Experimental study of incongruent evaporation kinetics of enstatite in vacuum and in hydrogen gas     

Shogo Tachibana  Akira TsuchiyamaHiroko Nagahara 《Geochimica et cosmochimica acta》2002,66(4):713-728

Variations in bulk Mg/Si ratios in the various groups of chondritic meteorites indicate that Mg/Si fractionation occurred in the primitive solar nebula. Enstatite (MgSiO₃) evaporates incongruently forming forsterite (Mg₂SiO₄) as an evaporation residue; therefore, evaporation of enstatite produces Mg/Si variations in solid (Mg-rich) and gas (Si-rich) and must be considered as a probable process responsible for Mg/Si fractionation recorded in chondrites. To understand the evaporation kinetics of enstatite, incongruent evaporation experiments on enstatite single crystals have been carried out in vacuum and in hydrogen gas at temperatures of 1300 to 1500°C. A polycrystalline forsterite layer is formed on the surface of enstatite by preferential evaporation of the SiO₂ component, both in vacuum and in hydrogen gas. The thickness of the forsterite layer in vacuum increases with time in the early stage of evaporation and later the thickness of the forsterite layer remains constant (several microns). This is due to the change in the rate limiting process from surface reaction plus nucleation and growth to diffusion in the surface forsterite layer. The activation energy of the diffusion-controlled evaporation rate constant of enstatite is 457 (±58) kJ/mol. A thinner forsterite layer is formed on the surface of enstatite in hydrogen gas than in vacuum. Evaporation of enstatite in hydrogen gas is also considered to be controlled by diffusion of ions through the forsterite layer. The thin forsterite layer formed in hydrogen gas is ascribed to the enhanced evaporation rate of forsterite in the presence of hydrogen gas.The results are applied to incongruent evaporation under the solar nebular conditions. The steady thickness of the forsterite of nebular pressure-temperature conditions is estimated to be submicron because of the enhanced evaporation rate of forsterite under hydrogen-rich nebular conditions if evaporated gases are taken away immediately and no back reaction occurs (an open system). Because enstatite grains in the solar nebula would be comparable to the estimated steady thickness of forsterite, evaporation of such enstatite grains under kinetic conditions could play an important role in producing variations in Mg/Si ratios between solid and gas in the solar nebula.  相似文献   

Proceedings of INTERRAD VII: Current radiolarian and related research     

Akira Yao  Patrick De  Wever 《Island Arc》1996,5(2):90-90

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Analysis of the global relationship of biennial variation of sea surface temperature and air-sea heat flux using satellite data     

Masanori Konda  Norihisa Imasato  Akira Shibata 《Journal of Oceanography》1996,52(6):717-746

We investigated the phase difference and the cross correlation coefficient between the band-pass filtered biennial variations of sea surface temperature (SST) and air-sea heat flux estimated by the monthly mean 2°×2° satellite data of Advanced Very High Resolution Radiometer (AVHRR) and Special Sensor Microwave/Imager (SSM/I) from July 1987 to June 1991. Judging from the phase difference, it can be determined whether the biennial variation of SST is controlled by local thermal air-sea interaction or oceanic processes of horizontal transport. When the local air-sea heat flux controls the biennial variation of SST, the phase of SST advances /2 (6 months) against that of the air-sea heat flux. In contrast, when the biennial variation of SST is controlled by the oceanic process, the phase difference between the SST and the air-sea heat flux becomes 0 or (12 months). In this case, two types of the phase differences are determined, depending on which variability of SST and air-sea heat flux is larger. The close thermal air-sea interaction is noticeable in the tropics and in the western boundary current region. The phase difference of /2 appears mainly in the north Pacific, the southeast Indian Ocean, and the western tropical Pacific; zero in the eastern tropical Pacific and the northeast and equatorial Atlantic; and that of in the central equatorial Pacific and north of the intertropical convergence zone (ITCZ) of the Atlantic. Phase differences of 0, , or /2 are possible in the western boundary current regions. This fact indicates that each current plays a different role to the biennial variation of SST. It is inferred that SST anomalies in the tropics are mutually correlated, and the process in which marked SST anomalies in the tropics are transferred to the remote area was probed. In the equatorial Pacific, the SST anomaly is transferred by the long planetary wave. On the other hand, it is found from the phase relationship and the horizontal correlation of SST that the SST anomaly in the central and western equatorial Pacific is connected through atmospheric mediation. It is suggested that the biennial variation of SST in the eastern Indian Ocean is affected by heat transport due to the Indonesian throughflow from the western tropical Pacific. It is found that the mentioned pattern of the interannual variation of SST in the tropical Atlantic as a dipole is not tenable.  相似文献   

Study of metal contents of elasmobranch fishes: part 1—metal concentration in the muscle tissues of a dogfish, squalus mitsukurii     

