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51.
The activity of a silicate liquid component in a melt at an elevated liquidus temperature and pressure may be expressed analytically in terms of the 1-bar liquidus temperature activity and functions of the partial molar volume and partial molar enthalpy of mixing. Alternatively, the activity of the elevated (i.e. higherP-T) liquidus may be expressed in terms of the difference of heat content, heat capacity, entropy and volume of the component in the crystalline form and in the melt. Equating these two expressions, the partial molar enthalpy of mixing and there-from the partial molar entropy of mixing may be determined, provided the liquidus temperatures of the phase in question at both 1 bar and higher pressure and at a constant melt composition are known. Several such retrievals for CaMgSi2O6, Mg2SiO4, NaAlSi3O8, and TiO2 from experimental phase equilibrium data are presented. It is argued that as the partial molar enthalpy of mixing generally has large values, the regular solution formulation on the basis of a constant function of the activity coefficient would lead to erroneousP-T estimates for ascending magmas. 相似文献
52.
Abhijit Basu 《Journal of Earth System Science》2005,114(3):375-380
Back scattered electron and transmission electron imaging of lunar soil grains reveal an abundance of submicrometer-sized
pure Fe0 globules that occur in the rinds of many soil grains and in the submillimeter sized vesicular glass-cemented grains called
agglutinates. Grain rinds are amorphous silicates that were deposited on grains exposed at the lunar surface from transient
vapors produced by hypervelocity micrometeorite impacts. Fe0 may have dissociated from Fe-compounds in a high temperature (>3000°C) vapor phase and then condensed as globules on grain
surfaces. The agglutinitic glass is a quenched product of silicate melts, also produced by micrometeorite impacts on lunar
soils. Reduction by solar wind hydrogen in agglutinitic melts may have produced immiscible droplets that solidified as globules.
The exact mechanism of formation of such Fe0 globules in lunar soils remains unresolved. 相似文献
53.
Auto-correlation analysis of wave heights in the Bay of Bengal 总被引:1,自引:0,他引:1
Time series observations of significant wave heights in the Bay of Bengal were subjected to auto-correlation analysis to determine
temporal variability scale. The analysis indicates an exponential fall of auto-correlation in the first few hours with a decorrelation
time scale of about six hours. A similar figure was found earlier for ocean surface winds. The nature of variation of auto-correlation
with time lags was also found to be similar for winds and wave heights 相似文献
54.
Aerodynamic drag coefficient and roughness length for three seasons over a tropical western Indian station 总被引:1,自引:0,他引:1
M.N. Patil 《Atmospheric Research》2006,80(4):280-293
Land Surface Processes Experiment (LASPEX) was conducted over semi-arid region of western India in 1997. As a part of this program, wind and temperature observations were taken using slow as well as fast response sensors over a semi-arid station Anand (22°35′N, 72°55′E) situated in Gujarat state of India. Turbulent parameters such as drag coefficient and sensible heat flux were estimated using eddy correlation method and aerodynamic roughness length was estimated using wind profiles. The analysis has been carried out for the data representing summer, monsoon and winter seasons. It was found that the wind speed does not exceed 5 ms− 1 during the observational period considered in this study. Relationship of aerodynamic drag coefficient and roughness length with wind speed and stability has been investigated. Aerodynamic roughness length was greater in the stable conditions when the wind speed was low and it reduced drastically during convective conditions. The resulting values of aerodynamic roughness length and drag coefficient for the monsoon period agree well with values reported in literature over Indian subcontinent for homogeneous grass covered surfaces. 相似文献
55.
A two-dimensional numerical model is employed to study the effect of the coastal urban heat island on the sea breeze front
and the thermal internal boundary layer height. The temperature at the land surface is determined by solving an energy budget
equation. The effect of the urban heat island is studied by varying the width of the region and its intensity. During the
early afternoon, the presence of the urban heat island enhances the strength of convergence of the sea breeze front and also
reduces its inland penetration. The presence of the urban heat island causes increased thermal internal boundary layer height.
