is divided into three sub-domains, and the velocity potential in each domain is obtained using the matched eigenfunction method. Then the reflection coefficient and the wave forces and moments on the perforated front wall and the submerged horizontal porous plate are calculated. The numerical results obtained for limiting cases are exactly the same as previous predictions for a perforated-wall breakwater with a submerged horizontal solid plate [Yip, T.L., Chwang, A.T., 2000. Perforated wall breakwater with internal horiontal plate. Journal of Engineering Mechanics ASCE 126 (5), 533–538] and a vertical wall with a submerged horizontal porous plate [Wu, J.H., Wan, Z.P., Fang, Y., 1998. Wave reflection by a vertical wall with a horizontal submerged porous plate. Ocean Engineering 25 (9), 767–779]. Numerical results show that with suitable geometric porosity of the front wall and horizontal plate, the reflection coefficient will be always rather small if the relative wave absorbing chamber width (distance between the front and back walls versus incident wavelength) exceeds a certain small value. In addition, the wave force and moment on the horizontal plate decrease significantly with the increase of the plate porosity.  相似文献   

Parabolic Wave Propagation Modelling in Orthogonal Coordinate Systems     

袁德奎  林斌良肖鸿 《中国海洋工程》2004,18(3):445-456

This paper presents a numerical model study of the propagation of water waves using the parabolic approximation of the mild-slope equation in the orthogonal coordinate system. Two types of coordinate systems are studied: (a) a general form of orthogonal coordinate system and (b) the conformal system, a special form of orthogonal coordinate system. Two typical examples, namely, expanded breakwaters and a circular channel, are studied to validate the model. First, the examples are studied by use of the general orthogonal coordinates. Then the same examples are computed by use of the confonnal system. The computational results show that the confonnal coordinate system generally gives better predictions than the general orthogonal system. A numerical technique for generating the conformal grid is combined with the numerical model to improve the practicability of the model. The comparison between the result from the numerical grid system and that from the analytical grid system shows that reliable computational results can be obtained by use of the numerical confonnal grid system.  相似文献   

自由生活海洋线虫的系统分类学   总被引：1，自引：0，他引：1  

张志南  周红 《中国海洋大学学报(自然科学版)》2003,33(6):891-900

自由生活海洋线虫是海洋中最丰富的后生动物 ,它属于小型底栖动物的永久性成员 ,即分选时 ,可通过 0 .5 mm或 1 mm网筛但被 0 .0 31 mm或 0 .0 4 2 mm孔径网筛蓄留的动物 ,本文讨论线虫在动物界的分类地位 ,与相近动物类群的亲缘关系 ,泄腺纲与泄管纲分类系统的由来和演变。海洋线虫属于泄腺纲 ,由 Bremerhaven种名录和 L orenzen确立的分类系统已得到广泛的应用。海洋线虫的分类系统仍处在发展和完善中 ,需要发现更多更有价值的共近裔性状用于物种水平和较高分类阶元的分析和鉴定  相似文献