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981.
The Drake Passage is located between the Antarctic Peninsula and Tierra del Fuego in the south of South America. Surface seawater samples were collected at seven sites in the Drake Passage during the austral summer of 2012. The 16S rRNA sequences were analyzed from 187 isolated bacterial strains. Three phyla, 29 genera and 56 species were identified. The three phyla were Actinobacteria, Firmicutes and Proteobacteria; the Proteobacteria included α-Proteobacteria, β-Proteobacteria and γ-Proteobacteria. γ-Proteobacteria, Actinobacteria and Firmicutes were the dominant class or phyla in terms of quantity and species. Gram-positive bacteria (Actinobacteria and Firmicutes) accounted for 57.8% of all types identified. There were nine dominant genera, including Curtobacterium, Staphylococcus, and Halomonas, and 14 dominant species including Curtobacterium flaccumfaciens, Curtobacterium pusillum, and Staphylococcus sciuri. Of the strains identified, 87.2% were catalase positive or weakly positive. 相似文献
982.
Chaoqi Yu Meihan Li Yinling Cao Xian He Hong Zhou Tingting Zhang Chongying Li 《中国地球化学学报》2018,37(3):456-464
Snow samples were collected over a 3-year period from 2012 to 2014 at the Hailuogou glacier of Mountain Gongga (Mt. Gongga) and analyzed for 16 priority polycyclic aromatic hydrocarbons (PAHs) using Gas Chromatography–Mass Spectrometry (GC–MS). The results show that total average levels of the 16 PAHs ranged from 452 to 290 ng·L?1 with a possible declining trend from 2012 to 2014. Distances between the sampling sites and the emission sources were estimated at typically less than 500 km. The results suggest that the major source of PAHs was from coal combustion, while contributions from automobile exhaust played an important role in more recent years. This finding was in agreement with the characteristics of presence of local industry, residence, and recent development of tourism of the surrounding areas. 相似文献
983.
Delu Li Rongxi Li Zengwu Zhu Xiaoli Wu Futian Liu Bangsheng Zhao Jinghua Cheng Baoping Wang 《中国地球化学学报》2018,37(1):134-150
Using trace elements to reconstruct paleoenvironment is a current hot topic in geochemistry. Through analytical tests of oil yield, ash yield, calorific value, total sulfur, major elements, trace elements, and X-ray diffraction, the quality, mineral content, occurrence mode of elements, and paleoenvironment of the Zhangjiatan oil shale of the Triassic Yanchang Formation in the southern Ordos Basin were studied. The analyses revealed relatively high oil yield (average 6.63%) and medium quality. The mineral content in the oil shale was mainly clay minerals, quartz, feldspar, and pyrite; an illite–smectite mixed layer comprised the major proportion of clay minerals. Compared with marine oil shale in China, the Zhangjiatan oil shale had higher contents of quartz, feldspar, and clay minerals, and lower calcite content. Silica was mainly in quartz and Fe was associated with organic matter, which is different from marine oil shale. The form of calcium varied. Cluster analyses indicated that Fe, Cu, U, V, Zn, As, Cs, Cd, Mo, Ga, Pb, Co, Ni, Cr, Sc, P, and Mn are associated with organic matter while Ca, Na, Sr, Ba, Si, Zr, K, Al, B, Mg, and Ti are mostly terrigenous. Sr/Cu, Ba/Al, V/(V + Ni), U/Th, AU, and δU of oil shale samples suggest the paleoclimate was warm and humid, paleoproductivity of the lake was relatively high during deposition of the shale—which mainly occurred in fresh water—and the paleo-redox condition was dominated by reducing conditions. Fe/Ti ratios of the oil shale samples suggest clear hydrothermal influence in the eastern portion of the study area and less conspicuous hydrothermal influence in the western portion. 相似文献
984.
In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N2 adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals. 相似文献
985.
Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and 57Fe–58Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ56Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ56Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ57Fe?=?0.534?±?0.010, 2SE). 相似文献
986.
