We used laser-ablation inductively coupled plasma mass spectrometry to measure the solubility of gold in synthetic sulfur-free vapor and brine fluid inclusions in a vapor + brine + haplogranite + magnetite + gold metal assemblage. Experiments were conducted at 800°C, oxygen fugacity buffered at Ni-NiO (NNO), and pressures ranging from 110 to 145 MPa. The wt% NaCl eq. of vapor increases from 2.3 to 19 and that of brine decreases from 57 to 35 with increasing pressure. The composition of the vapors and brines are dominated by NaCl + KCl + FeCl2 + H2O. Gold concentrations in vapor and brine decrease from 36 to 5 and 50 to 28 μg/g, respectively, and the calculated vapor:brine partition coefficients for gold decrease from 0.72 to 0.17 as pressure decreases from 145 to 110 MPa. These data are consistent with the thermodynamic boundary condition that the concentration of gold in the vapor and brine must approach a common value as the critical pressure is approached along the 800°C isotherm in the NaCl-KCl-FeCl2-HCl-H2O system.We use the equilibrium constant for gold dissolution as AuOH0, extrapolated from lower temperature and overlapping pressure range, to calculate expected concentrations of AuOH0 in our experimental vapors. These calculations suggest that a significant quantity of gold in our experimental vapors is present as a non-hydroxide species. Possible chloridogold(I) species are hypothesized based on the positively correlated gold and chloride concentrations in our experimental vapors. The absolute concentration of gold in our synthetic vapor, brine, and melt and calculated mass partition coefficients for gold between these physicochemically distinct magmatic phases suggests that gold solubility in aqueous fluids is a function of aqueous phase salinity, specifically total chloride concentration, at magmatic conditions. However, though we highlight here the effect of salinity, the combination of our data with data sets from lower temperatures evinces a significant decrease in gold solubility as temperature drops from 800°C to 600°C. This decrease in solubility has implications for gold deposition from ascending magmatic fluids. 相似文献
Technology has politics and plays a role in societal governance. This article explores the fishing community of Karanrang island (Spermonde Archipelago, Indonesia) to consider how fishing technologies reinforce existing power structures in the local informal governance system. Informal governance actors deploy the politics of technology in order to manage a socially problematic and environmentally destructive fishing economy. In the punggawa-sawi system of patron-client relationships, fishers are economically dependent on patrons, who supply them with fishing technologies like boats, bombs, and cyanide. The patrons themselves are embedded in a complex governance network, encompassing corrupt police and officials, importers, and live food fish traders. The politics of technology contribute to maintaining the local informal governance system of patron-client relationships. This paper draws upon theories from science and technology studies and network governance to argue that although patron-client relationships are problematic in themselves, the politics of technology further maintain power imbalances. 相似文献
Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,... 相似文献
The objective of this paper is to develop a spatial temporal runoff modelling of local rainfall patterns effect on the plant cover hilly lands in Kelantan River Basin. Rainfall interception loss based on leaf area index, loss/infiltration on the ground surface, and runoff calculation were considered as the main plant cover effects on the runoff volume. In this regard, a hydrological and geotechnical grid-based regional model (integrated model) was performed using Microsoft Excel® and GIS framework system for deterministic modelling of rainfall-induced runoff by incorporating plant cover effects. The infiltration process of the current model was integrated with the precipitation distribution method and rainfall interception approach while the runoff analysis of integrated model was employed based on loss/infiltration water on the ground surface with consideration of water interception loss by canopy and the remaining surface water. In the following, the spatial temporal analysis of rainfall-induced runoff was performed using 10 days of hourly rainfall events at the end of December 2014 in Kelantan River Basin. The corresponding changes in pressure head and consequent rate of infiltration were calculated during rainfall events. Subsequently, flood volume is computed using local rainfall patterns, along with water interception loss and the remaining surface water in the study area. The results showed the land cover changes caused significant differences in hydrological response to surface water. The increase in runoff volume of the Kelantan River Basin is as a function of deforestation and urbanization, especially converting the forest area to agricultural land (i.e. rubber and mixed agriculture). 相似文献
Cropland fallows are the next best-bet for intensification and extensification, leading to increased food production and adding to the nutritional basket. The agronomical suitability of these lands can decide the extent of usage of these lands. Myanmar’s agricultural land (over 13.8 Mha) has the potential to expand by another 50% into additional fallow areas. These areas may be used to grow short-duration pulses, which are economically important and nutritionally rich, and constitute the diets of millions of people as well as provide an important source of livestock feed throughout Asia. Intensifying rice fallows will not only improve the productivity of the land but also increase the income of the smallholder farmers. The enhanced cultivation of pulses will help improve nutritional security in Myanmar and also help conserve natural resources and reduce environmental degradation. The objectives of this study was to use remote sensing methods to identify croplands in Myanmar and cropland fallow areas in two important