Masashi Taguchi  Kenji Yasuda  Shozo Toda  Makoto Shimizu 《Marine environmental research》1979,2(3):239-249

Concentrations of Hg, Zn, Fe, Cd and Cu in the muscle tissues of a dogfish, Squalus mitsukurii, were determined by atomic absorption spectrometry and found to be in the ranges of f0·019–2·13, 1·8–3·6, 1·5–5·7, 0·001–0·018 and 0·12–0·70 μg/g wet weight, respectively. The frequency distributions of concentrations, with the exception of mercury, were found to be log-normal. The correlation coefficient between mercury content and total length was positive and large and statistically highly significant. For other metals negative correlations were observed. Mercury concentration in the muscle was found to increase in proportion to the total length cubed. Regression of mercury concentration on age of sharks was shown to be linear. Analysis of covariance showed that the difference between sexes was not statistically significant, either in slope or in height. The concentration of mercury in the muscle tissues of embryos was considerably lower, Cd roughly the same and Zn and Fe higher than those of mothers. The concentrations of Zn, Fe and Cu are higher in the embryonic stage and immediately after birth than in later stages of growth.  相似文献   

Seasonal variation of bottom turbidity layer in Etauchi Bay     

Terumi Tanimoto  Akira Hoshika 《Journal of Oceanography》1991,47(6):286-296

The beam attenuation coefficient, organic carbon (POC) and organic nitrogen (PON) contents of suspended materials in Etauchi Bay, which has little inflow of river water as well as very weak tidal current (maximum speed: 6.5cm·sec⁻¹), were measured as a function of depth for all seasons to understand a seasonal variation of bottom turbidity layer. In spring and summer, the beam attenuation coefficient in bottom layer and POC and PON contents of suspended materials in the surface water layer increased with time, which brought the occurrence of the bottom turbidity layer. From autumn to winter, however, their concentrations became low and constant over the whole depth almost independent of time. As a result, the bottom turbidity layer disappeared in winter and beam attenuation coefficient became constant over the whole depth. From these results, it may be considered that the bottom turbidity layer was produced by phytodetritus brought from surface water layer, rather than by resuspension of bottom sediment in Etauchi Bay.  相似文献   

A wind speed retrieval algorithm by combining 6 and 10 GHz data from Advanced Microwave Scanning Radiometer: Wind speed inside hurricanes     

Akira Shibata 《Journal of Oceanography》2006,62(3):351-359

A wind speed retrieval algorithm was developed using 6 and 10 GHz h-pol (6H and 10H) data of the Advanced Microwave Scanning Radiometer (AMSR) aboard the Advanced Earth Observation Satellite-II (ADEOS-II) and AMSR-E aboard AQUA, for the purpose of retrieving wind speed inside rainstorms, primarily hurricanes and typhoons. The h-pol was used rather than the v-pol, because the brightness temperature sensitivity to the ocean wind at h-pol is larger than v-pol. The microwave emission change of 6H and 10H corresponding to ocean wind was evaluated in no-rain areas by combining AMSR and SeaWinds data aboard the ADEOS-II (SeaWinds was NASA’s scatterometer), and it was found that the ratio of the two 6H to 10H increments due to ocean wind is 0.9. Assuming that this result also holds with higher wind speeds and under rainy conditions, the brightness temperatures at 6H and 10H were simulated using a microwave radiative transfer model. A parameter W6 (unit; Kelvin) was then defined, representing an increment at 6H due to ocean wind. W6 is applicable to rainy areas, and to all ranges of sea surface temperature. W6 was compared with wind speed reported by the National Hurricanes Center for several hurricanes in the Western Atlantic Ocean during three years (2002 to 2004). W6 averaged around centers of hurricanes was found to exhibit a sensitivity to wind speed, such as increasing from 22 K to 65 K as the wind speed rose from 65 to 140 knots (33 to 72 m/s), and an empirical relationship relating the averaged W6 to wind speed in hurricanes was derived.  相似文献   

Intrusion of less saline shelf water into the Kuroshio subsurface layer in the East China Sea   总被引：7，自引：0，他引：7  

Atsuhiko?IsobeEmail author  Eiji?Fujiwara  Pil-Hun?Chang  Koichi?Sugimatsu  Manabu?Shimizu  Takeshi?Matsuno  Atsuyoshi?Manda 《Journal of Oceanography》2004,60(5):853-863