As an important unconventional resource, oil shale has received widespread attention. The oil shale of the Chang 7 oil layer from Triassic Yanchang Formation in Ordos Basin represents the typical lacustrine oil shale in China. Based on analyzing trace elements and oil yield from boreholes samples, characteristics and paleo-sedimentary environments of oil shale and relationship between paleo-sedimentary environment and oil yield were studied. With favorable quality, oil yield of oil shale varies from 1.4% to 9.1%. Geochemical data indicate that the paleo-redox condition of oil shale’s reducing condition from analyses of V/Cr, V/(V + Ni), U/Th, δU, and authigenic uranium. Equivalent Boron, Sp, and Sr/Ba illustrate that paleosalinity of oil shale is dominated by fresh water. The paleoclimate of oil shale is warm and humid by calculating the chemical index of alteration and Sr/Cu. Fe/Ti and (Fe + Mn)/Ti all explain that there were hot water activities during the sedimentary period of oil shale. In terms of Zr/Rb, paleohydrodynamics of oil shale is weak. By means of Co abundance and U/Th, paleo-water-depth of oil shale is from 17.30 to 157.26 m, reflecting sedimentary environment which is mainly in semi deep–deep lake facies. Correlation analyses between oil yield and six paleoenvironmental factors show that the oil yield of oil shale is mainly controlled by paleo-redox conditions, paleoclimate, hot water activities, and depth of water. Paleosalinity and paleohydrodynamics have an inconspicuous influence on oil yield. 相似文献
987.
988.
本文利用褐铁矿中针铁矿经热脱水相变获得以纳米晶赤铁矿为主要物相的纳米-微米多级孔结构材料,并用于模拟净化富Mn~(2+)地下水。同时考察了热处理温度、初始pH值、初始Mn~(2+)浓度、吸附反应时间等对材料去除溶液中Mn~(2+)的影响。XRD、TEM、BET表征结果表明,300℃热处理产物中赤铁矿孔径最小为2.7 nm,比表面积最大达到107.4 m~2/g。吸附实验结果表明,在pH值5~10的范围内,p H值对煅烧褐铁矿颗粒对Mn~(2+)去除效果影响较小;材料在贫氧条件下对水中低浓度Mn~(2+)的最大吸附量为6.45 mg/g;吸附动力学符合准二级动力学模型;褐铁矿热处理形成的纳米晶赤铁矿对Mn~(2+)具有吸附和催化氧化作用,其中的杂质锰氧化物对Mn~(2+)的吸附和催化氧化具有增强作用。 相似文献
989.
航磁异常查证是矿产勘查中的一个重要环节,其目的是通过地面查证,确定异常是否存在,追踪异常源,了解异常源所处的地质环境,对异常作出客观评价,提出进一步工作的建议,为后续资料解释提供依据.通过使用地物化综合方法对黑C-2011-02243号异常查证发现:地质剖面测量和土壤地球化学测量可在地表发现较好的找矿线索;高精度磁测及激电中梯测量则反映了深部地质体及矿化特征.依据查证结果认为,在进行航磁异常查证工作时,可优先进行剖面性的地质、高精度磁法及土壤地球化学测量工作;在分析上述测量结果的基础上安排剖面性的电法测量;如存在进一步找矿信息,可安排面积性物化探测量及工程验证工作. 相似文献
990.
为了探讨在再生水地表回灌条件下,再生水对地下水中氨素和主要盐分浓度变化的影响,选取现实存在的清河再生水湿地公园为例,以氨氮、Cl-离子为主要研究对象,利用Hydrus-1D溶质运移模型和Modflow、MT3DMSD耦合地下水模型,模拟了再生水长期利用后的地下水氨氮和Cl-指标变化情况。研究结果显示,再生水到达包气带底部时,水中氮氨、Cl-离子含量高于研究区潜水地下水中的相应指标含量,氨氮超出地下水质量Ⅲ类标准。预测5~20年后,潜水中氨氮超标面积不断扩展,20年后将达14km2,氨氮超标垂向延伸至第一层弱透水层;Cl-离子在潜水中不超标,但在湿地公园周边浓度有所增加。湿地公园再生水的长期地表回灌将给当地地下水质量带来负面影响。 相似文献