agro-ecological regions, delta and coastal region and the dry zone. The study used moderate-resolution imaging spectroradiometer (MODIS) 250-m, 16-day normalized difference vegetation index (NDVI) maximum value composite (MVC), and land surface water index (LSWI) for one 1 year (1 June 2012–31 May 2013) along with seasonal field-plot level information and spectral matching techniques to derive croplands versus cropland fallows for each of the three seasons: the monsoon period between June and October; winter period between November and February; and summer period between March and May. The study showed that Myanmar had total net cropland area (TNCA) of 13.8 Mha. Cropland fallows during the monsoon season account for a meagre 2.4% of TNCA. However, in the winter season, 56.5% of TNCA (or 7.8 Mha) were classified as cropland fallows and during the summer season, 82.7% of TNCA (11.4 Mha) were cropland fallows. The producer’s accuracy of the cropland fallow class varied between 92 and 98% (errors of omission of 2 to 8%) and user’s accuracy varied between 82 and 92% (errors of commission of 8 to 18%) for winter and summer, respectively. Overall, the study estimated 19.2 Mha cropland fallows from the two major seasons (winter and summer). Out of this, 10.08 Mha has sufficient moisture (either from rainfall or stored soil water content) to grow short-season pulse crops. This potential with an estimated income of US$ 300 per hectare, if exploited sustainably, is estimated to bring an additional net income of about US$ 1.5 billion to Myanmar per year if at least half (5.04 Mha) of the total cropland fallows (10.08 Mha) is covered with short season pulses. 相似文献
Across the UK, sandy beaches and dunes protect coastal infrastructure from waves and extreme water levels during large-scale storms, while providing important habitats and recreational opportunities. Understanding their long-term evolution is vital in managing their condition in a changing climate. Recently, ground-penetrating radar (GPR) methods have grown in popularity in geomorphological applications, yielding centimetre-scale resolution images of near-surface stratigraphy and structure, thus allowing landscape evolution to be reconstructed. Additionally, abrupt changes in palaeo-environments can be visualized in three dimensions. Although often complemented by core data, GPR allows interpretations to be extended into areas with minimal ground-truth control. Nonetheless, GPR data interpretation can be non-intuitive and ambiguous, and radargrams may not initially resemble the expected subsurface geometry. Interpretation can be made yet more onerous when handling the large 3D data volumes that are facilitated with modern GPR technology. Here we describe the development of novel semi-automated GPR feature-extraction tools, based on ‘edge detection’ and ‘thresholding’ methods, which detect regions of increased GPR reflectivity which can be applied to aid in the reconstruction of a range Quaternary landscapes. Since reflectivity can be related to lithological and/or pore fluid changes, the 3D architecture of the palaeo-landscape can be reconstructed from the features extracted from a geophysical dataset. We present 500 MHz GPR data collected over a buried Holocene coastal dune system in North Wales, UK, now reclaimed for use as an airfield. Core data from the site, reaching a maximum depth 2 m, suggest rapid vertical changes from sand to silty-organic units, and GPR profiles suggest similar lateral complexity. By applying thresholding methods to GPR depth slices, these lateral complexities are effectively and automatically mapped. Furthermore, automatic extraction of the local reflection power yields a strong correlation with the depth variation of organic content, suggesting it is a cause of reflectivity contrast. GPR-interpolated analyses away from core control thus offer a powerful proxy for parameters derived from invasive core logging. The GPR data collected at Llanbedr airfield highlight a complex dune system to a depth of 2.8 m, probably deposited in several phases over ~700 years, similar to elsewhere in North Wales. 相似文献
Glacial lakes represent a threat for the populations of the Andes and numerous disastrous glacial lake outburst floods (GLOFs) occurred as a result of sudden dam failures or dam overtoppings triggered by landslides such as rock/ice avalanches into the lake. This paper investigates a landslide-triggered GLOF process chain that occurred on February 23, 2020, in the Cordillera Vilcabamba in the Peruvian Andes. An initial slide at the SW slope of Nevado Salkantay evolved into a rock/ice avalanche. The frontal part of this avalanche impacted the moraine-dammed Lake Salkantaycocha, triggering a displacement wave which overtopped and surficially eroded the dam. Dam overtopping resulted in a far-reaching GLOF causing fatalities and people missing in the valley downstream. We analyze the situations before and after the event as well as the dynamics of the upper portion of the GLOF process chain, based on field investigations, remotely sensed data, meteorological data and a computer simulation with a two-phase flow model. Comparison of pre- and post-event field photographs helped us to estimate the initial landslide volume of 1–2 million m3. Meteorological data suggest rainfall and/or melting/thawing processes as possible causes of the landslide. The simulation reveals that the landslide into the lake created a displacement wave of 27 m height. The GLOF peak discharge at the dam reached almost 10,000 m3/s. However, due to the high freeboard, less than 10% of the lake volume drained, and the lake level increased by 10–15 m, since the volume of landslide material deposited in the lake (roughly 1.3 million m3) was much larger than the volume of released water (57,000 m3, according to the simulation). The model results show a good fit with the observations, including the travel time to the uppermost village. The findings of this study serve as a contribution to the understanding of landslide-triggered GLOFs in changing high-mountain regions.