The possible origin and cause of the less saline shelf water detected in the Kuroshio subsurface layer around the shelf edge of the East China Sea are investigated using observational results obtained in May 1998–2001 in conjunction with a dataset archived by Japan Oceanographic Data Center and a numerical model. The observations show that subsurface intrusions of less saline water are always detected in May in layers above 24.5σθ isopycnal surface, and that salinity inversions (i.e., areas in which the less saline water lies beneath the saline water) are detected around the trough of the Kuroshio frontal eddy (or wave). Analyses of the archived dataset reveal that the isopycnal surface of 24.5σθ is the deepest layer of the Kuroshio pycnocline outcropping to the sea surface on the shallow shelf in early spring. Outcropping isopycnals above 24.5σθ encounter a less saline water plume originating from the Changjiang, especially in the western East China Sea. Thereafter, the less saline water moves along isopycnal layers and reaches the Kuroshio front around the shelf edge. Numerical models demonstrate that, when the frontal wave captures the less saline water, the shelf water takes the form of a salinity inversion in the trough because isohalines in the frontal wave have a phase lag between the upper and lower layers in consequence of the baroclinic instability.  相似文献   

Comments on the “shear effect” and diffusion in the Lagrangian framework     

Brian G. Sanderson  Akira Okubo 《Journal of Oceanography》1987,43(3):183-196

We indentify three different types of Lagrangian coordinate systems that are used in oceanography. These are: true Lagrangian coordinates (TLC), Lagrangian coordinates (LC), and averaged Lagrangian coordinates (ALC). The diffusion process is studied in each of these coordinate systems. At large scales the eddydiffusivity is proven to be independent of molecular diffusivity, providing the spectrum of turbulent kinetic energy varies as scale raised to a power less than 4 1/3. The shear effect is examined using solutions to the averaged Lagrangian diffusion equation obtained by Okuboet al. (1983). In Eulerian coordinates both advection and diffusion are necessary for the occurrence of the shear effect, while in ALC timedependent dispersion coefficients are necessary for the process. In TLC we use the method of Taylor (1921) to study the dispersion of material by a velocity field, that from the Eulerian perspective, consists of turbulent motion across a uniform shear. The transformation of the above Eulerian velocity field into TLC results in a uniform deformation field and turbulent motion both along and across the shear. This work shows how dispersion of material is related to the turbulent Eulerian velocity and uniform velocity gradients. The instantaneous rate of change of variance of a spreading patch of material is completely specified by the instantaneous divergence obtained over the area occupied by the patch (Kawai, 1976). This relationship is shown to depend upon the fact that at any particular instant it is possible to define TLC that are equivalent to the Eulerian coordinates. In order to describe patch spreading from divergence measured over longer periods it is also necessary to consider other dispersive processes.Contribution number of the Newfoundland Institute of Cold Ocean Science.  相似文献   

On the local equilibrium of winds and wind-waves in relation to surface drag   总被引：3，自引：0，他引：3  

Akira Masuda  Tadao Kusaba 《Journal of Oceanography》1987,43(1):28-36

Local equilibrium of winds and wind-waves is discussed as a basis for research of the drag coefficient of the water surface as well as for the spectral growth of wind-waves. This hypothesis assumes, in a narrow sense, that statistical properties are determined from four physical quantities, which represent winds and wind-waves: the friction velocityu _*, the gravitational accelerationg, the powerE of the surface displacement, and the peak frequency _p of a wind-wave spectrum. Then one has only one nondimensionalcontrol parameter, which may be either the wave age or wave nonlinearity (slope) of dominant waves. In a wide-sense, one can take into account viscosity and surface tension in terms of one more additional parameter by virtue of the virtual invariance of those material constants; that parameter describes the scale ratio between dominant waves and the short waves for which viscosity or surface tension is important. A unified expression for the roughness height according to this hypothesis turns out to include Charnock's and Toba's formulas as special cases. On the basis of a preliminary analysis of the experimental data, a new empirical formula is proposed.  相似文献   

A statistical method to get surface level air-temperature from satellite observations of precipitable water     

Pankajakshan Thadathil  Akira Shikauchi  Yasuhiro Sugimori  Masahisa Kubota 《Journal of Oceanography》1993,49(5):551-558

Ten-day mean surface level air-temperature from SSMI precipitable water (SSMI-T _a ) has been derived and compared with the temperature from two ocean data buoys (Buoy-T _a ) of Japan Meteorological Agency (JMA) for a period of six months (July–December, 1988). Statistical relations between air-temperature and mixing ratio, using data from ocean data buoys are used to derive air-temperature from mixing ratio, obtained from SSMI precipitable water. For getting the mixing ratio from precipitable water, regional mixing ratio-precipitable water relations have been used, instead of global relation proposed by Liu (1986). The rms errors (standard deviation of the difference between SSMI-T _a and Buoy-T _a ) for two buoy locations are found to be 1.15 and 1.12°C, respectively. Surface level temperature for the two buoy locations are also derived using direct regression relation between Buoy-T _a and precipitable water. The rms errors of the SSMI-T _a , in this case are found to be reduced to 1.0°C.  相似文献