Larger urban width causes larger vertical velocity and higher thermal internal boundary layer. Stronger convergence and higher
thermal internal boundary layer are also obtained in case of larger heat island intensity. 相似文献
56.
57.
Sensitivity of the radar scattering coefficient to the oceanic wind vector in the midangular range for frequencies from L-
to Ku- band is studied. This is based on computations of scattering coefficient via the two-scale scattering theory employing
a semi-empirical model for the ocean spectrum suggested by Fung and Lee and the slope distribution by Cox and Munk. Higher
frequency and incident angles of over 45 degrees seem to yield better wind sensitivity. 相似文献
58.
An exact analysis of Stokes' problem for an infinite vertical plate, whose temperature varies linearly with time, has been presented. It is observed that the velocity near the plate increases with the timet, and the Grashof numberGr. The skin-friction has been found to vary ast
7/2 and the Nusselt number varies as
or
whereP is the Prandtl number. 相似文献
59.
Abhijit Basu Susan J. Wentworth David S. McKay 《Meteoritics & planetary science》2002,37(12):1835-1842
Abstract— Evidence in favor of the model fusion of the finest fraction (F3) for the origin of lunar agglutinitic glass has been accruing. They include (1) theoretical expectations that shock pulses should engulf and melt smaller grains more efficiently than larger grains, (2) experimental results of impact shock, albeit at lower than presumed hypervelocity impacts of micrometeorites on the lunar regolith, and (3) new analyses confirming previous results that average compositions of agglutinitic glass are biased towards that of the finest fraction of lunar soils from which they had formed. We add another reason in support of the F3 model. Finer grains of lunar soils are also much more abundant. Hence, electrostatic forces associated with the rotating terminator region bring the finest grains that are obviously much lighter than courser grains to the surface of the Moon. This further contributes to the preferential melting of the finest fraction upon micrometeoritic impacts. New backscattered electron imaging shows that agglutinitic glass is inhomogeneous at submicron scale. Composition ranges of agglutinitic glass are extreme and deviate from that of the finest fraction, even by more than an order of magnitude for some components. Additionally, we show how an ilmenite grain upon impact would produce TiO2‐rich agglutinitic glass in complete disregard to the requirements of fusion of the finest fraction. We propose an addition to the F3 model to accommodate these observations (i.e., that micrometeorite impacts indiscriminately melt the immediate target regardless of grain size or grain composition). We, therefore, suggest that (1) agglutinitic glass is the sum of (a) the melt produced by the fusion of the finest fraction of lunar soils and (b) the microvolume of the indiscriminate target, which melts at high‐shock pressures from micrometeoritic impacts, and that (2) because of the small volume of the melt and incorporating cold soil grains, the melt quenched so rapidly that it did not mix and homogenize to represent any preferential composition, for example, that of the finest fraction. 相似文献
60.
Regional hydrostratigraphy and groundwater flow modeling in the arsenic-affected areas of the western Bengal basin, West Bengal, India 总被引:1,自引:1,他引:1
The first documented interpretation of the regional-scale hydrostratigraphy and groundwater flow is presented for a ~21,000-km2 area of the arsenic-affected districts of West Bengal [Murshidabad, Nadia, North 24 Parganas and South 24 Parganas (including Calcutta)], India. A hydrostratigraphic model demonstrates the presence of a continuous, semi-confined sand aquifer underlain by a thick clay aquitard. The aquifer thickens toward the east and south. In the south, discontinuous clay layers locally divide the near-surface aquifer into several deeper, laterally connected, confined aquifers. Eight 22-layer model scenarios of regional groundwater flow were developed based on the observed topography, seasonal conditions, and inferred hydrostratigraphy. The models suggest the existence of seasonally variable, regional, north–south flow across the basin prior to the onset of extensive pumping in the 1970s. Pumping has severely distorted the flow pattern, inducing high vertical hydraulic gradients across wide cones of depression. Pumping has also increased total recharge (including irrigational return flow), inflow from rivers, and sea water intrusion. Consequently, downward flow of arsenic contaminated shallow groundwater appears to have resulted in contamination of previously safe aquifers by a combination of mechanical mixing and changes in chemical equilibrium. 相似文献